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AbstractWe have investigated the spectroscopic properties (absorption spectra, emission spectra, emission lifetimes) of three triads in CH2Cl2: C2‐M‐C2, C343‐M‐C343, and C2‐M‐C343, in which M is a shape‐persistent macrocyclic hexagonal backbone composed of two 2,2′‐bipyridine (bpy) units embedded in opposing sides, and C2 and C343 are coumarin 2 and coumarin 343, respectively. All the components are strongly fluorescent species (Φ=0.90, 0.79, and 0.93 for M, C2, and C343, respectively, as established by investigating suitable model compounds). In each triad excitation of M leads to almost quantitative energy transfer to the lowest coumarin‐localised excited state. Upon addition of acid, the two bpy units of the M component undergo independent protonation leading to monoprotonated (e.g., C2‐M⋅H+‐C2) and diprotonated (e.g., C2‐M⋅2 H+‐C2) species. Further addition of acid leads to protonation of the coumarin component so that each triad is involved in four protonation equilibria. Protonation causes strong (and reversible, upon addition of base) changes in the absorption and fluorescence properties of the triads because of inversion of the excited‐state order and/or the occurrence of electron‐transfer quenching processes.

AbstractLand Surface Phenology (LSP) is the most direct representation of intra‐annual dynamics of vegetated land surfaces as observed from satellite imagery. LSP plays a key role in characterizing land‐surface fluxes, and is central to accurately parameterizing terrestrial biosphere–atmosphere interactions, as well as climate models. In this article, we present an evaluation of Pan‐European LSP and its changes over the past 30 years, using the longest continuous record of Normalized Difference Vegetation Index (NDVI) available to date in combination with a landscape‐based aggregation scheme. We used indicators of Start‐Of‐Season, End‐Of‐Season and Growing Season Length (SOS, EOS and GSL, respectively) for the period 1982–2011 to test for temporal trends in activity of terrestrial vegetation and their spatial distribution. We aggregated pixels into ecologically representative spatial units using the European Landscape Classification (LANMAP) and assessed the relative contribution of spring and autumn phenology. GSL increased significantly by 18–24 days decade−1 over 18–30% of the land area of Europe, depending on methodology. This trend varied extensively within and between climatic zones and landscape classes. The areas of greatest growing‐season lengthening were the Continental and Boreal zones, with hotspots concentrated in southern Fennoscandia, Western Russia and pockets of continental Europe. For the Atlantic and Steppic zones, we found an average shortening of the growing season with hotspots in Western France, the Po valley, and around the Caspian Sea. In many zones, changes in the NDVI‐derived end‐of‐season contributed more to the GSL trend than changes in spring green‐up, resulting in asymmetric trends. This underlines the importance of investigating senescence and its underlying processes more closely as a driver of LSP and global change.

AbstractDigitalization and sustainability have been the core drivers of transformation of the financial industry in recent years. In this context, green fintech plays a major role, which, however, is still an unexplored field in business, information systems and finance research. This paper conducts a systematic literature analysis and develops a research agenda based on a framework, which is derived from clustering 74 academic research papers. The framework consists of the four clusters strategy, organization, technology, and potentials along nine dimensions. The research agenda reveals that green fintech is still a very premature field of research. The analysis shows that areas like customer‐ and government‐related services, insurance‐oriented approaches and SDGs which focus on life on land and life below water are still rare and that most of the approaches focus on blockchain technology, while other financial technologies like artificial intelligence are still underrepresented.

Glacier and permafrost hazards in cold mountain regions encompass various flood and mass movement processes that are strongly affected by rapid and cumulative climate-induced changes in the alpine cryosphere. These processes are characterized by a range of spatial and temporal dimensions, from small volume icefalls and rockfalls that present a frequent but localized danger to less frequent but large magnitude process chains that can threaten people and infrastructure located far downstream. Glacial lake outburst floods (GLOFs) have proven particularly devastating, accounting for the most far-reaching disasters in high mountain regions globally. Comprehensive assessments of glacier and permafrost hazards define two core components (or outcomes): 1. Susceptibility and stability assessment: Identifies likelihood and origin of an event based on analyses of wide-ranging triggering and conditioning factors driven by interlinking atmospheric, cryospheric, geological, geomorphological, and hydrological processes. 2. Hazard mapping: Identifies the potential impact on downslope and downstream areas through a combination of process modeling and field mapping that provides the scientific basis for decision making and planning. Glacier and permafrost hazards gained prominence around the mid-20th century, especially following a series of major disasters in the Peruvian Andes, Alaska, and the Swiss Alps. At that time, related hazard assessments were reactionary and event-focused, aiming to understand the causes of the disasters and to reduce ongoing threats to communities. These disasters and others that followed, such as Kolka Karmadon in 2002, established the fundamental need to consider complex geosystems and cascading processes with their cumulative downstream impacts as one of the distinguishing principles of integrative glacier and permafrost hazard assessment. The widespread availability of satellite imagery enables a preemptive approach to hazard assessment, beginning with regional scale first-order susceptibility and hazard assessment and modeling that provide a first indication of possible unstable slopes or dangerous lakes and related cascading processes. Detailed field investigations and scenario-based hazard mapping can then be targeted to high-priority areas. In view of the rapidly changing mountain environment, leading beyond historical precedence, there is a clear need for future-oriented scenarios to be integrated into the hazard assessment that consider, for example, the threat from new lakes that are projected to emerge in a deglaciating landscape. In particular, low-probability events with extreme magnitudes are a challenge for authorities to plan for, but such events can be appropriately considered as a worst-case scenario in a comprehensive, forward-looking, multiscenario hazard assessment.

