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Abstract The kinetics of methane hydrate decomposition was studied using a semibatch stirred-tank reactor. The decomposition was accomplished by reducing the pressure on a hydrate slurry in water to a value below the three-phase equilibrium pressure at the reactor temperature. The data were obtained at temperatures from 274 to 283 K and pressures from 0.17 to 6.97 MPa. The stirring rates were high enough to eliminate mass-transfer effects. Analysis of the data indicated that the decomposition rate was proportional to the particle surface area and to the difference in the fugacity of methane at the equilibrium pressure and the decomposition pressure. The proportionality constant showed an Arrhenius temperature dependence. An estimate of the hydrate particle diameters in the experiments permitted the development of an intrinsic model for the kinetics of hydrate decomposition.

Abstract The kinetics of methane hydrate decomposition was studied using a semibatch stirred-tank reactor. The decomposition was accomplished by reducing the pressure on a hydrate slurry in water to a value below the three-phase equilibrium pressure at the reactor temperature. The data were obtained at temperatures from 274 to 283 K and pressures from 0.17 to 6.97 MPa. The stirring rates were high enough to eliminate mass-transfer effects. Analysis of the data indicated that the decomposition rate was proportional to the particle surface area and to the difference in the fugacity of methane at the equilibrium pressure and the decomposition pressure. The proportionality constant showed an Arrhenius temperature dependence. An estimate of the hydrate particle diameters in the experiments permitted the development of an intrinsic model for the kinetics of hydrate decomposition.

Transport is an important source of air pollution and greenhouse gas emissions. Although the applications of information and communication technologies (ICTs) for transport, also known as intelligent transport systems, are seen as having great potential to help reduce emissions from road transport, their exact impact on CO2 emissions are uncertain for decision makers from government to industry. This uncertainty hinders the deployment of such applications. Therefore there is a need for a common evaluation approach to assess the CO2 impact of ICT measures in a systemic and realistic way. In this study, a methodology framework to evaluate the impact of ICT measures on CO2 emissions is explained. The methodology was developed within the European Union FP7 project Amitran. In particular, this study focuses on the outline and the framework architecture of the methodology as well as the required interfaces between the required models. The use of the methodology is demonstrated by applying it to a use case of dynamic traffic light systems. Finally, the efforts made to validate the methodology and make it accessible to users are explained.

Transport is an important source of air pollution and greenhouse gas emissions. Although the applications of information and communication technologies (ICTs) for transport, also known as intelligent transport systems, are seen as having great potential to help reduce emissions from road transport, their exact impact on CO2 emissions are uncertain for decision makers from government to industry. This uncertainty hinders the deployment of such applications. Therefore there is a need for a common evaluation approach to assess the CO2 impact of ICT measures in a systemic and realistic way. In this study, a methodology framework to evaluate the impact of ICT measures on CO2 emissions is explained. The methodology was developed within the European Union FP7 project Amitran. In particular, this study focuses on the outline and the framework architecture of the methodology as well as the required interfaces between the required models. The use of the methodology is demonstrated by applying it to a use case of dynamic traffic light systems. Finally, the efforts made to validate the methodology and make it accessible to users are explained.

Abstract Cost-effectively decarbonising the power sector and household energy use using variable renewable energy will require that electricity consumption becomes much more flexible and responsive to constraints in supply and the distribution network. In recent years residential demand response (DR) has received increasing attention that has sought to answer, based on current evidence, questions about how much consumers will engage with DR. This paper critically reviews the evidence base for residential consumer engagement with DR and draws out several important limitations in it. We argue for a more action-oriented focus on developing practical strategies to enable and unlock greater loadshifting and consumer engagement with DR within a changing technology and regulatory context. A number of recommendations are put forward for accelerating UK consumer engagement with DR, presented under three broad strategies: (a) promote awareness of smart tariffs, smart meters and storage and automation behind-the-meter devices as mutually-supportive components within a common ‘DR technology cluster’; (b) deliver targeted support for adoption of electric vehicles and other storage and automation technologies; (c) enable and support informed adoption of DR-enabling products and services through ‘smarter’ digital comparison tools (DCTs), data portability, and faster, simpler switching. The interdependency between components within this DR technology cluster delivers efficiency but also poses a risk that one delayed component (e.g., smart metering) will hold-up policy and industry support for other components. The urgency of decarbonisation goals makes it necessary to push forward as many of these elements as possible rather than the pace being set by the slowest.

Abstract Cost-effectively decarbonising the power sector and household energy use using variable renewable energy will require that electricity consumption becomes much more flexible and responsive to constraints in supply and the distribution network. In recent years residential demand response (DR) has received increasing attention that has sought to answer, based on current evidence, questions about how much consumers will engage with DR. This paper critically reviews the evidence base for residential consumer engagement with DR and draws out several important limitations in it. We argue for a more action-oriented focus on developing practical strategies to enable and unlock greater loadshifting and consumer engagement with DR within a changing technology and regulatory context. A number of recommendations are put forward for accelerating UK consumer engagement with DR, presented under three broad strategies: (a) promote awareness of smart tariffs, smart meters and storage and automation behind-the-meter devices as mutually-supportive components within a common ‘DR technology cluster’; (b) deliver targeted support for adoption of electric vehicles and other storage and automation technologies; (c) enable and support informed adoption of DR-enabling products and services through ‘smarter’ digital comparison tools (DCTs), data portability, and faster, simpler switching. The interdependency between components within this DR technology cluster delivers efficiency but also poses a risk that one delayed component (e.g., smart metering) will hold-up policy and industry support for other components. The urgency of decarbonisation goals makes it necessary to push forward as many of these elements as possible rather than the pace being set by the slowest.

In recent years, a ban on short-haul flights for which alternative, more environmentally friendly transportation is available has been on European regulatory agendas, particularly in countries like Germany, with its well-developed high-speed rail (HSR) and a dense network of low-cost, point-to-point airline traffic. This study aims to quantify the potential impact on CO2 emissions of substituting short-haul flights with rail frequencies in 87 German air travel corridors. Using OAG data on passenger bookings and airline schedules for 2019, as well as current rail travel times, we determine the target flights by looking at the actual proportion of connecting passengers per frequency. We estimate a potential reduction in CO2 emissions of between 2.7% and 22%, depending on how strict the flight substitution is. However, the social benefits of those carbon emissions might fall short of the travel time losses experienced by the passengers. Increased investment to improve rail speeds and intermodal accessibility appears necessary before the substitution policies can be implemented.