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Acidogenic anaerobic fermentation route was explored for the production of bioethanol and volatile fatty acids (VFA) from the press mud (PM) obtained from sugar mill. Slurry was prepared from PM having 10% of total solids and the same was hydrolyzed under acidic thermal conditions. Both press mud slurry (PMS) and pre-treated press mud slurry (PTPMS) was used as feedstock with mixed microbial consortia (MMC) and enriched mixed microbial consortia (EMMC). Mix of bioethanol and VFA were obtained in all the four cases (PMS-MMC, PMS-EMMC, PTPMS-EMC and PTPMS-EMMC), but, bioethanol and VFA yield of 0.04 g/g and 0.27 g/g, respectively obtained from PTPMS with EMMC was found to be comparatively higher. Control experiments carried out with glucose yielded bioethanol and VFA of 0.042 g/g and 0.28 g/g, respectively demonstrating that the organism was using reducible sugars in the feedstock for the generation of bioethanol by simultaneously producing the VFA from COD.

The current status and challenges associated with the production and utilization of cellulosic ethanol in Korea are reviewed in this paper. Cellulosic ethanol has emerged as a promising option for mitigating Korea's CO(2) emissions and enhancing its energy security. Korea's limited biomass resources is the most critical barrier to achieving its implementation targets for cellulosic ethanol. Efforts to identify new suitable biomass resources for cellulosic ethanol production are ongoing and intensive. Aquatic biomasses including macroalgae and plantation wastes collected in the Southeast Asia region have been found to have great potential as feedstocks for the production of cellulosic ethanol. R&D explorations into the development of technologies that can convert biomass materials to ethanol more efficiently also are underway. It is expected that cellulosic ethanol will be in supply from 2020 and that, by 2030, its use will have effectively reduced Korea's total gasoline consumption by 10%.

Yard waste is either dumped or is being openly burned to get rid of it, instead of using it as a valuable renewable energy source. In this study, hydrothermal carbonization of yard waste was conducted to valorize it as a solid bio fuel, using a batch reactor. The effect of process parameter on yield, energy and physicochemical properties of the valorized solid bio fuel (hydrochar) was examined in this study by varying reaction temperature (160-200 °C for 2 h) and reaction time (2-24 h at 200 °C). The calorific value of hydrochar was within a range of 17.72-24.59 MJ/kg as compared to 15.37 MJ/kg for untreated yard waste. Hydrochar mass yield decreased from 78.6% at operating temperature - time of 160 °C -2 h to 45.6% at 200 °C -24 h. The plot of atomic ratios (H/C and O/C) demonstrates improvement in the coalification process which was mainly governed by decarboxylation and dehydration reactions. The grindability of the prepared hydrochar was comparable to that of coal. Hydrochar produced at lower reaction condition (160-200 °C at 2 h) have better flowability as compared to that produced at higher reaction condition (4-24 h at 200 °C). The reaction time longer than 12 h has a minimal effect on the yield, energy and physicochemical properties of hydrochar. Increasing reaction time and temperature improved the ignition and burnt temperature of hydrochar. All reaction condition has an energy ratio (energy output to energy input) of more than one making HTC process a net energy producer.

Biogas is a viable alternative for supplying clean and sustainable energy. Despite all manner of policy measures introduced by the Government of India, biogas is not widely used in India. This article tries to identify factors that influence the decision to adopt biogas at household level. We examine a conceptual framework empirically in which a household wants to maximize utility from biogas by using the India Human Development Survey (IHDS) I, which is a nationally representative, multi-topic survey. By applying both maximum likelihood and penalized likelihood methods (Firthlogit) of logistic regression on a sample size of almost 10,384 households, it has been found that wealthy people are more likely to adopt biogas compared to the marginalized section of the society. We recommend more inclusive policy measures for the weaker section of the society to create an enabling environment to make it a self-promoting technology.

The influence of various solvents (H2O, CH3OH, and C2H5OH) on product distribution and nature of products during hydrothermal liquefaction of sargassum tenerrimum algae has been examined. Hydrothermal liquefaction was performed using H2O (260, 280 and 300°C) and organic solvents CH3OH and C2H5OH (280°C) for 15min. The use of organic solvents significantly increased the yield of bio-oil. In the case of liquefaction with CH3OH and C2H5OH, the bio-oil yield was 22.8 and 23.8wt.% respectively whereas the bio-oil yield was 16.33wt.% with H2O. GC-MS analysis of the liquid products indicated the presence of various organic compounds including aromatics, nitrogenated and oxygenated compounds and higher selectivity amount of ester compounds were observed in the presence of alcoholic solvents. NMR and FT-IR showed that present of solvents have an effect on the decomposition of sargassum tenerrimum algae.

