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This study introduces novel phenothiazine-based organic dyes, 2-LBH-100, 2-LBH-44, and 2-Ryu-4, specifically designed for quasi-solid-state dye-sensitized solar cells (QsDSSCs). Employing a donor-π-acceptor architecture, these dyes incorporate varying electron-donating moieties, including bis(3-(hexyloxy)phenyl)amine and diphenylamino, coupled with a cyanoacrylic acid acceptor. Alkoxy substitutions in 2-LBH-100 and 2-LBH-44 enhanced solubility and dye loading on TiO2, leading to improved performance in QsDSSCs. 2-LBH-100 exhibited a power conversion efficiency (PCE) exceeding 5% with excellent stability, while 2-LBH-44 demonstrated a PCE of over 3%, increasing to 4% over time. 2-Ryu-4, with its diphenylamino donor, achieved an initial PCE of over 6%. This research highlights the crucial role of donor–acceptor interactions in optimizing organic dye design for high-performance QsDSSCs, paving the way for efficient and stable next-generation solar energy technologies.

The paper presents an experimental study on the formation process of burden surface texture on the blast furnace throat and its influence on the radial distribution of gas flow. The study was performed with the application of blast furnaces equipped with a bell-type charging device using radio-isotope means for the control of burden surface texture (profile) and burden surface level, i.e., gamma locators for burden surface texture. The study was carried out under the conditions of an operating blast furnace in an iron and steel plant using a unique GEOTAPS system for automated control of geometric and temperature parameters of burden material surface on the blast furnace throat. The influence of the surface texture on the gas flow distribution was also investigated. The possibility of a self-stabilization effect for burden surface texture and gas flow in an operating blast furnace under suitable conditions was experimentally proven. As a result of the experimental study performed, four ways of energy-saving technology implementation were determined for the control of blast furnace melting based on the data on the burden surface texture and previously unknown regularities of surface layer formation of burden material on the throat of an operating blast furnace with a bell-type charging device. The main idea of the paper is the development of automated control for the radial distribution of burden material and gas flow using actual or predicted surface texture parameters as important intermediate factors that both describe the process and have a significant simultaneous influence on it.

The paper presents a preliminary technical-economic comparison between a 3 kV DC railway and the use of trains with on-board storage systems. Numerical simulations have been carried out on a real railway line, which presents an electrified section at 3 kV DC and a non-electrified section, currently covered by diesel-powered trains. Different types of ESS have been analyzed, implementing the models in Matlab/Simulink environment. A preparatory economic investigation has been carried out.

Intra-day price spreads are of interest to electricity traders, storage and electric vehicle operators. This paper formulates dynamic density functions, based upon skewed-t and similar representations, to model and forecast the German electricity price spreads between different hours of the day, as revealed in the day-ahead auctions. The four specifications of the density functions are dynamic and conditional upon exogenous drivers, thereby permitting the location, scale and shape parameters of the densities to respond hourly to such factors as weather and demand forecasts. The best fitting and forecasting specifications for each spread are selected based on the Pinball Loss function, following the closed-form analytical solutions of the cumulative distribution functions.

This paper presents a one-dimensional finite-volume model of an unglazed photovoltaic/thermal (PVT) solar collector. The unit consists of a conventional solar photovoltaic (PV) collector coupled with a suitable heat exchanger. In particular, the collector includes a roll bond heat exchanger and it is not equipped with back and frame insulation. The system is discretized along the flow direction (longitudinal) of the cogenerative collector. For each finite-volume element of the discretized computational domain, mass and energy balances are implemented. The collector geometry and materials parameters are taken from a commercially available device. An on-field experimental investigation is performed in order to validate the proposed model. The model is used to evaluate both electrical and thermodynamic parameters for each element of the domain and for fixed operating conditions. Finally, a sensitivity analysis is also performed in order to investigate the energetic performance of the cogenerative collector as a function of the main design/environmental parameters.

This work presents an innovative control architecture, which takes its ideas from the theory of adaptive control techniques and the theory of statistical learning at the same time. Taking inspiration from the architecture of a classical neural network with several hidden levels, the principle is to divide the architecture of the adaptive controller into three different levels. Each level implements an algorithm based on learning from data and therefore we can talk about learning concepts. Each level has a different task: the first to learn the required reference to the control loop; the second to learn the coefficients of the state representation of a model of the system to be controlled; and finally, the third to learn the coefficients of the state representation of the actual controller. The design of the control system is reported from both a rigorous and an operational point of view. As an application example, the proposed control technique is applied on a second-order non-linear system. We consider a servo-drive based on a brushless DC (BLDC) motor, whose dynamic model considers all the non-linear effects related to the electromechanical nature of the electric machine itself, and also an accurate model of the switching power converter. The reported example shows the capability of the control algorithm to ensure trajectory tracking while allowing for disturbance rejection with different disturbance signal amplitude. The implementation complexity analysis of the new controller is also proposed, showing its low overhead vs. basic control solutions.

This paper deals with wave energy conversion in shallow water, analyzing the performance of two different oscillating-body systems. The first one is a heaving float, which is a system known in the literature. The second one is obtained by coupling the heaving float with a surging paddle. In order to check the different behaviors of the multibody system and the single-body heaving float, physical models of the two systems have been tested in a wave flume, by placing them at various water depths along a sloping bottom. The systems have been tested with monochromatic waves. For each water depth, several tests have been performed varying the geometrical and mechanical parameters of the two systems, in order to find their best configurations. It has been found that the multibody system is more energetic when the float and the paddle are close to each other. Capture width ratio has been found to significantly vary with water depth for both systems: in particular, capture width ratio of the heaving float (also within the multibody system) increases as water depth increases, while capture width ratio of the paddle (within the multibody system) increases as water depth decreases. At the end, the capture width ratio of the multibody system is almost always higher than that of the heaving float, and it increases as water depth increases on average; however, the multibody advantage over single body is significant for water depth less than the characteristic dimension of the system, and decreases as water depth increases.