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This study highlights how Chinese economic development detrimentally impacted water quality in recent decades and how this has been improved by enormous investment in environmental remediation funded by the Chinese government. To our knowledge, this study is the first to describe the variability of surface water quality in inland waters in China, the affecting drivers behind the changes, and how the government-financed conservation actions have impacted water quality. Water quality was found to be poorest in the North and the Northeast China Plain where there is greater coverage of developed land (cities + cropland), a higher gross domestic product (GDP), and higher population density. There are significant positive relationships between the concentration of the annual mean chemical oxygen demand (COD) and the percentage of developed land use (cities + cropland), GDP, and population density in the individual watersheds (p < 0.001). During the past decade, following Chinese government-financed investments in environmental restoration and reforestation, the water quality of Chinese inland waters has improved markedly, which is particularly evident from the significant and exponentially decreasing GDP-normalized COD and ammonium (NH4+-N) concentrations. It is evident that the increasing GDP in China over the past decade did not occur at the continued expense of its inland water ecosystems. This offers hope for the future, also for other industrializing countries, that with appropriate environmental investments a high GDP can be reached and maintained, while simultaneously preserving inland aquatic ecosystems, particularly through management of sewage discharge.

The influence of compost on the growth of bean plants irrigated with As-contaminated waters and its influence on the mobility of As in the soils and the uptake of As (as NaAs(III)O2) by plant components was studied at various compost application rates (3·10(4) and 6·10(4) kg ha(-1)) and at three As concentrations (1, 2 and 3 mg kg(-1)). The biomass and As and P concentrations of the roots, shoots and beans were determined at harvest time, as well as the chlorophyll content of the leaves and nonspecific and specifically bound As in the soil. The bean plants exposed to As showed typical phytotoxicity symptoms; no plants however died over the study. The biomass of the bean plants increased with the increasing amounts of compost added to the soil, attributed to the phytonutritive capacity of compost. Biomass decreased with increasing As concentrations, however, the reduction in the biomass was significantly lower with the addition of compost, indicating that the As phytotoxicity was alleviated by the compost. For the same As concentration, the As content of the roots, shoots and beans decreased with increasing compost added compared to the Control. This is due to partial immobilization of the As by the organic functional groups on the compost, either directly or through cation bridging. Most of the As adsorbed by the bean plants accumulated in the roots, while a scant allocation of As occurred in the beans. Hence, the addition of compost to soils could be used as an effective means to limit As accumulation in crops from As-contaminated waters.

Aiming to retard the self-polymerization of the reaction intermediates during bio-oil upgrading process, a large amount of alcohol (e.g., 50 wt% with respect to bio-oil) was used in the stabilization of fast pyrolysis oil by esterification before hydrotreatment by the authors in a previous work. In order to reduce the amount of alcohol use and hence improve the process economy, effects of stabilizing fast pyrolysis oil by esterification with methanol, ethanol or glycerol at a small loading (5 wt% w.r.t. bio-oil) in the presence of Amberlyst-35 DRY - A solid acid catalyst on the subsequent hydrotreatment of the oil were investigated. The bio-oil hydrotreatment experiments were carried out at 300 and 350 °C in a combined batch and semi-batch operation mode with Ru/C catalyst. The results demonstrated that, although stabilization of the pyrolysis oil by esterification with a small alcohol loading had least effects on the mass and carbon distribution in the hydrotreatment products and the elemental composition of the hydrotreated oil products, it could effectively reduce the molecular weight of the feed, prevent self-polymerization and decrease the overall molecular weight of the hydrotreated oil products.

