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Two approaches to synthesis of unsymmetrical disulfides based on different types of thiol activation, namely, an electrochemical method in the presence of a redox mediator and a microwave irradiation, were discussed. The mediated electrosynthesis procedures were carried out by the oxidative coupling of thiols or by the thiol-disulfide exchange in the presence of redox pairs—substituted o-aminophenol/o-iminobenzoquinone. It has been established that the formation of unsymmetrical disulfides under electrochemical conditions occurs as a result of both the oxidative coupling of sulfur-centered radicals, and a redox-mediator promoted thiol-disulfide exchange, which led to a high yield of heterodimeric products (89%–99%). The microwave-assisted synthesis made it possible to obtain the target products with yields of 13%–86% depending on different irradiation parameters such as power, temperature, and irradiation duration. However, this method requires a rigorous selection of conditions for each reaction and is therefore inferior to the electrochemical approach.

For zero‐defect wave soldering of double‐sided and multilayer printed circuit boards, the copper through‐hole‐plating must be impervious to gas generated in the laminate for the period of a few seconds while the solder is molten. The kinetics of the gas evolution during soldering have been related quantitatively to the integrity of the plated copper. This in turn is related to the quality of the electroless copper (evaluated using the backlighting test), the nature and distribution of the catalyst (evaluated using X‐ray photoelectron spectroscopy) and the methods and effectiveness of the hole‐wall preparation (evaluated using scanning electron microscopy). The relevance of laboratory measurements has been confirmed on a wide range of industrial production plating lines.

Beyond the anticipated experience associated with tourism destinations, the United Nations World Tourism Organization (UNWTO) has further tasked (especially the destination countries) on the importance of tourism to achieving the 2030 Sustainable Development Goals (SDGs). From this dimension, this study employed the ecological footprint of the 10 most visited countries (France, Spain, United States, China, Italy, Mexico, United Kingdom, Turkey, Germany, and Thailand) over the period 1995-2016. Specifically, the study employed an econometric approach and found that increase in tourism arrivals and globalization is detrimental to the attainment of sustainable environmental quality in a long term. Precisely, a 1% increase in international arrivals and globalization is responsible for a 0.18 and 0.89% increase in ecological footprint in the long-run. These impacts of tourism activities and globalization are detrimental to the environmental quality of the destination countries. Meanwhile, the real income per capita and biocapacity in the destination countries improve the environmental quality of the panel of destination countries in the long-run. In addition, the study found significant evidence of Granger causality from tourism and real income to ecological footprint without feedback, the globalization-ecological footprint Granger causality nexus is with feedback. Moreover, potentially effective policies for government and other stakeholders especially toward attaining Global goals were proffered in the study.

The industrial sector accounts for 17% of end-use energy in the UK, and 54% globally. Therefore, there is substantial scope for simulating and assessing potential energy retrofit options for industrial buildings. Building Energy Modelling (BEM) applied to industrial buildings poses a complex but important opportunity for reducing global energy demand, due to years of renovation and expansion. Large and complex industrial buildings make modelling existing geometry for BEM difficult and time consuming. This paper presents a potential solution for quickly capturing and processing as-built geometry of a factory to be utilized in BEM. Laser scans were captured from the interior of an industrial facility to produce a Point Cloud. The existing capabilities of a Point Cloud processing software were assessed to identify the potential development opportunities to automate the conversion of Point Clouds to building geometry for BEM applications. In conclusion, scope exists for increasing the speed of 3D geometry creation of an existing industrial building for application in BEM and subsequent thermal simulation.

Abstract Space–time kinetics calculations for CANDU ® 1 reactors are routinely performed using the Improved Quasistatic (IQS) method. The IQS method calculates kinetics parameters such as the effective delayed-neutron fraction and generation time using adjoint weighting. In the current implementation of IQS, the direct flux, as well as the adjoint, is calculated using a two-group cell-homogenized reactor model which is inadequate for capturing the effect of the softer energy spectrum of the delayed neutrons. Additionally, there may also be fine spatial effects that are lost because the intra-cell adjoint shape is ignored. The purpose of this work is to compare the kinetics parameters calculated using the two-group cell-homogenized model with those calculated using lattice-level fine-group heterogeneous adjoint weighting and to assess whether the differences are large enough to justify further work on incorporating lattice-level adjoint weighting into the IQS method. A second goal is to evaluate whether the use of a fine-group cell-homogenized lattice-level adjoint, such as is the current practice for Light Water Reactors (LWRs), is sufficient to capture the lattice effects in question. It is found that, for CANDU lattices, the generation time is almost unaffected by the type of adjoint used to calculate it, but that the effective delayed-neutron fraction is affected by the type of adjoint used. The effective delayed-neutron fraction calculated using the two-group cell-homogenized adjoint is 5.2% higher than the “best” effective delayed-neutron fraction value obtained using the detailed lattice-level fine-group heterogeneous adjoint. The effective delayed-neutron fraction calculated using the fine-group cell-homogenized adjoint is only 1.7% higher than the “best” effective delayed-neutron fraction value but is still not equal to it. This situation is different from that encountered in LWRs where weighting by a fine-group cell-homogenized adjoint is sufficient to calculate the correct effective delayed-neutron fraction. It is concluded that lattice-level weighting with a detailed fine-group heterogeneous adjoint is desirable for the correct calculation of the effective delayed-neutron fraction in CANDU lattices.

We have developed algorithms and programs for automated tests of synchronous machines. The programs were made using the LabVIEW development system. They are interrelated and have been combined into one software system. An approximation of its characteristics using regression equations of different orders with mean-square rate control is used in the algorithms to determine static parameters. A combined optimizing algorithm that is based on the least squares method and alternating-variable descent method is used to determine dynamic parameters. A new effective and adaptive method of sliding trigonometric interpolation is used to filter out possible noise in measuring channels of voltage and current sensors, while determining the parameters of sinusoidal signals in the stationary modes and dots of envelope curves in the transient modes. To reduce the time needed to obtain static characteristics, the software has a special virtual instrument with a field current control loop with a PID controller that provides desired field forcing. The SMTest software system has been tested using HIL modeling and laboratory test stations. Analysis of test results shows that, even when the acquired signal has a 30% noise level, the calculation error in the determination of parameters does not exceed 6%. The software, when used in stationary or mobile test stations, allows automating the process of obtaining characteristics and determining the main static and dynamic parameters of midand high-power rotor synchronous machines.

The aim of the research presented in the article is to develop methods and means for integrated modeling of compact expanded capacity power lines. Algorithms for determining modes of electrical energy systems were used based on phase coordinates based on application of elements models in form of lacelike equivalent networks with fully-meshed topology. These models and methods were implemented in Fazonord-APC software application, ensuring modeling of EES sta-tionary modes, and determining strengths of electromagnetic fields generated by power lines of different design. We demonstrate results of modes and electromagnetic fields modeling on routes of 220 kV compact overhead power supply lines (COPL) with horizontal positioning of wires. For the purpose of comparison, similar calculations were performed for a typical overhead power line (TOPL). The modeling results allowed to formulate the following conclusions: when overall sections of COPL and TOPL are equal, the losses of active power in compact OPL are significantly lower; thus, when transmitted power is 375 MW, the losses in COPL are reduced by 45% compared to a typical 220 kV OPL; at compact OPL receiver end a lower unsymmetry is observed; COPL ensure better electromagnetic safety conditions; electrical field strength at a height of 1.8 m for COPL axis is less than a similar index for TOPL by approximately 1.5 times; magnetic field in the same point is reduced to 60%.