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Abstract It has been estimated that the world's consumption of Liquefied Natural Gas (LNG) will increase significantly over the next 20 years, thus making exergy recovery from the regasification process a fundamental issue. When LNG is regasified in order to distribute the fuel through a pipeline network, a large amount of exergy is released. Three combined cycle schemes for energy generation have been analysed in this paper: the first one is a direct expansion cycle, combined with a Rankine cycle, the second one presents a double expansion with reheating and a recovery heat exchanger, and the last one shows two parallel Rankine cycles working under different turbine pressures. The performance of the three cycles has been compared, and the effects of using working fluids with different characteristics have been analysed in detail. Twelve working fluids were selected, according to their thermodynamic, ambient and safety proprieties. The working pressure and temperature that maximise the specific work have been found for each cycle and fluid.

Abstract It has been estimated that the world's consumption of Liquefied Natural Gas (LNG) will increase significantly over the next 20 years, thus making exergy recovery from the regasification process a fundamental issue. When LNG is regasified in order to distribute the fuel through a pipeline network, a large amount of exergy is released. Three combined cycle schemes for energy generation have been analysed in this paper: the first one is a direct expansion cycle, combined with a Rankine cycle, the second one presents a double expansion with reheating and a recovery heat exchanger, and the last one shows two parallel Rankine cycles working under different turbine pressures. The performance of the three cycles has been compared, and the effects of using working fluids with different characteristics have been analysed in detail. Twelve working fluids were selected, according to their thermodynamic, ambient and safety proprieties. The working pressure and temperature that maximise the specific work have been found for each cycle and fluid.

Abstract The present paper explores the utilisation of dopants to increase the critical temperature of Carbon Dioxide (sCO2) as a solution towards maintaining the high thermal efficiencies of sCO2 cycles even when ambient temperatures compromise their feasibility. To this end, the impact of adopting CO2-based mixtures on the performance of power blocks representative of Concentrated Solar Power plants is explored, considering two possible dopants: hexafluorobenzene (C6F6) and titanium tetrachloride (TiCl4). The analysis is applied to a well-known cycle -Recuperated Rankine- and a less common layout -Precompression-. The latter is found capable of fully exploiting the interesting features of these non-conventional working fluids, enabling thermal efficiencies up to 2.3% higher than the simple recuperative configuration. Different scenarios for maximum cycle pressure (250–300 bar), turbine inlet temperature (550–700 ° C) and working fluid composition (10–25% molar fraction of dopant) are considered. The results in this work show that CO2-blends with 15–25%(v) of the cited dopants enable efficiencies well in excess of 50% for minimum cycle temperatures as high as 50 ° C. To verify this potential gain, the most representative pure sCO2 cycles have been optimised at two minimum cycle temperatures (32 ° C and 50 ° C), proving the superiority of the proposed blended technology in high ambient temperature applications.

Abstract The present paper explores the utilisation of dopants to increase the critical temperature of Carbon Dioxide (sCO2) as a solution towards maintaining the high thermal efficiencies of sCO2 cycles even when ambient temperatures compromise their feasibility. To this end, the impact of adopting CO2-based mixtures on the performance of power blocks representative of Concentrated Solar Power plants is explored, considering two possible dopants: hexafluorobenzene (C6F6) and titanium tetrachloride (TiCl4). The analysis is applied to a well-known cycle -Recuperated Rankine- and a less common layout -Precompression-. The latter is found capable of fully exploiting the interesting features of these non-conventional working fluids, enabling thermal efficiencies up to 2.3% higher than the simple recuperative configuration. Different scenarios for maximum cycle pressure (250–300 bar), turbine inlet temperature (550–700 ° C) and working fluid composition (10–25% molar fraction of dopant) are considered. The results in this work show that CO2-blends with 15–25%(v) of the cited dopants enable efficiencies well in excess of 50% for minimum cycle temperatures as high as 50 ° C. To verify this potential gain, the most representative pure sCO2 cycles have been optimised at two minimum cycle temperatures (32 ° C and 50 ° C), proving the superiority of the proposed blended technology in high ambient temperature applications.

