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Abstract The reverse flat-plate collector is a non-concentrating collector. It can collect solar heat at high temperatures which cannot be achieved by conventional non-concentrating collectors. In this paper, the authors have proposed a number of modified versions of the originally proposed reverse flat-plate collector. The new designs are of single, as well as double, absorber type. The thermal performance of these modified reverse flat-plate collectors is compared with that of a single absorber reverse flat-plate collector, as well as with the corresponding normal flat-plate collector. It is found that the new design having two absorbers gives the best thermal performance as compared with other configurations. The analytical models presented in this paper very well describe the experimental results.

Abstract In this work addition of ethanol to high viscosity jatropha methyl ester (JME) through port injection is investigated in order to determine its effect fuel viscosity reduction on diesel engine performance. In addition to viscosity alteration, the impact of ethanol addition on combustion characteristics such as combustion duration, ignition delay and emissions levels from diesel engines fuelled with blends of ethanol, diesel and JME is studied in particular. It is found that blending of oxygenated fuels with diesel modifies the chemical structure and physical properties which again alter the engine operating conditions, combustion parameters and emissions levels. However, the injection of only 5% ethanol through port injection allows for a total of 25% blending of biofuels into diesel yet keeping the fuel characteristics close to that of conventional diesel. However, both experimental and numerical results show that ethanol addition in JME blended diesel results in a slight increase in fuel consumption and thermal efficiency for the same power outputs as that of conventional diesel fuel. Also, the combustion characteristics with ethanol addition include improved maximum in-cylinder peak pressure, cumulative heat release (CHR) rate of heat release (ROHR), in-cylinder peak temperature and combustion duration. Regarding emission characteristics the experimental results show significant reduction in smoke, carbon monoxide (CO) and total hydrocarbon (THC) emissions with extended oxygen mass percentage in the fuel at higher engine loads. However, oxides of nitrogen (NOx) emissions are found to increase at high loads although the common tradeoff between smoke and NOx is found to be more prominent for the oxygenated fuels.

In this study, levulinic acid (LA) was produced from rice straw biomass in co-solvent biphasic reactor system consisting of hydrochloric acid and dichloromethane organic solvent. The modified protocol achieved a 15% wt LA yield through the synergistic effect of acid and acidic products (auto-catalysis) and the designed system allowed facile recovery of LA to the organic phase. Further purification of the resulting extractant was achieved through traditional column chromatography, which yielded a high purity LA product while recovering ∼85% wt. Upon charcoal treatment of the resultant fraction generated an industrial grade target molecule of ∼99% purity with ∼95% wt recovery. The system allows the solvent to be easily recovered, in excess of 90%, which was shown to be able to be recycled up to 5 runs without significant loss of final product concentrations. Overall, this system points to a method to significantly reduce manufacturing cost during large-scale LA preparation.

Abstract A CFD modelling study has been undertaken to examine the co-firing of pulverised coal and biomass with particular regard to the burnout of the larger diameter biomass particles. Computations were based on a research combustion facility that replicates an industrial coal-fired power station. Three percent, by mass, of pinewood was blended with a bituminous UK coal, and the effects of the wood particle size and shape on the burnout of the combined wood and coal char were investigated. The effect of varying the devolatilisation and char combustion rate constants for the biomass component in the blend was also investigated. It was concluded that the combustion of small (200 μm) wood particles was rapid but the rate of combustion of larger particles was dependent on their composition, size, and shape.

The Severn Estuary has the world's second largest tide range and a barrage across the estuary, located just seawards of Cardiff in Wales and Weston in the South West England, has been proposed for over half a century, with the objective of extracting large amounts of tidal energy. A Severn Barrage, as previously proposed by the Severn Tidal Power Group (STPG), would be the largest renewable energy project for tidal power generation in the world, if built as proposed, and would generate approximately 5% of the UK's electricity needs. However, concerns have been raised over the environmental impacts of such a barrage, including potential increase in flood risk, loss of intertidal habitats etc. In addressing the challenges of maximizing the energy output and minimizing the environmental impacts of such a barrage, this research study has focused on using a Continental Shelf model, based on the modified Environmental Fluid Dynamics Code (EFDC) with a barrage operation module (EFDC_B), to investigate both the far and near field hydrodynamic impacts of a barrage for different operating scenarios. Three scenarios have been considered to simulate the Severn Barrage, operating via two-way generation and using different combinations of turbines and sluices. The first scenario consisted of 216 turbines and 166 sluices installed along the barrage; the second consisted of 382 turbines with no sluices; and the third consisted of 764 turbines and no sluices. The specification of the sluice gates and turbines are the same for all scenarios. The model results indicate that the third scenario has the best mitigating effects for the far-field and near-field flood risks caused by a barrage and produces the most similar results of minimum water depth and maximum velocity distributions to those obtained from simulating the natural conditions of the estuary, i.e. the current conditions. The results also show that the flow patterns around the barrage are closest to those for the existing natural conditions with minimal slight changes in the estuary. Thus, the results clearly indicate that the environmental impacts of a Severn Barrage can be minimized if the barrage is operated for two-way generation and under the third scenario. Although it appears that the energy output for the third scenario is less than that obtained for the other two scenarios, if very low head (VLH) turbines are used, then the third scenario could generate more energy as more turbines could be cited along the barrage structure. Therefore, the study shows that a Severn Barrage, operating in two-way generation and with 764 turbines (ideally VLH turbines), would be the best option to meet the needs of maximizing the energy output, but having a minimal impact on environmental changes in the estuary and far-field.

