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Abstract This study presents an evaluation of the error induced by neglecting the effect of air compressibility in modelling Oscillating Water Column (OWC) wave energy converters. A compressible two phases CFD model in the open-source software package OpenFOAM® is validated and then used to simulate a fixed OWC device, detached from the sea bottom. A comparative analysis of the results obtained by simulating the device at full-scale (1:1) and at four smaller scales (1:50, 1:25, 1:10 and 1:5) is performed in order to assess the scale effects associated with air compressibility. Indeed, for the air pressure levels considered in the simulations (up to 350 Pa at model scale 1:50), the effect of neglecting the air compressibility results in an overestimation up to about 15% for the air pressure in the OWC chamber and the subsequent air volume flux, but less than 10% for the capture width ratio. This overestimation increases with increasing pressure level. Results are analysed in terms of dimensionless parameters and a new parameter, strongly related to the compressible effects, is proposed and used to provide generalized equations delivering correction factors.

Antiprotons have been suggested as a possibly superior modality for radiotherapy, due to the energy released when antiprotons annihilate, which enhances the Bragg peak and introduces a high-LET component to the dose. However, concerns are expressed about the inferior lateral dose distribution caused by the annihilation products.We use the Monte Carlo code FLUKA to generate depth-dose kernels for protons, antiprotons, and carbon ions. Using these we then build virtual treatment plans optimized according to ICRU recommendations for the different beam modalities, which then are recalculated with FLUKA. Dose-volume histograms generated from these plans can be used to compare the different irradiations.The enhancement in physical and possibly biological dose from annihilating antiprotons can significantly lower the dose in the entrance channel; but only at the expense of a diffuse low dose background from long-range secondary particles. Lateral dose distributions are improved using active beam delivery methods, instead of flat fields.Dose-volume histograms for different treatment scenarios show that antiprotons have the potential to reduce the volume of normal tissue receiving medium to high dose, however, in the low dose region antiprotons are inferior to both protons and carbon ions. This limits the potential usage to situations where dose to normal tissue must be reduced as much as possible.

China joined the ICOM in 1983. Joining such an international community of museological experts and scholars implied sharing the standards and founding principles, however if we consider the development and the status quo of the art museum system in China, it is possible to point out some contradictions and peculiarities. Since the early 1980s, following a renovation process of the entirety of Chinese national institutions, the museum system has been enjoying an unprecedented development. As well, a more general discourse on the cultural heritage of the country has increasingly gained a prominent position in the cultural policy agenda. As far as art museums are concerned, since the end of the 1990s, the country has been experiencing a rapid and unprecedented development as well, encompassing both the state-owned and private sector. However, today the proliferation of art museums appears to be more driven by the compulsion for a status symbol rather than pursuing a cultural mission. Therefore, a key question arises concerning the quality of these art institutions, their effective role in the promotion of art, and their cultural impact. This study aims to enrich the debate on museums of contemporary art, and intends to offer a parameter of sustainability in order to evaluate the Chinese art museum system.

The determination of minimum free energy pathways (MFEP) is one of the most widely used strategies to study reactive processes. For chemical reactions in complex environments, the combination of quantum mechanics (QM) with a molecular mechanics (MM) representation is usually necessary in a hybrid QM/MM framework. However, even within the QM/MM approximation, the affordable sampling of the phase space is, in general, quite restricted. To reduce drastically the computational cost of the simulations, several methods such as umbrella sampling require performing a priori a selection of a reaction coordinate. The quality of the computed results, in an affordable computational time, is intimately related to the reaction coordinate election which is, in general, a nontrivial task. In this work, we provide an approach to model reactive processes in complex environments that does not require the a priori selection of a reaction coordinate. The proposed methodology combines QM/MM simulations with an extrapolation of the nudged elastic bands (NEB) method to the free energy surface (FENEB). We present and apply our own FENEB scheme to optimize MFEP in different reactive processes, using QM/MM frameworks at semiempirical and density functional theory levels. Our implementation is based on performing the FENEB optimization by uncoupling the optimization of the band in a perpendicular and tangential direction. In each step, a full optimization with the spring force is performed, which guarantees that the images remain evenly distributed. The robustness of the method and the influence of sampling on the quality of the optimized MFEP and its associated free energy barrier are studied. We show that the FENEB method provides a good estimation of the reaction barrier even with relatively short simulation times, supporting that its combination with QM/MM frameworks provides an adequate tool to study chemical processes in complex environments.