In October 2021, the government of Catamarca, a province located in Northern Argentina, announced the beginning of a consultation process to debate about a lithium mining project located in the Salar del Hombre Muerto. According to several laws and international treaties passed by Argentina, before any program, project or law that affect Indigenous peoples, their territories and resources, a Free Prior and Informed Consent (FPIC) consultation has to be held. In Argentina, the provinces are in charge of controlling all mining activities and carrying out consultation processes. However, in many cases the provinces have not upheld this right to consultation and local communities have regularly protested. Therefore, consultation processes often take place in conflictive scenarios. The aim of this Viewpoint is to illustrate, through an ethnographic approach, how concretely a consultation process around lithium mining was carried out in Catamarca. Our findings show that the fairness of this particular consultation process was compromised by limits imposed on access to transparent information and by barriers imposed to local participation. We conclude that in order to to move towards a fair energy transition it is imperative to address the vulnerability of local communities, to guarantee greater transparency of information about lithium projects, and to hold FPIC according to the spirit and the letter of international conventions. Fil: Clavijo Lara, Araceli Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones en Energía no Convencional. Universidad Nacional de Salta. Facultad de Ciencias Exactas. Departamento de Física. Instituto de Investigaciones en Energía no Convencional; Argentina Fil: Diaz Paz, Walter Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones en Energía no Convencional. Universidad Nacional de Salta. Facultad de Ciencias Exactas. Departamento de Física. Instituto de Investigaciones en Energía no Convencional; Argentina Fil: Escosteguy, Melisa Lucía. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones en Energía no Convencional. Universidad Nacional de Salta. Facultad de Ciencias Exactas. Departamento de Física. Instituto de Investigaciones en Energía no Convencional; Argentina Fil: Seghezzo, Lucas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones en Energía no Convencional. Universidad Nacional de Salta. Facultad de Ciencias Exactas. Departamento de Física. Instituto de Investigaciones en Energía no Convencional; Argentina Fil: Hufty, Marc. No especifíca;

AbstractWe report the design, synthesis and evaluation of dynamic “octopus” amphiphiles with emphasis on their efficiency as activators in synthetic membrane‐based sensing systems. Previously, we found that the in situ treatment of charged hydrazides with hydrophobic aldehydes or ketones gives amphiphilic counterion activators of polyion transporters in lipid bilayers, and that their efficiency increases with the number of their hydrophobic tails. Herein, we expand this series to amphiphiles with one cationic head (guanidinium or ammonium) and four exchangeable hydrophobic tails. These results, with the highest number of tails reported to date, confirm that dynamic octopus amphiphiles provide access to maximal activity and selectivity. Odorants, such as muscone, carvone, or anisaldehyde are used to outline their usefulness in differential sensing systems that operate based on counterion‐activated DNA transporters in fluorogenic vesicles. The enhanced ability of octopus amphiphiles to enable the discrimination of enantiomers as well as that of otherwise intractable ortho, meta, and para isomers and short cyclo‐/alkyl tails is demonstrated. These findings identify dynamic octopus amphiphiles as being promising for application to differential sensing, “fragrant” cellular uptake, and slow release.

Questions of justice in the transition to a green economy have been raised by various social forces. Very few proposals, however, have been as focused and developed as the “just transition” strategy proposed by global labour unions. Yet, labour unions are remarkably absent from discussions of the transition towards a green economy. This is surprising as labour unions are arguably the largest organizations in the world fighting for basic rights and more just social relations. This paper tries to advance the potential contribution of labour unions in this arena by asking: what is the full scope of “just transition” today and how have labour unions developed and refined it over the years to render the move towards a green economy both environmentally and socially sustainable? The concept of just transition is hotly debated within labour unions and has different interpretations, and hence different strategies. The last section assesses these interpretations by means of a normative framework, which seeks to fuse political economy and political ecology. Empirically, we add to the growing literature on labour environmentalism, as well as transitions more generally. Analytically, our goal is to place the various approaches to a “just transition” within a heuristic framework of environmental justice that is explicit about power relations when demanding justice, two themes central to this special issue.

The Paris Agreement, in force since 2016, stipulates the new multilateral foundations for climate actions under the United Nations Convention on Climate Change. This Agreement incorporated Payment for Environmental Services (PES) and Markets for Environmental Services (MES) among its strategies to combat climate change. However, abundant literature has outlined economic, social and environmental equity concerns regarding the implementation of PES and MES under the Kyoto Protocol. How have these concerns been taken into account in the establishment of PES and MES in the Paris Agreement? How can equity considerations be comprehensively assessed in this regard? Through the triangulation of methodologies including literature review, participant observation and interviews with key informants, this thesis explains the consideration of equity in the newly established PES and MES in the Paris Agreement.