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Electrochemical Behaviour of Platinum Nanoparticles Supported on Polypyrrole (PPy)/C Composite

descriptionPublicationkeyboard_double_arrow_right Article , Other literature type 27 May 2008Publisher:The Electrochemical SocietyJournal:ECS Transactions, volume 6, pages 93-103 (issn: 1938-5862, eissn: 1938-6737,

Authors: Souad Mokrane; Laid Makhloufi; Nicolas Alonso-Vante;

doi: 10.1149/1.2943228

Electrochemical Behaviour of Platinum Nanoparticles Supported on Polypyrrole (PPy)/C Composite

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Abstract

We report on the synthesis of composites Polypyrrole/Carbon (PPy/C) to be used as matrix-support of platinum nanoparticles prepared by carbonyl chemical route. The composite materials with different PPy loading were characterized by physical chemical methods, such as elemental analysis, infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), and transmission electron microscopy (TEM). The catalysts: 20 wt. % Pt/composites were used as substrates for the oxygen reduction reaction in acid medium. For the same catalyst loading (50 µg cm-2), it was observed that the nature of the composite strongly influences the electrochemical activity of nanoparticulated platinum.

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