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Given the significant amount of installed generation-capacity based on wind power, and also due to current economic downturn, the subsidies and incentives that have been widely used by wind-power producers to recover their investment costs have decreased and are even expected to disappear in the near future. In these conditions, wind-power producers need to develop offering strategies to make their investments profitable counting solely on the market. This paper proposes a multi-stage risk-constrained stochastic complementarity model to derive the optimal offering strategy of a wind-power producer that participates in both the day-ahead and the balancing markets. Uncertainties concerning wind-power productions, market prices, demands' bids, and rivals' offers are efficiently modeled using a set of scenarios. The conditional-value-at-risk metric is used to model the profit risk associated with the offering decisions. The proposed model is recast as a tractable mixed-integer linear programming program solvable using available branch-and-cut algorithms. Results of a case study are reported and discussed to show the effectiveness and applicability of the proposed approach.

This paper describes anaerobic thermophilic sludge digestion (55 °C) in a continuously stirred tank reactor (CSTR) on a pilot-plant scale (150 L). The experimental protocol was defined to examine the effect of the increase in the organic loading rate on the efficiency of the digester and to report on its steady-state performance. The reactor was subjected to a programme of steady-state operation over a range of solids retention times (SRTs) of 75, 40, 27, 20 and 15 days and organic loading rates (OLR) in the range 0.4–2.2 kg VS/(m3 day). The digester was fed with raw sludge (containing approximately 35 kg/m3 volatile solids (VS)) once daily during the 75-day SRT period, twice daily during the 40-day SRT period and three times a day during the 27-, 20- and 15-day SRT periods. The reactor was initially operated with an organic loading rate of 0.4 kg VS/(m3 day) and an SRT of 75 days. The volatile solids removal efficiency in the reactor was found to be 73%, while the volumetric methane production rate produced in the digester reached 0.02 m3/(m3 day). Over a 338-day operating period, an OLR of 2.2 kg VS/(m3 day) was achieved with 49.1% VS removal efficiency in the pilot sludge digester, at which time the volumetric methane production rate content of biogas produced in the digester reached 0.4 m3/(m3 day). The chemical oxygen demand (COD) mass balance obtained indicated that COD used for methane generation increased when the SRT was decreased or when the influent organic loading rate was increased. This implies that the amount of COD used in the anabolism route decreased with SRT due the microbial population becoming adapted to new operational conditions and more COD being used to generate methane.

One of the major goals of engine designers is the reduction of fuel consumption and pollutant emissions while keeping or even improving engine performance. In recent years, different technical issues have been investigated and incorporated into internal combustion engines in order to fulfill these requirements. Most are related to the combustion process since it is responsible for both fuel consumption and pollutant emissions. Additionally, the most critical operating points for an engine are both the starting and the warming up periods (the time the engine takes to reach its nominal temperature, generally between 80°C and 90°C), since at these points fuel consumption and pollutant emissions are larger than at any other points. Thus, reducing the warm-up period can be crucial to fulfill new demands and regulations. This period depends strongly on the engine cooling system and the different strategies used to control and regulate coolant flow and temperature. In the present work, the influences of different engine cooling system configurations on the warm-up period of a Diesel engine are studied. The first part of the work focuses on the modeling of a baseline engine cooling system and the tests performed to adjust and validate the model. Once the model was validated, different modifications of the engine coolant system were simulated. From the modelled results, the most favourable condition was selected in order to check on the test bench the reduction achieved in engine warm-up time and to quantify the benefits obtained in terms of engine fuel consumption and pollutant emissions under the New European Driving Cycle (NEDC). The results show that one of the selected configurations reduced the warm-up period by approximately 159 s when compared with the baseline configuration. As a consequence, important reductions in fuel consumption and pollutant emissions (HC and CO) were obtained.

Abstract CIEMAT is promoting experiences on heliostats for replacement of damaged facets on CESA-1 field, design of new modules for Phoebus-like plants and innovative high-risk options for the future. Glass-metal facets, stretched membranes, glass fiber and holographic concentrators are being considered in a number of developments.