Abstract This paper aims to present a feasibility study of the innovative plant for methanol synthesis from carbon dioxide-sequestered by fossil fuel power plant and hydrogen, which is produced by water electrolyzer employing the over-production on the electrical grid. The thermo-economic analysis is performed in the framework of the MefCO2 H2020 EU project and it is referred to the German economic scenario, properly taking into account the real market costs and cost functions for different components of the plant. Three different plant capacities for methanol production (4000 10,000 and 50,000 ton/year) have been investigated, assuming an average cost for electrical energy to feed electrolysers and analyzing the influence of the most significant parameters (oxygen selling option, methanol selling price and electrolysers’ capital cost) on the profitability of the plant. The analysis has been performed in W-ECoMP, software for the thermo-economic analysis and plant optimization developed by the University of Genoa.

Abstract The present work attempts to devise an efficient method utilizing an on-grid photovoltaic-thermal heat pump water heater (PV-THPWH) integrated with a real-time variable frequency controller to achieve the goal of energy-efficient buildings. The prime focus is to reduce the grid's dependence on the compressor's energy-intensive operation by employing a feedback-controlled variable frequency drive (VFD). Additionally, the possibilities involved with addressing the electrical and thermal energy requirements of an energy-efficient building was investigated utilizing the proposed system. R-32 refrigerant in the photovoltaic-thermal (PV-T) evaporator coils of the heat pump assembly help to cool the photovoltaic (PV) panel while delivering the absorbed heat in the condenser to heat water contained inside the storage tank. Outdoor experiments and theoretical investigations of the combined system were carried out to appraise the dynamic behavior under varying solar irradiation and ambient temperature conditions. The observations conveyed that the PV-THPWH system succeeded in reducing the PV panel operating temperature by 25%, which resulted in a 20% increment in PV power output. Also, the performance indicators, such as the instantaneous energy efficiency and instantaneous PV efficiency, were found to increase by 15% and 34%, respectively, resulting in an average coefficient of performance of 6.4. For a clear sky day, the recorded total PV energy output was 4.67 units, while the VFD compressor consumption was 3.42 units, and the surplus 1.25 units were sent to the grid. Furthermore, the economic analysis reported a payback period of 2.3 years for the developed PV-THPWH system.

Abstract The rapid increase in energy demand and the limited resources of fossil fuel as well as the environmentally damaging effects, drive the world to find new options for sustainable electricity generation, which is represented by renewable energies. Concentrating solar power (CSP) is one of the most promising technologies in the field of electricity generation to tackle this issue with a competitive cost in the future. This paper presents an investigation of the potential of implementation of CSP plants in Libya. The socio-economic context, current energy situation of the country and different types of CSP plants are discussed. Moreover, an assessment of site parameters required for CSP plants including solar resources, land use and topography, water resources and grid connections are investigated in detail. In addition, thermo-economic simulation of a 50 MW parabolic trough power plant is performed. The simulation is conducted based on meteorological data measured by the weather station installed at the Centre for Solar Energy Research and Studies (CSERS) in Tajoura city. The performance results are compared with the reference plant Andasol-1 in Spain. Even though the proposed plant is located on the North coast where solar resources are at their minimum compared with other regions of the country, the outcome of the study proves that Libya is not only suitable but it can be economically competitive in the implementation of CSP technology.

Abstract Gold nanoparticles (Au-NPs) seeded plasmonic nanofluids (PNFs) have shown promising results in overall performance enhancement of direct absorption solar collector (DASC) due to localized surface plasmon resonance (LSPR) effect. For the work presented here, Au-NPs were synthesized by the wet chemical method and were utilized to prepare plasmonic nanofluid. The surface plasmon resonance peak of Au-NPs was observed at 531 nm using UV–Visible spectrophotometer study. The testing for performance enhancement of gold plasmonic nanofluid (GPNF) laden DASC so far is limited to laboratory scale setups or simulation studies. Considering the dearth of outdoor experimental studies, an attempt has been made in the present study to evaluate the thermal performance of Au-NPs (∼40 nm) based nanofluid (∼0.0002 wt%) in full scale DASC. The experiments have been performed at different flow rates under clear sky outdoor conditions in winter season at Jalandhar, India. The maximum collector outlet temperature was measured to be 55 °C with GPNF which is about 7 °C higher than the maximum outlet temperature obtained with de-ionized water as working fluid. Thermal efficiency with GPNF is about 33% higher than de-ionized water at the optimal flow rate of 0.030 kg/s.