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Pyrolysis recovery and product distribution of shrimp shell waste: Insights from thermogravimetric-Fourier transform infrared spectroscopy and pyrolysis–gas chromatography/mass spectrometry characterization

Shrimp consumption is increasing owing to its rich nutrition and delicious taste. As a result, the generation of shrimp shell waste is also increasing, while the current disposal method such as landfilling causes pollution and produces harmful leachate to living organisms and the environment. Therefore, a proper management strategy is needed to dispose of shrimp shell waste to mitigate the adverse effects caused to the environment. This study presents an in-depth approach to reveal the properties of shrimp shell waste and explore its potential for use in various applications. The shrimp shell waste was subjected to pyrolysis–gas chromatography/mass spectrometry and thermogravimetric-Fourier transform infrared spectroscopy pyrolysis to evaluate the gas composition from pyrolysis. Thermogravimetric-Fourier transform infrared spectroscopy analysis reveals that when the optimal temperature for pyrolysis is 400 °C–600 °C, the predominant functional group of gases produced are –CH, –OH, and –NH. On the other hand, the results of pyrolysis–gas chromatography/mass spectrometry indicate that hydrocarbon (51.86%) is the main product of shrimp shell waste pyrolysis at 900 °C, which can be used in paints, paint thinners, rubber, printing inks, adhesives (glue). Although it has a calorific value of 15.113 MJ/kg, it cannot be directly burned because of its high nitrogen concentration (10.85 wt.%) which may generate harmful pollutants such as nitrogen oxides. Overall, pyrolysis is recommended as a viable method for converting shrimp shell waste into versatile products.
- Universiti Malaysia Terengganu Malaysia
- Universiti Malaysia Terengganu Malaysia
- Yuan Ze University Taiwan
- Aarhus University Denmark
- Chandigarh University India
citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).1 popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.Average influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).Average impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.Average
