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Electrocatalytic Activity and Durability of Pt-Decorated Non-Covalently Functionalized Graphitic Structures

Authors: Negro E; Stassi A; Baglio V; Arico AS; Koper GJM;

Electrocatalytic Activity and Durability of Pt-Decorated Non-Covalently Functionalized Graphitic Structures

Abstract

Carbon graphitic structures that differ in morphology, graphiticity and specific surface area were used as support for platinum for Oxygen Reduction Reaction (ORR) in low temperature fuel cells. Graphitic supports were first non-covalently functionalized with pyrene carboxylic acid (PCA) and, subsequently, platinum nanoparticles were nucleated on the surface following procedures found in previous studies. Non-covalent functionalization has been proven to be advantageous because it allows for a better control of particle size and monodispersity, it prevents particle agglomeration since particles are bonded to the surface, and it does not affect the chemical and physical resistance of the support. Synthesized electrocatalysts were characterized by electrochemical half-cell studies, in order to evaluate the Electrochemically Active Surface Area (ECSA), ORR activity, and durability to potential cycling and corrosion resistance.

Countries
Italy, Netherlands
Keywords

oxygen reduction reaction, Chemical technology, Fuel cell, Carbon corrosion, TP1-1185, carbon corrosion, Durability, Oxygen reduction reaction, fuel cell, Chemistry, Carbon nanofibers, carbon nanofibers, durability, Pt catalyst, QD1-999

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
views
OpenAIRE UsageCountsViews provided by UsageCounts
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9
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Energy Research