Abstract This paper proposes a novel approach in order to accurately calculate the savings due to heat metering. The approach is based on a detailed dynamic simulation of building-plant systems. The building is geometrically modelled in Google Sketchup and linked to the TRNSYS environment, including an extremely detailed model for the simulation of building thermo-physical behavior. All the models are validated using the data provided by the occupants. The model allows one to evaluate the yearly energy demand, energy supplied by radiators, heat gains, etc. A specific case study is developed for a residential building located in Naples (South Italy). The developed model is used to calculate the building energy demand for 3 scenarios: centralized heating system not equipped with heat metering; centralized heating system with thermostatic valves and not equipped with heat metering; centralized heating system with thermostatic valves and equipped with heat metering. Results show that in case of centralized heating systems equipped with thermostatic valves and heat metering devices, thermal energy savings up to 64% can be reached mainly when the system operates for many hours per day, leading to discounted pay back periods lower than 4 years.

Abstract This paper proposes a novel approach in order to accurately calculate the savings due to heat metering. The approach is based on a detailed dynamic simulation of building-plant systems. The building is geometrically modelled in Google Sketchup and linked to the TRNSYS environment, including an extremely detailed model for the simulation of building thermo-physical behavior. All the models are validated using the data provided by the occupants. The model allows one to evaluate the yearly energy demand, energy supplied by radiators, heat gains, etc. A specific case study is developed for a residential building located in Naples (South Italy). The developed model is used to calculate the building energy demand for 3 scenarios: centralized heating system not equipped with heat metering; centralized heating system with thermostatic valves and not equipped with heat metering; centralized heating system with thermostatic valves and equipped with heat metering. Results show that in case of centralized heating systems equipped with thermostatic valves and heat metering devices, thermal energy savings up to 64% can be reached mainly when the system operates for many hours per day, leading to discounted pay back periods lower than 4 years.

Abstract The paper investigates different control strategies for the thermal storage management in SHC (Solar Heating and Cooling) systems. The SHC system under investigation is based on a field of evacuated solar collectors coupled with a single-stage LiBr–H 2 O absorption chiller; auxiliary thermal energy is supplied by a gas-fired boiler. The SHC is also equipped with a novel thermal storage system, consisting in a variable volume storage tank. It includes three separate tanks and a number of mixers and diverters managed by novel control strategies, based on combinations of series/parallel charging and discharging approaches. The aim of this component is to vary the thermal storage capacity as a function of the combinations of solar radiation availability and user thermal/cooling energy demands. The system allows one to increase the number of active tanks when the time shift between solar energy and user demand is high. Conversely, when this time shift is low, the number of active tanks is automatically reduced. In addition, when the solar energy in excess cannot be stored in such tanks, a heat exchanger is also used in the solar loop for producing DHW (Domestic Hot Water). The analysis is carried out by means of a zero-dimensional transient simulation model, developed by using the TRNSYS software. In order to assess the operating and capital costs of the systems under analysis, an economic model is also proposed. In addition, in order to determine the set of the synthesis/design variables which maximize the system profitability, a parametric analysis was implemented. The novel variable-volume storage system, in both the proposed configurations, was also compared with a constant-volume storage system from the energy and economic points of view. The results showed that the presented storage system allows one to save up to 20% of the natural gas used by the auxiliary boiler only for very high solar fractions. In all the other cases, marginal savings are achieved by the variable-volume storage tanks system.

Abstract The paper investigates different control strategies for the thermal storage management in SHC (Solar Heating and Cooling) systems. The SHC system under investigation is based on a field of evacuated solar collectors coupled with a single-stage LiBr–H 2 O absorption chiller; auxiliary thermal energy is supplied by a gas-fired boiler. The SHC is also equipped with a novel thermal storage system, consisting in a variable volume storage tank. It includes three separate tanks and a number of mixers and diverters managed by novel control strategies, based on combinations of series/parallel charging and discharging approaches. The aim of this component is to vary the thermal storage capacity as a function of the combinations of solar radiation availability and user thermal/cooling energy demands. The system allows one to increase the number of active tanks when the time shift between solar energy and user demand is high. Conversely, when this time shift is low, the number of active tanks is automatically reduced. In addition, when the solar energy in excess cannot be stored in such tanks, a heat exchanger is also used in the solar loop for producing DHW (Domestic Hot Water). The analysis is carried out by means of a zero-dimensional transient simulation model, developed by using the TRNSYS software. In order to assess the operating and capital costs of the systems under analysis, an economic model is also proposed. In addition, in order to determine the set of the synthesis/design variables which maximize the system profitability, a parametric analysis was implemented. The novel variable-volume storage system, in both the proposed configurations, was also compared with a constant-volume storage system from the energy and economic points of view. The results showed that the presented storage system allows one to save up to 20% of the natural gas used by the auxiliary boiler only for very high solar fractions. In all the other cases, marginal savings are achieved by the variable-volume storage tanks system.