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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Repositori Instituci...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
The Journal of Physical Chemistry Letters
Article . 2015 . Peer-reviewed
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Impact of Capacitive Effect and Ion Migration on the Hysteretic Behavior of Perovskite Solar Cells

Authors: Juan Bisquert; Juan Bisquert; Kai Zhu; Mengjin Yang; Germà Garcia-Belmonte; Wenle Li; Bo Chen; +4 Authors

Impact of Capacitive Effect and Ion Migration on the Hysteretic Behavior of Perovskite Solar Cells

Abstract

In the past five years, perovskite solar cells (PSCs) based on organometal halide perovskite have exhibited extraordinary photovoltaic (PV) performance. However, the PV measurements of PSCs have been widely recognized to depend on voltage scanning condition (hysteretic current density-voltage [J-V] behavior), as well as on voltage treatment history. In this study, we find that varied PSC responses are attributable to two causes. First, capacitive effect associated with electrode polarization provides a slow transient non-steady-state photocurrent that modifies the J-V response. Second, modification of interfacial barriers induced by ion migration can modulate charge-collection efficiency so that it causes a pseudo-steady-state photocurrent, which changes according to previous voltage conditioning. Both phenomena are strongly influenced by ions accumulating at outer interfaces, but their electrical and PV effects are different. The time scale for decay of capacitive current is on the order of seconds, whereas the slow redistribution of mobile ions requires several minutes.

Country
Spain
Keywords

Ions, Titanium, Perovskite solar cells, Oxides, Calcium Compounds, Photocurrent density−voltage, J−V hysteresis, Photovoltaics, Power conversion efficiency, Electricity, Solar Energy, Humans

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visibility
citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
views
OpenAIRE UsageCountsViews provided by UsageCounts
342
Top 0.1%
Top 1%
Top 0.1%
8
bronze