• Energy Research
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Abstract With the rapid advancement in wearable electronics, energy harvesting devices based on triboelectric nanogenerators (TENGs) have been intensively investigated for providing sustainable power supply for them. However, the fabrication of wearable TENGs still remains great challenges, such as flexibility, breathability and washability. Here, a route to develop a new kind of woven-structured triboelectric nanogenerator (WS-TENG) with a facile, low-cost, and scalable electrospinning technique is reported. The WS-TENG is fabricated with commercial stainless-steel yarns wrapped by electrospun polyamide 66 nanofiber and poly(vinylidenefluoride-co-trifluoroethylene) nanofiber, respectively. Triggered by diversified friction materials under a working principle of freestanding mode, the open-circuit voltage, short-circuit current and maximum instantaneous power density from the WS-TENG can reach up to 166 V, 8.5 µA and 93 mW/m2, respectively. By virtue of high flexibility, desirable breathability, washability and excellent durability, the fabricated WS-TENG is demonstrated to be a reliable power textile to light up 58 light-emitting diodes (LED) connected serially, charge commercial capacitors and drive portable electronics. A smart glove with stitched WS-TENGs is made to detect finger motion in different circumstances. The work presents a new approach for self-powered textiles with potential applications in biomechanical energy harvesting, wearable electronics and human motion monitoring.

Charging lithium–oxygen batteries with redox mediators suppresses singlet oxygen generation at rates orders of magnitude faster than quenchers.

Abstract Driven by wind and buoyancy effects in the urban environment, ventilation performance and pollutant transmission are highly related to human health. In order to investigate characteristics of the single-sided natural ventilation and interunit dispersion problem, this study conducted scaled outdoor experiments in summer and winter periods in two-dimensional street canyons. Tracer gas method was adopted to predict the ventilation rate and simulate the pollutant dispersion. It was found the ventilation performance of windward and leeward rooms showed different trends with wind velocities. Archimedes number Ar was used to examine the interactions of the buoyancy and the wind forces. It revealed that the non-dimensional ventilation rates of all rooms were generally smaller than the results of buoyancy effect only. It indicates that interactions between the buoyancy and wind effects were destructive, which reduced the ventilation rates. The interunit dispersion characteristics with the wind effect were highly dependent on source locations. The results of the tracer gas concentrations of the reentered rooms were not showing simple increasing or decreasing trends. This study provides authentic and instant airflow and pollutant dispersion information in an urban environment. The dataset of this experiment can offer validations for further numerical simulations.

Abstract Conventional vanadium redox flow batteries (VRFBs) using Nafion 115 suffered from issues associated with high ohmic resistance and high capital cost. In this work, we report a commercial membrane (VANADion), consisting of a porous layer and a dense Nafion layer, as a promising alternative to Nafion 115. In the dual-layer structure, the porous layer (∼210 μm) can offer a high ionic conductivity and the dense Nafion layer (∼20 μm) can depress the convective flow of electrolyte through the membrane. By comparing with the conventional Nafion 115 in a VRFB, it is found that the change from the conventional Nafion 115 to the composite one results in an increase in the energy efficiency from 71.3% to 76.2% and an increase in the electrolyte utilization from 54.1% to 68.4% at a current density of as high as 240 mA cm−2. In addition, although two batteries show the comparable cycling performance at current densities ranging from 80 mA cm−2 to 240 mA cm−2, the composite membrane is estimated to be significantly cheaper than the conventional Nafion 115 due to the fact that the porous layer is rather cost-effective and the dense Nafion layer is rather thin. The impressive combination of desirable performance and low cost makes this composite membrane highly promising in the VRFB applications.

Ternary OSCs fabricated with two acceptors with similar absorption spectra achieved the best PCE of 14.13% with an impressive FF of 78.2%.

Global urban development is increasingly becoming an aspect of focus as nations fight sustainability challenges. A review of the current literature on urban sustainability suggests that research on development of cities, in both developed and developing countries, is growing fast, with an emphasis on sustainable development. However, very little of this research contains an integrated framework to systematically identify and examine the various dimensions of urban sustainability and to measure and evaluate them appropriately. Cities are more than the sum of their sectors, and are complex and interdependent systems on whose dynamics the quality of life of millions of human beings and a good part of the economy depend. Environmental, economic, social and governance problems can create formidable barriers to urban sustainability. Governance remains a critically important dimension of urban sustainability, especially when discussing urbanization in developing countries, given rapid population movements and imbalances in socio-economic development. Understanding how cities function is fundamental to resolving these imbalances. The aim of this paper is to provide a review and analysis of the concept of urban sustainability and to propose the development of a holistic framework through integration of environmental, economic, social, and governance dimensions of sustainability. Such a review would make it possible to understand the complex dynamics of the four dimensions and to assess the progress and challenges in moving towards urban sustainability, taking the case of Nairobi, Kenya, as an example. The paper argues that, for urban sustainability in developing countries, more emphasis should be placed on the governance dimension, because this is where the biggest challenge exists, with increasing needs for immediate management of rapid urbanization.

Zinc oxide (ZnO) nanostar synthesized by simple and up-scalable microwave-assisted surfactant free hydrolysis method was applied as catalyst for biodiesel synthesis through one-step simultaneous esterification and transesterification from high free fatty acid (FFA) contaminated unrefined feedstock. It was found that ZnO nanostar catalyst was reacted with FFA to yield zinc oleate (ZnOl) as intermediate and finally became zinc glycerolate (ZnGly). With the re-deposition of ZnGly back to the ZnO nanostar catalyst at the end of the reaction, the catalyst can be easily recovered and stay active for five cycles. Furthermore, the rate of transesterification is highly promoted by the presence of FFA (6 wt.%) which makes it an efficient catalyst for low grade feedstock like waste cooking oil and crude plant oils.

AbstractAlthough transition metal phosphide electrocatalysts display unique electronic structure that serves as functional centers for hydrogen evolution reaction, the synthesis of this class of materials for oxygen evolution remains a challenge due to the complex multielectron transfer pathways and sluggish reaction kinetics. This study details an in‐situ modification and transformation of cyanide‐bridged nickel‐iron (CN‐NiFe) organometallic hybrid into the preferential Fe2P phase with prevailing exposed faceted active centers by leveraging on the facile coordinate cleavage dynamics and compound reactivity of labile metal organic coordination frameworks. The resultant transition metal phosphide attains high electrochemical surface area, low Tafel slope, and low overpotential for the oxygen evolution reaction, while also demonstrating bifunctional electrocatalytic performance for overall water splitting. Comprehensive experimental studies and density functional theory calculations reveal that the exceptional catalytic activity originates from the transformation of framework metallic sites into preferential active sites allows an optimal adsorption of oxygen evolution reaction intermediates.image