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Corrosion assessment of promising hydrated salts as sorption materials for thermal energy storage systems

Authors: Angel G. Fernández; Margalida Fullana; Luigi Calabrese; Valeria Palomba; Andrea Frazzica; Luisa F. Cabeza;

Corrosion assessment of promising hydrated salts as sorption materials for thermal energy storage systems

Abstract

Salt hydrates are an appealing option to be used as sorption materials in thermal energy storage (TES). In this work, strontium bromide and magnesium sulphate have been selected as one of the most promising salt hydrates since they present high energy storage density (>130 kWh/m3) and efficiency (>20%). One of the main drawbacks of sorption materials rely on control the hydratation-dehydratation process but there are other parameters that can modify this behaviour as the corrosive potential of these salts in contact with the container material selected for the application. Hence, four different metal container materials, specifically stainless steel, copper, aluminium, and carbon steel have been tested in SrBr2$6H2O and MgSO4$7H2O hydrate salts, during 100 h at dehydratation conditions. After the gravimetric and micrograph analysis carried out via scanning electron microscopy (SEM) study, only carbon steel is not recommended for this application in contact with SrBr2$6H2O, obtaining a corrosion rate of 0.038 mm/year, with a metallographic corrosion layer thickness of 25.2 mm. Aluminium, copper and stainless steel showed a better corrosion resistance also in SrBr2$6H2O and MgSO4$7H2O with corrosion rates below 0.008 mm/year. This work was partially funded by the Ministerio de Ciencia, Innovación y Universidades de España (RTI2018-093849-B-C31 - MCIU/AEI/FEDER, UE). The authors would like to thank the Catalan Government for the quality accreditation given to their research group GREiA (2017 SGR 1537). GREiA is a certified agent TECNIO in the category of technology developers from the Government of Catalonia. This work is partially supported by ICREA under the ICREA Academia programme.

Countries
Italy, Spain, Spain, Spain, Spain
Keywords

Hydrated salts, Thermal energy storage, Corrosion, Sorption materials, Corrosion; Hydrated salts; Sorption materials; Thermal energy storage

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
25
Top 10%
Average
Top 10%
Green
hybrid