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Japanese Journal of Applied Physics

Article . 1974 . Peer-reviewed

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Japanese Journal of Applied Physics

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Infrared Spectral Studies of Hydrogen Fluoride Adsorbed on Potassium Bromide

descriptionPublicationkeyboard_double_arrow_right Article , Journal 01 Jan 1974Publisher:IOP PublishingJournal:Japanese Journal of Applied Physics, volume 13, page 109 (issn: 0021-4922, eissn: 1347-4065,

Authors: Shozo Takeno; Soichi Hayashi; Tohru Takenaka; Kazuhiro Wada;

doi: 10.7567/jjaps.2s2.109

Infrared Spectral Studies of Hydrogen Fluoride Adsorbed on Potassium Bromide

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Abstract

Infrared absorption spectra of adsorbed HF on the inner surface of KBr windows have been observed at room temperature. As the equilibrium gas pressure p over the adsorbed species is changed, different spectra are obtained for the following pressure ranges: (a) p\gtrsim40, (b) 15\lesssimp\lesssim30, (c) 3\lesssimp\lesssim11 and (d) p\lesssim2 Torr. Spectral changes between adjacent pressure ranges are sharp, and these changes occur almost reversibly with variation of the pressure. The four spectra are considered to correspond to the four phases of adsorption: (a) KFnHF (n4), (b) KF3HF, (c) KF2HF and (d) KFHF.

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Kyoto University
Japan

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