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The high power density, ease of transportation and storage and many years of development of internal combustion engine technologies have put liquid hydrocarbon fuels at a privileged position in our energy mix. Therefore processes that use renewable energy sources to produce liquid hydrocarbon fuels from H2O and CO2 are of crucial importance. Concentrated Solar Power (CSP) can be employed as the only energy source for the renewable production of hydrogen from water either indirectly, e.g. by supplying the electricity for electrolysis, or directly by supplying the necessary heat for thermochemically producing hydrogen. Among the various thermochemical cycles tested so far for CSP-driven hydrogen production via water splitting (WS), those based on redox-pair oxide systems, are directly adaptable to carbon dioxide splitting (CDS) and/or combined CO2/H2O splitting for the production of CO or syngas, respectively. The acknowledgement of this fact has recently revived the interest of the scientific community on such technologies. The current article presents the development, evolution and current status of CSP-aided syngas production via such redox-pair-based thermochemical cycles. At first the various redox oxide material compositions tested for water/carbon dioxide splitting are presented and their redox chemistries are discussed. Then the selection of suitable solar reactors is addressed in conjunction with the boundary conditions imposed by the redox systems as well as the heat demands, technical peculiarities and requirements of the cycle steps. The various solar reactor concepts proposed and employed for such reactions and their current status of development are presented. Finally, topics where further work is needed for commercialization of the technology are identified and discussed.

Abstract We present two advances in representing variable renewables (VRE) in global energy-economy-climate models: accounting for region-specific integration challenges for eight world regions and considering short-term storage. Both advances refine the approach of implementing residual load duration curves (RLDCs) to capture integration challenges. In this paper we derive RLDCs for eight world regions (based on region-specific time series for load, wind and solar) and implement them into the REMIND model. Therein we parameterize the impact of short-term storage using the highly-resolved model DIMES. All RLDCs and the underlying region-specific VRE time series are made available to the research community. We find that the more accurate accounting of integration challenges in REMIND does not reduce the prominent role of wind and solar in scenarios that cost-efficiently achieve the 2 °C target. Until 2030, VRE shares increase to about 15–40% in most regions with limited deployment of short-term storage capacities (below 2% of peak load). The REMIND model's default assumption of large-scale transmission grid expansion allows smoothening variability such that VRE capacity credits are moderate and curtailment is low. In the long run, VRE become the backbone of electricity supply and provide more than 70% of global electricity demand from 2070 on. Integration options ease this transformation: storage on diurnal and seasonal scales (via flow batteries and hydrogen electrolysis) and a shift in the non-VRE capacity mix from baseload towards more peaking power plants. The refined RLDC approach allows for a more accurate consideration of system-level impacts of VRE, and hence more robust insights on the nature of power sector decarbonization and related economic impacts.

Abstract. Present day tropospheric ozone and its changes between 1850 and 2100 are considered, analysing 15 global models that participated in the Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP). The multi-model mean compares well against present day observations. The seasonal cycle correlates well, except for some locations in the tropical upper troposphere. Most (75%) of the models are encompassed with a range of global mean tropospheric ozone column estimates from satellite data, although there is a suggestion of a high bias in the Northern Hemisphere and a low bias in the Southern Hemisphere. Compared to the present day multi-model mean tropospheric ozone burden of 337 Tg, the multi-model mean burden for 1850 time slice is ~ 30% lower. Future changes were modelled using emissions and climate projections from four Representative Concentration Pathways (RCPs). Compared to 2000, the relative changes for the tropospheric ozone burden in 2030 (2100) for the different RCPs are: −5% (−22%) for RCP2.6, 3% (−8%) for RCP4.5, 0% (−9%) for RCP6.0, and 5% (15%) for RCP8.5. Model agreement on the magnitude of the change is greatest for larger changes. Reductions in precursor emissions are common across the RCPs and drive ozone decreases in all but RCP8.5, where doubled methane and a larger stratospheric influx increase ozone. Models with high ozone abundances for the present day also have high ozone levels for the other time slices, but there are no models consistently predicting large or small changes. Spatial patterns of ozone changes are well correlated across most models, but are notably different for models without time evolving stratospheric ozone concentrations. A unified approach to ozone budget specifications is recommended to help future studies attribute ozone changes and inter-model differences more clearly.