This work studied outdoor pilot scale production of Nannochloropsis gaditana in tubular photobioreactors. The growth and biomass composition of the strain were studied under different culture strategies: continuous-mode (varying nutrient supply and dilution rate) and two-stage cultures aiming lipid enhancement. Besides, parameters such as irradiance, specific nitrate input and dilution rate were used to obtain models predicting growth, lipid and fatty acids production rates. The range of optimum dilution rate was 0.31-0.351/day with maximum biomass, lipid and fatty acids productivities of 590, 110 and 66.8 mg/l day, respectively. Nitrate limitation led to an increase in lipid and fatty acids contents (from 20.5% to 38.0% and from 16.9% to 23.5%, respectively). Two-stage culture strategy provided similar fatty acids productivities (56.4 mg/l day) but the neutral lipids content was doubled.

AbstractBlack TiO2 has demonstrated a great potential for a variety of renewable energy technologies. However, its practical application is heavily hindered due to lack of efficient hydrogenation methods and a deeper understanding of hydrogenation mechanisms. Here, a simple and straightforward hot wire annealing (HWA) method is presented to prepare black TiO2 (H–TiO2) nanorods with enhanced photo‐electrochemical (PEC) activity by means of atomic hydrogen [H]. Compared to conventional molecular hydrogen approaches, the HWA shows remarkable effectiveness without any detrimental side effects on the device structure, and simultaneously the photocurrent density of H–TiO2 reaches 2.5 mA cm−2 (at 1.23 V vs reversible hydrogen electrode (RHE)). Due to the controllable and reproducible [H] flux, the HWA can be developed as a standard hydrogenation method for black TiO2. Meanwhile, the relationships between the wire temperatures, structural, optical, and photo‐electrochemical properties are systematically investigated to verify the improved PEC activity. Furthermore, the density functional theory (DFT) study provides a comprehensive insight not only into the highly efficient mechanism of the HWA approach but also its favorably low‐energy‐barrier hydrogenation pathway. The findings will have a profound impact on the broad energy applications of H–TiO2 and contribute to the fundamental understanding of its hydrogenation.

Abstract This paper presents a model of a lead-acid battery developed with bond graphs. The bond graph structure is used to reproduce the behavior of reversible electrochemical cells in charging conditions or in discharging conditions. The work presented here has been applied to the particular case of lead-acid battery, so widely used in the automotive industry as standard 12 V batteries and as traction batteries in electrical or hybrid vehicles. The model considers each half-cell independently. For each half-cell the main electrode reaction and the electrolysis reaction of water are considered, that will be the hydrogen evolution reaction in the negative electrode and the oxygen evolution reaction in the positive. Electrochemical principles are considered in order to consider the main phenomena that appear in the battery, like the equilibrium potential, and the overpotential, modeled by means of the activation or charge transfer and the diffusion mechanisms. Each one of this phenomena are modeled with their corresponding bond graph elements and structures, showing the correspondence between bond graph elements and its physical interpretation in this field. First, an isothermal model has been developed in order to show the behavior of the main phenomena. A more complex model has also been developed including thermal behavior. This model is very useful in the case of traction batteries in electrical and hybrid vehicles where high current intensities appear. Some simulation results are also presented in order to show the accuracy of the proposed models and the differences of behavior if thermal effects are considered.

Abstract The steam gasification of high density polyethylene in continuous mode has been carried out in a conical spouted bed reactor. The effect of temperature (in the 800–900 °C range) and steam/plastic mass ratio (between 0 and 2) on the distribution of products (gas and tar) and their composition has been studied. In order to reduce tar formation, two catalysts have been used in situ, namely, olivine and γ-Al 2 O 3 . The spouted bed reactor has an excellent performance between 850 and 900 °C, and an increase in the steam/plastic ratio from 1 to 2 only improves slightly both carbon conversion efficiency (to 93.6% with steam/plastic ratio = 2) and hydrogen concentration (61.6%). The use of olivine and γ-Al 2 O 3 instead of sand gives way to a moderate reduction in the tar formation , whose yield is 4.8% with olivine. The syngas obtained has a H 2 /CO ratio of 2.2, with a low tar content whose composition (monoaromatics, mainly benzene) augurs well for the use of the syngas in DME synthesis.