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Photoconductive transients and one-dimensional charge carrier dynamics in discotic liquid crystals

handle: 20.500.14243/202078
Photoconductive transients and one-dimensional charge carrier dynamics in discotic liquid crystals
Carrier transits and photoconductivity in hexaalkoxytriphenylene- (HAT) based liquid crystals and their binary 1:1 mixtures with hexaalkylphenyltriphenylene (PTP) are analyzed using time-dependent diffusion theory. The HAT6 derivatives, which show the best transits, can be modeled with a homogeneously distributed single-trap model. The transit data for the compound formed by the 1:1 binary mixture of HAT11-PTP9, which exhibits better columnar stability and higher carrier mobility, cannot, however, be explained using homogeneous multiple trapping models alone. The evidence presented in this paper also suggests that the trap-limited carrier relaxation does indeed obey the law of one-dimensional transport, which says that with an electric field. i.e., in the drift-limited regime, carriers take less time to reach the equilibrium values of the diffusivity. This is a particularly exciting result, which directly confirms rigorous theoretical predictions and is consistent with the previously discussed data taken in the crystalline phase of HAT6.
- University of London United Kingdom
- National Research Council Italy
- Queen Mary University of London United Kingdom
- University of Leeds United Kingdom
MECHANISM, ELECTRONIC CONDUCTIVITY, MODEL, COLUMNAR PHASE, SYSTEMS, MOBILITY, ENERGY MIGRATION, STOCHASTIC TRANSPORT, TIME DISPERSION, TRIPHENYLENE
MECHANISM, ELECTRONIC CONDUCTIVITY, MODEL, COLUMNAR PHASE, SYSTEMS, MOBILITY, ENERGY MIGRATION, STOCHASTIC TRANSPORT, TIME DISPERSION, TRIPHENYLENE
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