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Degradation issues correlated to microstructural changes are the main obstacles to solid oxide fuel cell and electrolyser applications, making their identification and understanding fundamental steps. Coupling experimental activities with modelling, this work analyses the state-of-the-art Ni-YSZ (Yttria-Stabilized Zirconia)/YSZ/CGO (Cerium Gadolinium Oxide)/LSCF (Lanthanum Strontium Cobalt Ferrite)-CGO-based cell after 1000 h of galvanostatic electrolysis operation at fixed temperature and high steam composition in the inlet gas. Following a multiscale approach, the system behaviour is characterized through electrochemical impedance spectra and polarization curves as well as studying microstructure evolution, with a focus on Ni-cermet functional layer in view of Ni instability detected as the main degradation cause. A comparison with a cell consisting of the same initial geometrical structure and materials but aged in fuel cell mode allows to highlight the influence of operating mode and parameters on Ni-YSZ microstructure. Ni particle size and phase fraction variations experimentally observed on the electrode surface are correlated to water content and applied polarization simulated local values. Ni uneven distribution at the electrolyte interface and particle coarsening, above all, lead to an increase in polarization loss under electrolysis and fuel cell mode, respectively, since both penalise the charge transfer reaction and migration.

Degradation issues correlated to microstructural changes are the main obstacles to solid oxide fuel cell and electrolyser applications, making their identification and understanding fundamental steps. Coupling experimental activities with modelling, this work analyses the state-of-the-art Ni-YSZ (Yttria-Stabilized Zirconia)/YSZ/CGO (Cerium Gadolinium Oxide)/LSCF (Lanthanum Strontium Cobalt Ferrite)-CGO-based cell after 1000 h of galvanostatic electrolysis operation at fixed temperature and high steam composition in the inlet gas. Following a multiscale approach, the system behaviour is characterized through electrochemical impedance spectra and polarization curves as well as studying microstructure evolution, with a focus on Ni-cermet functional layer in view of Ni instability detected as the main degradation cause. A comparison with a cell consisting of the same initial geometrical structure and materials but aged in fuel cell mode allows to highlight the influence of operating mode and parameters on Ni-YSZ microstructure. Ni particle size and phase fraction variations experimentally observed on the electrode surface are correlated to water content and applied polarization simulated local values. Ni uneven distribution at the electrolyte interface and particle coarsening, above all, lead to an increase in polarization loss under electrolysis and fuel cell mode, respectively, since both penalise the charge transfer reaction and migration.

In this study, innovative polyurethane (PUR)-based aerogels were developed and reinforced with silica (SiO2) particles derived from rice husk through two distinct treatments: acid digestion (AD) and sol-gel (SG). These materials address the dual challenge of valorizing agricultural by-products and improving acoustic insulation properties. Acoustic characterization using impedance tube methods revealed a homogeneous internal structure, as evidenced by the consistent absorption rates on both sides of the aerogels. PUR aerogels doped with 1 wt% SG (SiO2_SG1), 2 wt% AD (SiO2_AD2), and 1 wt% AD (SiO2_AD1) achieved the highest absorption coefficients, outperforming traditional materials at specific frequencies, while 2 wt% SG (SiO2_SG2) exhibited the lowest absorption rate. Transmission loss measurements further demonstrated that SiO2_SG1 achieved superior performance at low frequencies, while SiO2_SG2 excelled at high frequencies, highlighting the tunable acoustic behavior of these aerogels. Compared to conventional insulation materials, these aerogels combine lightweight properties, high porosity, and sustainable synthesis, offering a cost-effective and eco-friendly alternative for building applications. This work demonstrates a significant step forward in the integration of bio-based resources into high-performance acoustic materials, bridging the gap between sustainability and functionality in material design.

In this study, innovative polyurethane (PUR)-based aerogels were developed and reinforced with silica (SiO2) particles derived from rice husk through two distinct treatments: acid digestion (AD) and sol-gel (SG). These materials address the dual challenge of valorizing agricultural by-products and improving acoustic insulation properties. Acoustic characterization using impedance tube methods revealed a homogeneous internal structure, as evidenced by the consistent absorption rates on both sides of the aerogels. PUR aerogels doped with 1 wt% SG (SiO2_SG1), 2 wt% AD (SiO2_AD2), and 1 wt% AD (SiO2_AD1) achieved the highest absorption coefficients, outperforming traditional materials at specific frequencies, while 2 wt% SG (SiO2_SG2) exhibited the lowest absorption rate. Transmission loss measurements further demonstrated that SiO2_SG1 achieved superior performance at low frequencies, while SiO2_SG2 excelled at high frequencies, highlighting the tunable acoustic behavior of these aerogels. Compared to conventional insulation materials, these aerogels combine lightweight properties, high porosity, and sustainable synthesis, offering a cost-effective and eco-friendly alternative for building applications. This work demonstrates a significant step forward in the integration of bio-based resources into high-performance acoustic materials, bridging the gap between sustainability and functionality in material design.

