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Abstract Methane dry reforming with CO2 using FeO powder in molten salt has been investigated at various flow rates of CH4/CO2 mixed gases (CH4/CO2=1) between 50 and 400 ml/min at 1223 K in an infrared furnace. This work is carried out to determine the usefulness of this method for the chemical storage of solar energy. The CH4/CO2 mixed gases passing through the molten salt (Na2CO3/K2CO3=1) containing the FeO powder were catalytically decomposed into CO, H2 and H2O. The product gas mole ratios, CO/H2/H2O, were shown to be 3:1:1 for a high flow rate of 200 ml/min and to be CO/H2=2:1 for a low flow rate of 50 ml/min. The results were explained in terms of the kinetics of the CH4-reforming reaction and the thermodynamics of the redox process of FeO powder mixed in the molten salt; CH 4 +2FeO⇒2Fe+H 2 +CO+H 2 O Fe+CO 2 ⇒FeO+CO for a high flow rate, and FeO+CH 4 ⇒Fe+2H 2 +CO Fe+CO 2 ⇒FeO+CO for a low flow rate.

Abstract Methane dry reforming with CO2 using FeO powder in molten salt has been investigated at various flow rates of CH4/CO2 mixed gases (CH4/CO2=1) between 50 and 400 ml/min at 1223 K in an infrared furnace. This work is carried out to determine the usefulness of this method for the chemical storage of solar energy. The CH4/CO2 mixed gases passing through the molten salt (Na2CO3/K2CO3=1) containing the FeO powder were catalytically decomposed into CO, H2 and H2O. The product gas mole ratios, CO/H2/H2O, were shown to be 3:1:1 for a high flow rate of 200 ml/min and to be CO/H2=2:1 for a low flow rate of 50 ml/min. The results were explained in terms of the kinetics of the CH4-reforming reaction and the thermodynamics of the redox process of FeO powder mixed in the molten salt; CH 4 +2FeO⇒2Fe+H 2 +CO+H 2 O Fe+CO 2 ⇒FeO+CO for a high flow rate, and FeO+CH 4 ⇒Fe+2H 2 +CO Fe+CO 2 ⇒FeO+CO for a low flow rate.

Abstract An improved hybrid vacuum and pressure-assisted infiltration technique was developed for the infiltration of phase change materials (PCM) into the graphite foam matrix. A single chamber with no moving part infiltration setup was designed and fabricated. Pelletized PCM was introduced to provide enough porosity for air removal using vacuum pumps with no need for transfer PCM after melting and infiltration. Simple design, the use of stainless steel, and the corrosion resistance feature of PCM provides a very cost-effective design and easily controllable process. Mixed alkali and alkaline chloride salts as PCM were infiltrated into the high porosity graphite foam to enhance the thermal conductivity of latent heat storage medium. Chloride based PCM with proven corrosion-resistant features, high energy storage density that enables storage and release of energy at nearly constant temperatures close to the melting temperature of 355 °C are used in this study, as an example. The composites of infiltrated graphite foam and chloride salt PCMs were studied using SEM, EDS microstructural analyses to determine the effectiveness of the infiltration process. An infiltration efficiency greater than 90% of the available porosity was achieved. The thermal conductivity of the infiltrated samples was analyzed using a laser Nano-flash thermal conductivity device. The thermal conductivity of the foam/PCM composite was shown to be larger by a factor greater than 40 times of pure chloride PCM (1–2 W/m-K). Low-cost infiltration with proven efficacy and repeatability of infiltrated PCM could be a breakthrough for 3rd generation of CSP plant applications with supercritical CO2 power cycles.

Abstract An improved hybrid vacuum and pressure-assisted infiltration technique was developed for the infiltration of phase change materials (PCM) into the graphite foam matrix. A single chamber with no moving part infiltration setup was designed and fabricated. Pelletized PCM was introduced to provide enough porosity for air removal using vacuum pumps with no need for transfer PCM after melting and infiltration. Simple design, the use of stainless steel, and the corrosion resistance feature of PCM provides a very cost-effective design and easily controllable process. Mixed alkali and alkaline chloride salts as PCM were infiltrated into the high porosity graphite foam to enhance the thermal conductivity of latent heat storage medium. Chloride based PCM with proven corrosion-resistant features, high energy storage density that enables storage and release of energy at nearly constant temperatures close to the melting temperature of 355 °C are used in this study, as an example. The composites of infiltrated graphite foam and chloride salt PCMs were studied using SEM, EDS microstructural analyses to determine the effectiveness of the infiltration process. An infiltration efficiency greater than 90% of the available porosity was achieved. The thermal conductivity of the infiltrated samples was analyzed using a laser Nano-flash thermal conductivity device. The thermal conductivity of the foam/PCM composite was shown to be larger by a factor greater than 40 times of pure chloride PCM (1–2 W/m-K). Low-cost infiltration with proven efficacy and repeatability of infiltrated PCM could be a breakthrough for 3rd generation of CSP plant applications with supercritical CO2 power cycles.

