The contradiction between human and land has always been a problem in the process of development and utilization of land resources. Under such circumstances, relevant government agencies put forward the management concept of land resource capitalization. As an effective policy to implement the conception of land resource capitalization, land transfer is of great significance to reforming rural land systems and liberating productivity in poor areas of Tai-hang Mountain in Hebei. However, how to integrate environmental impact and value evaluation of ecosystem services of land transfer in the process of resource capitalization deserves our attention. This paper takes the land transfer of Fuping, Hebei in Tai-hang Mountain as an example, combined with life cycle assessment (LCA), life cycle cost assessment (LCC), and the methods of value evaluation of ecosystem services to quantify the changes of environmental loads, economic costs, and ecosystem services in the whole process and different stages of land resource capitalization. Moreover, through the sensitivity analysis of key environmental indicators, the possibility of restricting environmental costs is explored. This paper studies land transfer from the direction of the cross-discipline and provides a new idea for land resource management.