Abstract The phonon-glass electron-crystal paradigm has guided thermoelectric research in recent years. However, the inherent conflict between atomic disorder reducing phonon conduction, and the order required to maintain high electron mobility, creates a significant challenge in material design, which has driven innovation in nanostructuring and composite materials. Here, vertically aligned nanocomposites (VANs) composed of self-assembled metallic La0.7Sr0.3MnO3 (LSMO) nanopillars in a surrounding ZnO matrix are investigated for controllable thermal conductivity. Tuning of the crystal orientation of the substrate controls the epitaxial alignment of the LSMO and ZnO phases along the horizontal and vertical interfaces. The VAN films on (111)-oriented STO substrates exhibit an increased power factor of 0.52 μW·cm−1·K−2 at 600 °C beyond ZnO films of 0.15 μW·cm−1·K−2. Detailed characterization and modeling of the thermal conductivity demonstrates a reduction of about 75% as well as anisotropic behavior for the VAN films with out-of-plane and in-plane thermal conductivities of respectively 9.2 and 1.5 W·m−1·K−1, in strong contrast to the isotropic behavior in ZnO films with a thermal conductivity of 38 W·m−1·K−1. These results show the promising strategy of VAN thin films with a nanopillar-matrix architecture to scatter phonons and to enhance the thermoelectric performance.

Abstract The phonon-glass electron-crystal paradigm has guided thermoelectric research in recent years. However, the inherent conflict between atomic disorder reducing phonon conduction, and the order required to maintain high electron mobility, creates a significant challenge in material design, which has driven innovation in nanostructuring and composite materials. Here, vertically aligned nanocomposites (VANs) composed of self-assembled metallic La0.7Sr0.3MnO3 (LSMO) nanopillars in a surrounding ZnO matrix are investigated for controllable thermal conductivity. Tuning of the crystal orientation of the substrate controls the epitaxial alignment of the LSMO and ZnO phases along the horizontal and vertical interfaces. The VAN films on (111)-oriented STO substrates exhibit an increased power factor of 0.52 μW·cm−1·K−2 at 600 °C beyond ZnO films of 0.15 μW·cm−1·K−2. Detailed characterization and modeling of the thermal conductivity demonstrates a reduction of about 75% as well as anisotropic behavior for the VAN films with out-of-plane and in-plane thermal conductivities of respectively 9.2 and 1.5 W·m−1·K−1, in strong contrast to the isotropic behavior in ZnO films with a thermal conductivity of 38 W·m−1·K−1. These results show the promising strategy of VAN thin films with a nanopillar-matrix architecture to scatter phonons and to enhance the thermoelectric performance.

Third-generation biofuels are currently a promising alternative for energy production, since electricity prices have risen sharply and the search for alternative energy sources to fossil fuels has become a necessity. The use of the anaerobic digestion process for the production of biomethane from microalgae has been studied over the years and has reached a certain degree of maturity, becoming the most straightforward way to obtain energy from microalgae without the need for a previous drying or extraction phase, thus eliminating the costs associated with these operations. Microalgae also show a high potential to grow in different media, including wastewater, as well as a high capacity for nutrient absorption and carbon dioxide fixation, which aid in decarbonization. These characteristics, combined with biomethane production, can contribute to achieving a satisfactory bioenergy production in a circular economy model. Peer reviewed 2 Tablas

Third-generation biofuels are currently a promising alternative for energy production, since electricity prices have risen sharply and the search for alternative energy sources to fossil fuels has become a necessity. The use of the anaerobic digestion process for the production of biomethane from microalgae has been studied over the years and has reached a certain degree of maturity, becoming the most straightforward way to obtain energy from microalgae without the need for a previous drying or extraction phase, thus eliminating the costs associated with these operations. Microalgae also show a high potential to grow in different media, including wastewater, as well as a high capacity for nutrient absorption and carbon dioxide fixation, which aid in decarbonization. These characteristics, combined with biomethane production, can contribute to achieving a satisfactory bioenergy production in a circular economy model. Peer reviewed 2 Tablas