Abstract There are instances in remote areas where heat is being wasted, e.g., in internal combustion, engines, etc. Some of this heat can be recovered to produce distilled water in solar stills. The solar still replaces the cooling tower, ponds, or radiators normally used to control the engine temperature. The diesel cooling water in such a system remains separate from the saline water in the solar still. The advantages of using such a system compared with a conventional solar still are: 1. (a) water costs are very much reduced 2. (b) the area occupied is much less, i.e., about 1 5 th 3. (c) production has much less seasonal variation 4. (d) the efficiency of the solar still is improved due to the higher operating temperatures. From experiments conducted at Highett using a Mk VI solar still fitted with a simple heat exchanger and a separate electrically-heated source of hot water to simulate the waste heat, design data are not available for application to working systems. The information required to match a solar still to a diesel's cooling requirement is: 1. (a) engine efficiency 2. (b) hourly fuel consumption 3. (c) hourly solar radiation 4. (d) hourly ambient temperatures. A by-product of this work has been the production of a “solar water heater” which costs less than that of the cheapest conventional system. This “solar” hot water system uses a heat exchanger similar to what is used to transfer the waste heat to the saline water. It is envisaged to have hot water productions approximately the same as the distilled water productions. The influence of hot water production on the output of the waste heat solar still is discussed.

Abstract There are instances in remote areas where heat is being wasted, e.g., in internal combustion, engines, etc. Some of this heat can be recovered to produce distilled water in solar stills. The solar still replaces the cooling tower, ponds, or radiators normally used to control the engine temperature. The diesel cooling water in such a system remains separate from the saline water in the solar still. The advantages of using such a system compared with a conventional solar still are: 1. (a) water costs are very much reduced 2. (b) the area occupied is much less, i.e., about 1 5 th 3. (c) production has much less seasonal variation 4. (d) the efficiency of the solar still is improved due to the higher operating temperatures. From experiments conducted at Highett using a Mk VI solar still fitted with a simple heat exchanger and a separate electrically-heated source of hot water to simulate the waste heat, design data are not available for application to working systems. The information required to match a solar still to a diesel's cooling requirement is: 1. (a) engine efficiency 2. (b) hourly fuel consumption 3. (c) hourly solar radiation 4. (d) hourly ambient temperatures. A by-product of this work has been the production of a “solar water heater” which costs less than that of the cheapest conventional system. This “solar” hot water system uses a heat exchanger similar to what is used to transfer the waste heat to the saline water. It is envisaged to have hot water productions approximately the same as the distilled water productions. The influence of hot water production on the output of the waste heat solar still is discussed.

Abstract In this work we review and recalibrate existing models, and present a novel comprehensive model for estimation of the downward atmospheric longwave (LW) radiation for clear and cloudy sky conditions. LW radiation is an essential component of thermal balances in the atmosphere, playing also a substantial role in the design and operation of solar power plants. Unlike solar irradiance, LW irradiance is not measured routinely by meteorological or solar irradiance sensor networks. In most cases, it must be calculated indirectly from meteorological variables using simple parametric models. Under clear skies, fifteen parametric models for calculating LW irradiance are compared and recalibrated. All models achieve higher accuracy after grid search recalibration, and we show that many of the previously proposed LW models collapse into only a few different families of models. A recalibrated Brunt-family model is recommended for future use due to its simplicity and high accuracy (rRMSE = 4.37%). To account for the difference in nighttime and daytime clear-sky emissivities, nighttime and daytime Brunt-type models are proposed. Under all sky conditions, the information of clouds is represented by cloud cover fraction (CF) or cloud modification factor (CMF, available only during daytime). Three parametric models proposed in the bibliography are compared and calibrated, and a new model is proposed to account for the alternation of vertical atmosphere profile by clouds. The proposed all-sky model has 3.8–31.8% lower RMSEs than the other three recalibrated models. If GHI irradiance measurements are available, using CMF as a parameter yields 7.5% lower RMSEs than using CF. For different applications that require LW information during daytime and/or nighttime, coefficients of the proposed models are corrected for diurnal and nocturnal use.