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Corrosion evaluation of eutectic chloride molten salt for new generation of CSP plants. Part 1: Thermal treatment assessment

Authors: Fernández, Angel G.; Cabeza, Luisa F.;

Corrosion evaluation of eutectic chloride molten salt for new generation of CSP plants. Part 1: Thermal treatment assessment

Abstract

The operating temperature of a steam turbine is limited to 565 ºC by the molten nitrate heat-transfer fluid; therefore, a new molten salt chemistry is needed to increase the maximum operating temperature in the new generation of CSP plants and improve the thermal-to-electrical energy conversion efficiency in the turbine block, such as chloride molten salts. Nevertheless, the prevention of high-temperature corrosion on containment materials using chlorides plays a critical role and a corrosion mitigation plan is needed to achieve the target plant lifetime of 30 years. This paper presents a corrosion mitigation strategy focused on different thermal treatments performed in the eutectic ternary chloride molten salt composed by MgCl2/NaCl/KCl (55.1 wt.%/24.5 wt. %/20.4 wt.%). Corrosion rates were obtained through linear polarization resistance technique in a conventional commercial stainless steel (AISI 304) at 720 ºC during 5 h of immersion after the different thermal treatments carried out. Scanning electron microscopy and XRD analysis were used to confirm the corrosion rates and corrosion layer proposed by electrochemical techniques, obtaining a minimum corrosion rate of 6.033 mm/year for the best thermal treatment performed. Angel G. Fernández wants to acknowledge the financial support from the European Union's Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant No 712949 (TECNIOspring PLUS) and from the Agency for Business Competitiveness of the Government of Catalonia. This work was partially funded by the Ministerio de Ciencia, Innovación y Universidades de España (RTI2018-093849-B-C31). The authors would like to thank the Catalan Government for the quality accreditation given to their research group GREiA (2017 SGR 1537). GREiA is a certified agent TECNIO in the category of technology developers from the Government of Catalonia. This work is partially supported by ICREA under the ICREA Academia programme.

Country
Spain
Keywords

Corrosion mitigation, Chloride molten salt, Thermal energy storage, Thermal purification treatment, Concentrated solar power

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
59
Top 1%
Top 10%
Top 1%
Green
hybrid