Anode with good electrocatalytic capabilities is more specifically required to reduce the ohimic losses during microbial fuel cell (MFC) operation. Highly conductive polymers viz., Polyaniline (PANi) and Polyaniline/Carbon nanotube (PANi/CNT) composite were prepared by in situ oxidative chemical polymerization method. Anodes were fabricated independently by coating PANi and CNT/PANi composites on the surface of SSM. The fabricated electrodes were evaluated as anode against stainless steel mess (SSM) as cathode during MFC operation. Maximum bioelectricity generation was observed in SSM-PANi/CNT-anode with power density of 48 mW/m2 and COD removal efficiency of 80% compared with SSM-PANi-anode (38 mW/m2; 65%) and SSM-anode (28 mW/m2; 58%). Bioelectrochemical characterization of the electrode materials using cyclic voltammetry and electrochemical impedance spectroscopy showed high electrocatalytic activity of PANi/CNT composite electrode. The study concluded the efficiency of PANi/CNT composite electrodes as bioanode in operation of MFCs towards achieving increased bioelectricity production along with wastewater treatment.

Abstract Biodiesel has gained the forefront of our focus on renewable transportation fuels. This article provides a comprehensive review on the sources used as feedstock and their classification based on generation or type (edible, non-edible, waste resources and animal fats) along with a variety of classical and modern oil extraction techniques. The technical aspects of the various biodiesel production methods currently implemented to the best of our knowledge are discussed here, which include in-situ biodiesel production, both catalysed (homogeneous and heterogeneous systems) and uncatalysed classical production approaches, with emphasis on how each of these approaches are affected by their reaction parameters. The review also highlights the observed drawbacks of each process with a view to assessing the implementation of supercritical and superheated technologies as an alternative, economically feasible advancement. Supercritical process (SCP) has shown great prospect in the obtainment of high quality biodiesel from a wide range of high to low grade feedstock with minimal impacts on the presence of water or FFAs (free fatty acids). From available literature it is shown that these do not affect the process significantly, and various other supercritical fluids such as methyl acetate, tert-butyl methyl ether (MTBE) and dimethyl carbonate can also be used to avoid glycerol formation. The process however, suffers from high initial implementation cost being the most prominent drawback, among others like thermal degradation of the fuel. Another promising technique, the superheated vapour technology (SHV) has emerged as an alternative, with limited literature proving the superiority of either of these processes to be inconclusive. In future works, researchers need to look into various aspects such as developing a spiral reactor for heat recovery, using software based optimization for eliminating redundant experiments analysing production cost for industrial scale-up and improving the fuel’s oxidative stability by adding antioxidants for convenient long-term storage and use.

Abstract Globally, three-quarter of a billion people live without electricity. Besides, hundreds of million use a solar lantern for less than 4 h a day. Most of the access-deprived are in the Global South, predominantly in Sub-Saharan Africa and South Asia. The United Nations framed the seventh Sustainable Development Goal to improve access. Solar photovoltaic powered mini-grids are increasingly extending better service to deprived regions. However, poor load-factor and expensive storage adversely affect viability. Also, these mini-grids do not support infrequent large loads to avoid further loss of load-factor. Electric cooking is efficient and non-polluting; water treatment facilities can save millions from contaminant and pathogen by providing clean water. Besides, both electric cooking and water treatment are less expensive than alternatives. But mini-grids frequently do not support these. Indeed, the presence of sustained productive loads favourably influences the mini-grid economy. This study investigates the role of critical household loads to deliver similar bearing on the mini-grid economy. Results underscore realisation of desirable impact with household collaboration under a demand-response program. Collaborative consumption can lower initial investment by 62% and reduce the unit energy cost to $0.23. Also, cooperation improves the mini-grid load factor and promotes viability. Additionally, fast deployment needs during and after Covid-19 remains inherently supported while mitigating the pandemic induced financial stress of both consumer and mini-grid operator. This study of 88 nation-states underscores that demand response in a mini-grid can not only improve affordability for all consumers, but it can also bring 186 million people within affordable access.

Abstract Sugarcane is a major crop cultivated globally and the residue left over after the crop harvest and extraction of juice is a good biomass source that can be used for the production of several useful chemicals. The sugarcane bagasse is an excellent substrate for the production of various biochemicals and enzymes through fermentation. Now major interest is focused on the utilization of these residue for biofuel production. The sugarcane crop residue is rich in cellulose and hemicellulose, hence it can be used for the production of bioethanol and other liquid transportation fuels. The present review gives a detailed account of the availability of sugarcane residue and various commercially important products that can be produced from this residue. It also provides recent developments in R&D on the bioconversion of sugarcane crop residue for value added products.