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Abstract. The impact of multiphase reactions involving nitrogen dioxide (NO2) and aromatic compounds was simulated in this study. A mechanism (CAPRAM 2.4, MODAC Mechanism) was applied for the aqueous phase reactions, whereas RACM was applied for the gas phase chemistry. Liquid droplets were considered as monodispersed with a mean radius of 0.1 µm and a liquid content (LC) of 50 µg m-3. The multiphase mechanism has been further extended to the chemistry of aromatics, i.e. reactions involving benzene, toluene, xylene, phenol and cresol have been added. In addition, reaction of NO2 with dissociated hydroxyl substituted aromatic compounds has also been implemented. These reactions proceed through charge exchange leading to nitrite ions and therefore to nitrous acid formation. The strength of this source was explored under urban polluted conditions. It was shown that it may increase gas phase HONO levels under some conditions and that the extent of this effect is strongly pH dependent. Especially under moderate acidic conditions (i.e. pH above 4) this source may represent more than 75% of the total HONO/NO2 - production rate, but this contribution drops down close to zero in acidic droplets (as those often encountered in urban environments).

AbstractThe concept of a ‘just transition’ to a low‐carbon economy is firmly embedded in mainstream global discourses about mitigating climate change. Drawing on Karl Polanyi's political economy elaborated inThe Great Transformation, we interrogate the idea of a just transition and place it within its historical context. We address a major contradiction at the core of global energy transition debates: the rapid shift to low‐carbon energy‐systems will require increased extraction of minerals and metals. In doing so, we argue that extractive industries are energy and carbon‐intensive, and will enlarge and intensify social and ecological injustice. Our findings reveal the importance of understanding how the idea of a just transition is used, and by who, and the type of justice that underpins this concept. We demonstrate the need to ground just transition policies and programmes in a notion of justice as fairness.

Datacenter power demand has been continuously growing and is the key driver of its cost. An accurate mapping of compute resources (CPU, RAM, etc.) and hardware types (servers, accelerators, etc.) to power consumption has emerged as a critical requirement for major Web and cloud service providers. With the global growth in datacenter capacity and associated power consumption, such models are essential for important decisions around datacenter design and operation. In this paper, we discuss two classes of statistical power models designed and validated to be accurate, simple, interpretable and applicable to all hardware configurations and workloads across hyperscale datacenters of Google fleet. To the best of our knowledge, this is the largest scale power modeling study of this kind, in both the scope of diverse datacenter planning and real-time management use cases, as well as the variety of hardware configurations and workload types used for modeling and validation. We demonstrate that the proposed statistical modeling techniques, while simple and scalable, predict power with less than 5% Mean Absolute Percent Error (MAPE) for more than 95% diverse Power Distribution Units (more than 2000) using only 4 features. This performance matches the reported accuracy of the previous started-of-the-art methods, while using significantly less features and covering a wider range of use cases.

Societal relations in rural areas have entered into a new stage of adjustment over the past decade. However, the adjustment, which might bring about profound societal changes in countryside as well as in China as a whole, have not been paid much attention and very few studies have been conducted from the perspective of ecological resource crises. We use the case of a village as an example to show how water pollution, as one of the contributory factors, possibly affect the transition of clans and societal changes in Chinese villages. Through observation and interviews, we find that there is an apparent rise of “New Clanism” within clans, which gradually abandons the tradition of supremacy of clan interests and places family or individual interests at top priority. We also find that clan boundaries get increasingly obscure since the integrity of clans is undermined by the rise of new interest groups across clans, but the boundaries remain relatively clear due to the consistency (albeit incomplete) of clan interests. Some new clan élites and representatives of new interest groups get involved in village governance, which indicates that their goals have shifted from natural resources to social or political capital. The significance of our findings is that they provide not only a unique perspective for the interaction between society and resources, but also some new ideas for the future study of rural China at the environment-social interface.

A specific role for the HTGR in a national energy strategy is examined. The issue is addressed in two ways. First, the role of the HTGR-GT Binary cycle plant is examined in a national energy strategy based on symbiosis between fast breeder and advanced converter reactors utilizing the thorium U233 fuel cycle. Second, the advantages of the HTGR-GT dry-cooled plant operating in arid regions is examined and compared with a dry-cooled LWR. An event tree analysis of potential benefits is applied.

For lithium–sulfur batteries, 3D cathodes might be of interest for containing the active material and trapping the polysulfides during cycling, owing to their binder-free and freestanding features. In this work, the MoS2 grown on the 3D structured Carbon Cloth (CC@MoS2) is firstly used to fabricate the Li–S battery and the sulfur loading can be freely tuned by adjusting thermal annealing time at 200 °C. A two-step melt-diffusion strategy is reported for fabrication of cathodes, which involves in melting and diffusion of sulfur covered by CC@MoS2 composites instead of dissolution of sulfur in the toxic organic solvents. Compared with the non-polar carbon cloth, the CC@MoS2 composites exhibit better adsorption capacity for polysulfides due to more edge active sites, which could effectively facilitate polysulfide redox kinetics. The SEM images of the CC@MoS2 cathode after 300 cycles show that MoS2 can still maintain the nanosheet morphology. After 300 cycles at 0.5 C, the CC@MoS2 cathodes loaded with 2 mg sulfur exhibit a better reversible capacity of 698 mA h g−1 compared with CC@MoS2 loaded with 1 mg sulfur (604 mA h g−1) and CC@MoS2 loaded with 4 mg sulfur (420 mA h g−1). This work proposes an environmentally friendly method to fabricate the lithium–sulfur battery cathode material and the sulfur loading can be freely adjusted.