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Abstract In recent years living walls have increasingly spread, thus becoming a diffuse architectural envelope cladding technology. Consequently, a more precise understanding of their thermal behavior and impact on the building energy balance are needed. One of the most important effects provided by the use of living walls is the shading of the building envelope, with clear benefits during the cooling period. Furthermore, many features characterize the thermal behavior of living walls, namely plant species, leaf area index (LAI), evapotranspiration, emissivity and air cavity type. All these particular characteristics have been accounted in the mathematical model developed in the frame of the presented research, whose aim is to provide a tool for the prediction of the thermal behavior of living walls. Two kinds of living walls, one with grass and closed air cavity and the other one with vertical garden and open air cavity were considered. The results achieved by means of the developed model show a good agreement with the measurements also supported by model efficiency indexes such as Nash–Sutcliffe efficiency index (NSEC). Values of around 0.7 were obtained for the NSEC index for both the investigated living walls.

Abstract In recent years living walls have increasingly spread, thus becoming a diffuse architectural envelope cladding technology. Consequently, a more precise understanding of their thermal behavior and impact on the building energy balance are needed. One of the most important effects provided by the use of living walls is the shading of the building envelope, with clear benefits during the cooling period. Furthermore, many features characterize the thermal behavior of living walls, namely plant species, leaf area index (LAI), evapotranspiration, emissivity and air cavity type. All these particular characteristics have been accounted in the mathematical model developed in the frame of the presented research, whose aim is to provide a tool for the prediction of the thermal behavior of living walls. Two kinds of living walls, one with grass and closed air cavity and the other one with vertical garden and open air cavity were considered. The results achieved by means of the developed model show a good agreement with the measurements also supported by model efficiency indexes such as Nash–Sutcliffe efficiency index (NSEC). Values of around 0.7 were obtained for the NSEC index for both the investigated living walls.

Recycled waste materials obtained from industrial and agricultural processes are becoming promising thermal and acoustic insulating solutions in building applications; their use can play an important role in the environmental impact reduction. The aim of the present paper is the evaluation of the thermal performance of recycled waste panels consisting of cork scraps, rice husk, coffee chaff, and end-life granulated tires, glued in different weight ratios and pressed. Six panels obtained from the mixing of these waste materials were fabricated and analyzed. In particular, the scope is the selection of the best compromise solutions from the thermal and environmental points of view. To this aim, thermal resistances were measured in laboratory and a Life Cycle Assessment (LCA) analysis was carried out for each panel; a cross-comparative examination was performed in order to optimize their properties and find the best panels solutions to be assembled in the future. Life Cycle Analysis was carried out in terms of primary Embodied Energy and Greenhouse Gas Emissions, considering a ‘‘cradle-to-gate” approach. The obtained thermal conductivities varied in the 0.055 to 0.135 W/mK range, in the same order of magnitude of many traditional systems. The best thermal results were obtained for the panels made of granulated cork, rice husk, and coffee chaff in this order. The rubber granulate showed higher values of the thermal conductivity (about 0.15 W/mK); a very interesting combined solution was the panel composed of cork (60%), rice husk (20%), and coffee chaff (20%), with a thermal conductivity of 0.08 W/mK and a Global Warming Potential of only 2.6 kg CO2eq/m2. Considering the Embodied Energy (CED), the best solution is a panel composed of 56% of cork and 44% of coffee chaff (minimum CED and thermal conductivity).

Recycled waste materials obtained from industrial and agricultural processes are becoming promising thermal and acoustic insulating solutions in building applications; their use can play an important role in the environmental impact reduction. The aim of the present paper is the evaluation of the thermal performance of recycled waste panels consisting of cork scraps, rice husk, coffee chaff, and end-life granulated tires, glued in different weight ratios and pressed. Six panels obtained from the mixing of these waste materials were fabricated and analyzed. In particular, the scope is the selection of the best compromise solutions from the thermal and environmental points of view. To this aim, thermal resistances were measured in laboratory and a Life Cycle Assessment (LCA) analysis was carried out for each panel; a cross-comparative examination was performed in order to optimize their properties and find the best panels solutions to be assembled in the future. Life Cycle Analysis was carried out in terms of primary Embodied Energy and Greenhouse Gas Emissions, considering a ‘‘cradle-to-gate” approach. The obtained thermal conductivities varied in the 0.055 to 0.135 W/mK range, in the same order of magnitude of many traditional systems. The best thermal results were obtained for the panels made of granulated cork, rice husk, and coffee chaff in this order. The rubber granulate showed higher values of the thermal conductivity (about 0.15 W/mK); a very interesting combined solution was the panel composed of cork (60%), rice husk (20%), and coffee chaff (20%), with a thermal conductivity of 0.08 W/mK and a Global Warming Potential of only 2.6 kg CO2eq/m2. Considering the Embodied Energy (CED), the best solution is a panel composed of 56% of cork and 44% of coffee chaff (minimum CED and thermal conductivity).

AbstractThe aim is to develop a catalysed water-based capture process, avoiding the energy intensive steam stripping steps necessary with amine solvents. The naturally occurring zinc metallo-enzyme carbonic anhydrase/hydratase (CAH) can concentrate CO2 using a reversible hydration/dehydration cycle at neutral pH and at ambient temperatures. Some tripodal complexes of zinc (II)–[zinc-itrilo-tris(2-benzimidazoyl-methyl-6-sulfonic acid, (zinc-L1S), and zinc-tris(2-benzimidazoylmethyl)-amine, (zinc-LI)], and also cadmium (II), cobalt (II) and other metals complexed to these tripodal ligands have been prepared, and show activity that mimics the CAH catalytic process–hydration of CO2 to bicarbonate followed by the reverse dehydration of the bicarbonate to regenerate CO2 in a pH dependent mechanism. The thermal stability of these complex catalysts has been demonstrated by Differential Thermo-Gravimetric (DTG) studies to above 200 °C. A process for fast absorption/desorption is proposed.

AbstractThe aim is to develop a catalysed water-based capture process, avoiding the energy intensive steam stripping steps necessary with amine solvents. The naturally occurring zinc metallo-enzyme carbonic anhydrase/hydratase (CAH) can concentrate CO2 using a reversible hydration/dehydration cycle at neutral pH and at ambient temperatures. Some tripodal complexes of zinc (II)–[zinc-itrilo-tris(2-benzimidazoyl-methyl-6-sulfonic acid, (zinc-L1S), and zinc-tris(2-benzimidazoylmethyl)-amine, (zinc-LI)], and also cadmium (II), cobalt (II) and other metals complexed to these tripodal ligands have been prepared, and show activity that mimics the CAH catalytic process–hydration of CO2 to bicarbonate followed by the reverse dehydration of the bicarbonate to regenerate CO2 in a pH dependent mechanism. The thermal stability of these complex catalysts has been demonstrated by Differential Thermo-Gravimetric (DTG) studies to above 200 °C. A process for fast absorption/desorption is proposed.

Developing causal loop diagrams (CLDs) involves identifying stakeholders and endogenous variables and formulating variable causal relationships. Traditionally, the CLDs are developed mainly using a qualitative approach such as literature review, observations and interviews with stakeholders. However, modellers may question which stakeholders should be approached, whether the relevant variables are selected, and what to do when stakeholders perceive different variable relationships in the CLDs differently. Applying in a case study, this research proposes a multi-method approach by combining both quantitative and qualitative methods to select stakeholders, identify endogenous/exogenous variables, and develop the CLDs. The proposed quantitative method is expected to provide modellers with a justifiable stakeholder and variable selection process. The method also highlights possible hidden variables and relationships, which were further explored with a traditional qualitative approach.