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Optimized method for black carbon analysis in ice and snow using the Single Particle Soot Photometer

Authors: Martin Gysel; Margit Schwikowski; Margit Schwikowski; Margit Schwikowski; Susan Kaspari; M. Laborde; J. A. Menking; +2 Authors

Optimized method for black carbon analysis in ice and snow using the Single Particle Soot Photometer

Abstract

Abstract. In this study we attempt to optimize the method for measuring black carbon (BC) in snow and ice using a single particle soot photometer (SP2). Beside the previously applied ultrasonic (CETAC) and Collison-type nebulizers we introduce a jet (APEX-Q) nebulizer to aerosolize the aqueous sample for SP2 analysis. Both CETAC and APEX-Q require small sample volumes (few milliliters) which makes them suitable for ice core analysis. The APEX-Q shows the least size-dependent nebulizing efficiency in the BC particle diameter range of 100–1000 nm. The CETAC has the advantage that air and liquid flows can be monitored continuously. All nebulizer-types require a calibration with BC standards for the determination of the BC mass concentration in unknown aqueous samples. We found Aquadag to be a suitable material for preparing calibration standards. Further, we studied the influence of different treatments for fresh discrete snow and ice samples as well as the effect of storage. The results show that samples are best kept frozen until analysis. Once melted, they should be sonicated for 25 min, immediately analyzed while being stirred and not be refrozen.

Countries
United States, Switzerland
Keywords

Climate, TA715-787, ice, Environmental engineering, snow, TA170-171, black carbon, Atmospheric Sciences, climate change, Earthwork. Foundations, glaciology, 540 Chemistry, 570 Life sciences; biology, Environmental Sciences

  • BIP!
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    citations
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    69
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
69
Top 10%
Top 10%
Top 10%
Green
gold