Balancing financial performance and corporate sustainability is a challenge, especially in today’s economic environment. Based on the idea that there’s a trade-off between what’s “good for the business” and what’s “good for the environment and society,” companies sometimes perceive corporate sustainability and corporate social responsibility (CSR) as an add-on cost, or they may perceive sustainability as an opportunity for “green PR.” By doing so, they may miss significant opportunities for business growth, innovation, and organizational change. In this article, we describe how General Electric (GE) and Procter & Gamble (P&G) have operationalized corporate sustainability initiatives using management control and management accounting systems. Current forces of change are driving a general rethinking of business in a more sustainable direction. Pressures come from national and international regulatory bodies as well as from business partners, stakeholders, and activists. For instance, many companies require their suppliers to comply with standards for environmental management systems certification, such as the ISO 14000 series or the European Union’s Eco-Management and Audit Scheme.Moreover, thanks to new technologies, customers are increasingly informed, empowered, and active, and their demand for products that are clearly identified as sustainable is growing. Employees are also looking for companies that operate in a socially responsible way, which can impact the ability of an organization to recruit and retain talent. In addition, the financial community is paying closer attention to socially responsible investments (SRI) and investment rating systems such as the Dow Jones Sustainability Index. These internal and external stakeholder views shouldn’t be neglected by companies aiming to achieve superior corporate sustainability performance. As suggested in the May 2009 Strategic Finance article “Co-Creating Strategic Risk-Return Management” by Mark Frigo and Venkat Ramaswamy, “Sustainable wealth creation requires balanced risk taking by focusing on co-creation opportunities that can generate superior returns while simultaneously reducing risks for companies and their stakeholders.” Since shareholder value creation is driven from creating value for others (customers, employees, suppliers, and other stakeholders), organizations can think in terms of how these stakeholders can be engaged to help define and achieve sustainability performance. This process can help identify new sustainability opportunities that will create mutual value with internal and external stakeholders. The current drivers of change and the economic downturn provide an opportunity for more integrated, strategic, and value-creating sustainability efforts.

AbstractThis study presents the chiral resolution of flurbiprofen enantiomers by preparative liquid chromatography using the simulated moving bed (SMB) technology. Flurbiprofen enantiomers are widely used as nonsteroidal anti‐inflammatory drugs, and although demonstrate different therapeutic actions, they are still marketed as a racemic mixture. The results presented here clearly show the importance of the selection of the proper solvent composition for the preparative separation of flurbiprofen enantiomers. Chiral SMB separation is carried out using a laboratory‐scale unit (the FlexSMB‐LSRE®) with six columns, packed with the Chiralpak AD® stationary phase (20 μm). Results presented include the experimental measurement of equilibrium and kinetic data for two very different solvent compositions, a traditional high hydrocarbon content [10%ethanol/90%n‐hexane/0.01% trifluoroacetic acid (TFA)] and a strong polar organic composition (100%ethanol/0.01%TFA). Experimental data, obtained using the two mobile phase compositions, are used to predict and optimize the SMB operation. After selecting 10%ethanol/90%n‐hexane/0.01%TFA as the most appropriate solvent composition, three feed concentrations of racemic flurbiprofen were considered. Using 40 g/l of racemic flurbiprofen feed solution, the purities for both outlet streams were above 99.4%, the productivity was 13.1 gfeed/(Lbedh), and a solvent consumption of 0.41 Lsolvent/gfeedwas achieved. Chirality, 2011. © 2011 Wiley‐Liss, Inc.

Abstract Fodder for feeding pork and poultry requires a large amount of cultivated and processed agricultural crops, which are often related to greenhouse gas emissions from land-use change (LUC). Given the rapid growth in meat production in Brazil for domestic consumption and international export, the link between LUC emissions and consumption of pork and poultry meat is central to evaluating the role of Brazilian meat production and the implications for international climate policies. In this paper, we first estimate LUC emissions from soybean production destined to feed pork and poultry in Brazil during the period 2008–2012. Second, we allocate such emissions to domestic and international consumption of pork and poultry meat. Concerning international consumption, Brazilian export of meat to 189 countries is evaluated. Although the majority of the LUC emissions from soybean production are tied to the domestic consumption, 17% and 39% of the emissions embodied in Brazilian pork and poultry, respectively, are exported to other countries. The most prominent destinations of Brazilian pork and poultry in terms of embodied LUC emissions are Eastern Europe, Asia and South America. In the case of pork, the fluxes of emissions from Brazil to Ukraine (1.28 Mt CO2-eq) and Russia (1.18 Mt CO2-eq) are particularly large. In the case of poultry, the largest transfers of embodied emissions are from Brazil to developing countries and especially the Middle East. These results are relevant to environmental policies and international agreements aimed at achieving the sustainability of Brazil's meat sector.