In order to overcome the barriers against the FCVs, a platinum-free anionic fuel cell has been developed. The platinum-free fuel cell, by using liquid hydrazine hydrate (N2H4·H2O) for fuel, comprises cobalt or nickel for the anode and cobalt for the cathode, can demonstrate a high performance, and achieves zero CO2 emissions. For vehicle application, a detoxification method, which repeatedly fixes and releases hydrazine hydrate, has also been developed. In this paper, the fuel cell performance using nickel, cobalt and platinum as an anode catalyst was compared. It was shown clearly that nickel and cobalt have the superior catalytic activity to platinum. The influence of fuel concentration and KOH addition is also discussed. This new fuel cell technology can conquer the conventional subject, and is expected to spread widely. Moreover, this technology was exhibited and attracted attention in Environmental Showcase of G8 Hokkaido Toyako Summit held in July, 2008.