
You have already added 0 works in your ORCID record related to the merged Research product.
You have already added 0 works in your ORCID record related to the merged Research product.
<script type="text/javascript">
<!--
document.write('<div id="oa_widget"></div>');
document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=undefined&type=result"></script>');
-->
</script>
An experimental and modeling study of ammonia with enriched oxygen content and ammonia/hydrogen laminar flame speed at elevated pressure and temperature

An experimental and modeling study of ammonia with enriched oxygen content and ammonia/hydrogen laminar flame speed at elevated pressure and temperature
Laminar flame speeds of ammonia with oxygen-enriched air (oxygen content varying from 21-30 vol.%) and ammonia-hydrogen-air mixtures (fuel hydrogen content varying from 0-30 vol.%) at elevated pressure (1-10 bar) and temperature (298-473 K) were determined experimentally using a constant volume combustion chamber. Moreover, ammonia laminar flame speeds with helium as an inert were measured for the first time. Using these experimental data along with published ones, we have developed a newly compiled kinetic model for the prediction of the oxidation of ammonia and ammonia-hydrogen blends in freely propagating and burner stabilized premixed flames, as well as in shock tubes, rapid compression machines and a jet-stirred reactor. The reaction mechanism also considers the formation of nitrogen oxides, as well as the reduction of nitrogen oxides depending on the conditions of the surrounding gas phase. The experimental results from the present work and the literature are interpreted with the help of the kinetic model derived here. The experiments show that increasing the initial temperature, fuel hydrogen content, or oxidizer oxygen content causes the laminar flame speed to increase, while it decreases when increasing the initial pressure. The proposed kinetic model predicts the same trends than experiments and a good agreement is found with measurements for a wide range of conditions. The model suggests that under rich conditions the N2H2 formation path is favored compared to stoichiometric condition. The most important reactions under rich conditions are: NH2+NH=N2H2+H, NH2+NH2=N2H2+H2, N2H2+H=NNH+H2 and N2H2+M=NNH+H+M. These reactions were also found to be among the most sensitive reactions for predicting the laminar flame speed for all the cases investigated.
AMMONIA, Kinetic modeling, [SPI.FLUID]Engineering Sciences [physics]/Reactive fluid environment, NOX, NOx, [SPI.FLUID] Engineering Sciences [physics]/Reactive fluid environment, kinetic modeling, Ammonia-hydrogen, ammonia, laminar flame speed, ammonia-hydrogen, Laminar flame speed
AMMONIA, Kinetic modeling, [SPI.FLUID]Engineering Sciences [physics]/Reactive fluid environment, NOX, NOx, [SPI.FLUID] Engineering Sciences [physics]/Reactive fluid environment, kinetic modeling, Ammonia-hydrogen, ammonia, laminar flame speed, ammonia-hydrogen, Laminar flame speed
4 Research products, page 1 of 1
- 2021IsAmongTopNSimilarDocuments
- 2019IsAmongTopNSimilarDocuments
- 2021IsAmongTopNSimilarDocuments
citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).391 popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.Top 0.1% influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).Top 1% impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.Top 0.01%
