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Spectroscopic Study of Vanadium Electrolytes in Vanadium Redox Flow Battery (VRFB)

descriptionPublicationkeyboard_double_arrow_right Article , Other literature type 02 Apr 2013Publisher:The Electrochemical SocietyJournal:ECS Transactions, volume 45, pages 25-36 (issn: 1938-5862, eissn: 1938-6737,

Authors: Denis Noel Buckley; Robert P. Lynch; Xin Gao; Leahy Martin J;

doi: 10.1149/04526.0025ecst

Spectroscopic Study of Vanadium Electrolytes in Vanadium Redox Flow Battery (VRFB)

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Abstract

In this paper, we characterize the absorbance spectra and explain the spectroscopic behavior typically found in VRFB electrolytes at various mixture ratios of VII/VIII and VIV/VV mixtures in H2SO4. We demonstrate that the linear behavior of absorbance with respect to mixture ratio for the anolyte (VII/VIII) can be used to determine mixture ratio. In addition, we find that the non-linear behavior of the absorbance with respect to mixture ratio for the catholyte (VIV/VV) is due to the formation of a vanadium complex.

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University of Limerick
Ireland

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