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Modified sorbents based on soda production sludge for extracting ions of heavy metals from aqueous solutions waste water

The purification of industrial and surface wastewater from heavy metal ions (HMI) to requirements for the discharge of treated wastewater into natural waters is one of the most complicated environmental and technological problems. For the deep purification of waste water from the HMI, the use of cheap sorbents obtained from production waste is the most promising. One of the many-tonnage wastes of technology of inorganic substances is the sludge formed in the production of soda by the ammonia Solvay, s method. Currently, sludge is stored in sludge accumulators and is a long-term source of pollution of environmental objects. Scientific developments in the utilization of slimes with the production of building materials, etc., have not found wide practical use, which is due to the heterogeneity of the granulometric and chemical composition of the waste. Carried out X-ray phase analysis and studies of the physicochemical and chemical properties of waste samples showed that its main components are calcium carbonate (calcite) and calcium hydroxide (portlandite). It is known that the natural mineral limestone efficiently extracts HMI from aqueous solutions with the formation of less soluble basic salts, carbonates, and hydroxy carbonates of HM. It has been established that sludge samples have high sorption activity when copper(II) and zinc ions are extracted from low concentrated solutions (sorption capacity for copper ions is 35.0 mg/g, sorption capacity for zinc ions is 40 mg/g). To increase the operational properties, a method has been developed for the production of a modified granular sorbent based on the sludge of soda production, consisting in treating with sodium silicate. The effect of a dose of sodium silicate in the sorbent composition on the mechanical strength and sorption properties of the obtained samples was studied. It has been established that the introduction of 8,6% SiO2 into the sludge leads to an increase in the mechanical strength by 50–80%, and does not have a significant effect on the sorption activity of the material. The kinetic and sorption regularities of extraction of copper(II) ions and zinc on modified sorbents are revealed. Based on the analysis of the adsorption isotherms obtained, the adsorption equilibrium constants and maximum adsorption values (Amax (Cu2+) = 50.8 mg/g; Amax (Zn2+) = 97.1 mg/g) were determined. Obtained sorption materials can be recommended for wastewater treatment from HMI.
- Perm National Research Polytechnic University Russian Federation
- Perm National Research Polytechnic University Russian Federation
heavy metals ions, sorption capacity, sorbents, soda production sludge, calcium carbonate
heavy metals ions, sorption capacity, sorbents, soda production sludge, calcium carbonate
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