Water quality agencies and scientists are increasingly adopting standardized sampling methodologies because of the challenges associated with interpreting data derived from dissimilar protocols. Here, we compare 13 protocols for monitoring streams from different regions and countries around the globe. Despite the spatially diverse range of countries assessed, many aspects of bioassessment structure and protocols were similar, thereby providing evidence of key characteristics that might be incorporated in a global sampling methodology. Similarities were found regarding sampler type, mesh size, sampling period, subsampling methods, and taxonomic resolution. Consistent field and laboratory methods are essential for merging data sets collected by multiple institutions to enable large-scale comparisons. We discuss the similarities and differences among protocols and present current trends and future recommendations for monitoring programs, especially for regions where large-scale protocols do not yet exist. We summarize the current state in one of these regions, Latin America, and comment on the possible development path for these techniques in this region. We conclude that several aspects of stream biomonitoring need additional performance evaluation (accuracy, precision, discriminatory power, relative costs), particularly when comparing targeted habitat (only the commonest habitat type) versus site-wide sampling (multiple habitat types), appropriate levels of sampling and processing effort, and standardized indicators to resolve dissimilarities among biomonitoring methods. Global issues such as climate change are creating an environment where there is an increasing need to have universally consistent data collection, processing and storage to enable large-scale trend analysis. Biomonitoring programs following standardized methods could aid international data sharing and interpretation.

Textile effluents are characterised by high content of recalcitrant compounds and are often discharged (together with municipal wastewater to increase their treatability) into centralized wastewater treatment plants with a complex treatment scheme. This paper reports the results achieved adopting a granular sludge system (sequencing batch biofilter granular reactor - SBBGR) to treat mixed municipal-textile wastewater. Thanks to high average removals in SBBGR (82.1% chemical oxygen demand, 94.7% total suspended solids, 87.5% total Kjeldahl nitrogen, 77.1% surfactants), the Italian limits for discharge into a water receiver can be complied with the biological stage alone. The comparison with the performance of the centralized plant treating the same wastewater has showed that SBBGR system is able to produce an effluent of comparable quality with a simpler treatment scheme, a much lower hydraulic residence time (11 h against 30 h) and a lower sludge production.

The reasons for the acidification problem affecting Food Waste (FW) anaerobic digestion were explored, combining the outcomes of microbiological data (FISH and CARD-FISH) and process modelling, based on the Anaerobic Digestion Model n°1 (ADM1). Long term semi continuous experiments were carried out, both with sole FW and with Waste Activated Sludge (WAS) as a co-substrate, at varying operational conditions (0.8-2.2 g VS L-1 d-1) and FW / WAS ratios. Acidification was observed along FW mono-digestion, making it necessary to buffer the digesters; ADM1 modelling and experimental results suggested that this phenomenon was due to the methanogenic activity decline, most likely related to a deficiency in trace elements. WAS addition, even at proportions as low as 10% of the organic load, settled the acidification issue; this ability was related to the promotion of the methanogenic activity and the consequent enhancement of acetate consumption, rather than to WAS buffering capacity. The ability of the ADM1 to model processes affected by low microbial activity, such as FW mono-digestion, was also assessed. It was observed that the ADM1 was only adequate for digestions with a high activity level for both bacteria and methanogens (FISH/CARD-FISH ratio preferably >0.8) and, under these conditions, the model was able to correctly predict the relative abundance of both microbial populations, extrapolated from FISH analysis.

Abstract Biogas production is increasing as a sustainable energy supply, with digestate resulting as a by-product of biogas plants. As a result, the high concentration of Clostridium spp. in digestate became a concern in dairy farming areas. Clostridium spores can contaminate soils and crops when digestate is used as fertilizer, causing a conflictual cohabitation of biogas with traditional cheese productions. In order to solve the problem, this study aimed to search for a technical solution enabling either a drastic reduction or the elimination of the content of Clostridium spp. within digestate. Results showed a complete elimination of Clostridium spp. in pelleted stored solid digestate; in addition, pelleting caused a reduction of pH and water mass fraction in terms of fresh weight, and a concentration of mineral nutrients compared to stored solid digestate. Pellet can represent a possible sustainable solution both in reducing potential risks linked to the presence of Clostridium spp. in digestate and in improving the transportation and distribution of high-value fertilizer. Hence, pelleting of solid digestate could offer a simple and efficient method to allow cohesistence of biogas plants and dairy farming.