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Atmospheric chemistry of CH3CHF2 (R-152a): mechanism of the CH3CF2O2+HO2 reaction

descriptionPublicationkeyboard_double_arrow_right Article , Journal 01 Jun 2004 Denmark, Japan Publisher:Elsevier BVJournal:Chemical Physics Letters, volume 391, pages 165-169 (issn: 0009-2614,

Authors: Hashikawa, Y; Kawasaki, M; Andersen, Mads Peter Sulbæk; Hurley, MD; Wallington, TJ;

doi: 10.1016/j.cplett.2004.04.095

handle: 2433/3787

Atmospheric chemistry of CH3CHF2 (R-152a): mechanism of the CH3CF2O2+HO2 reaction

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Abstract

FTIR smog chamber techniques have been used to investigate the mechanism of the reaction of CH3CF2O2 with HO2 radicals in 100–700 Torr of synthetic air at 296 K. The reaction gives CH3CF2OOH and COF2 in molar yields of 0.53 ± 0.05 and 0.47 ± 0.05, respectively. Results are discussed with respect to the atmospheric chemistry of peroxy radicals and the environmental impact of R-152a.

Countries

Denmark, Japan

Related Organizations

Kyoto University
Japan
Ford Motor Company (United States)
United States
University of Copenhagen
Denmark
Ford Motor Company (United States)
United States
University of Copenhagen
Denmark

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