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Recent Progress in Metal Borohydrides for Hydrogen Storage

doi: 10.3390/en4010185
The prerequisite for widespread use of hydrogen as an energy carrier is the development of new materials that can safely store it at high gravimetric and volumetric densities. Metal borohydrides M(BH4)n (n is the valence of metal M), in particular, have high hydrogen density, and are therefore regarded as one such potential hydrogen storage material. For fuel cell vehicles, the goal for on-board storage systems is to achieve reversible store at high density but moderate temperature and hydrogen pressure. To this end, a large amount of effort has been devoted to improvements in their thermodynamic and kinetic aspects. This review provides an overview of recent research activity on various M(BH4)n, with a focus on the fundamental dehydrogenation and rehydrogenation properties and on providing guidance for material design in terms of tailoring thermodynamics and promoting kinetics for hydrogen storage.
- Kyushu University Japan
- University of Hawaiʻi Sea Grant United States
- Kyushu University Japan
- Institute for Materials Research, Tohoku University Japan
- Tohoku University Japan
Technology, T, hydride, hydrogen; hydride; borohydride; hydrogen storage, hydrogen storage, hydrogen, borohydride, jel: jel:Q0, jel: jel:Q4, jel: jel:Q40, jel: jel:Q, jel: jel:Q43, jel: jel:Q42, jel: jel:Q41, jel: jel:Q48, jel: jel:Q47, jel: jel:Q49
Technology, T, hydride, hydrogen; hydride; borohydride; hydrogen storage, hydrogen storage, hydrogen, borohydride, jel: jel:Q0, jel: jel:Q4, jel: jel:Q40, jel: jel:Q, jel: jel:Q43, jel: jel:Q42, jel: jel:Q41, jel: jel:Q48, jel: jel:Q47, jel: jel:Q49
citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).428 popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.Top 1% influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).Top 1% impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.Top 0.1%
