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Deposits formation on heat transfer surfaces is one of the main problems associated to biomass co-combustion. It reduces plant efficiency and availability and increases maintenance costs. It is obvious that an increasing amount of low-temperature melting components in fuel ash accelerates and aggravates this process. Research is done to evaluate the validity of thermal analysis methods to characterise fusion of biomass and waste ashes. Laboratory ashes from a set of biomass and waste fuels are leached in successive steps. The original and the leached ashes are analysed by Thermo-Mechanical Analysis (TMA). Traces obtained from TMA show to be promising ash fingerprints to classify deposition tendencies. Additionally Simultaneous Thermal Analysis (STA) is performed on selected samples. Furthermore, improved chemical equilibrium calculations are proposed to predict the proportion of melted species resulting from combustion of biomass fuels. The model takes into account the reactivity of the inorganic matter in the fuel as issued from ash leaching.

In future distribution grids, prosumers (i.e., energy consumers with storage and/or production capabilities) will trade energy with each other and with the main grid. To ensure an efficient and safe operation of energy trading, in this paper, we formulate a peer-to-peer energy market of prosumers as a generalized aggregative game, in which a network operator is only responsible for the operational constraints of the system. We design a distributed market-clearing mechanism with convergence guarantee to an economically-efficient and operationally-safe configuration (i.e., a variational generalized Nash equilibrium). Numerical studies on the IEEE 37-bus testcase show the scalability of the proposed approach and suggest that active participation in the market is beneficial for both prosumers and the network operator. 11 pages, 8 figures. Published in IEEE Transactions on Smart Grid, 2022

Abstract A simple way to improve its power coefficient (cp) of a Savonius turbine is by its installation above a cuboidal building as the building will redirect the wind and increase its speed significantly. To determine the gain, a turbine was constructed and installed above a bluff body and tow tested. Detailed measurements of vehicle speed and turbine power were made. Tow test speeds were 8, 10 and 12 m/s, while TSR range was 0.6–1.1. Most importantly, wind speed at the position beside and slightly above the turbine was measured during test runs. The cp calculated using this measured wind speed was used to validate CFD simulation results. Simulation results were also used to obtain the relationships between the wind speed of the free stream and at the anemometer position. Typically, wind speed at the anemometer position is about 9% higher than those of the free stream. These relationships were used to derive the free stream wind speed of each experimental run. The cp calculated using these derived free stream wind speeds showed an increase of 25% at 12 m/s wind speed, compared to the cp reported by previous researchers for a similar turbine operating in unmodified air flow.

Gasification is considered to be a promising way to use biomass with high efficiency in combined heatand power production, for the production of second generation biofuels and in the chemical industry.Especially allothermal fluidized bed steam gasification produces a medium calorific, nitrogen free gassuitable for a variety of downstream processes. In general the raw product gas has to be cleaned fromcondensable hydrocarbons (tar) and conditioned (e.g. adjustment of the H2/CO-ratio) before downstreamuse. The operating conditions of the gasification reactor have a large impact on the quality of the productgas. Hence first steps to a product gas low in tar content can be undertaken directly in the reactor. In thisstudy the capability of influencing the tar content and gas composition by changing temperature (750?840 C), steam to biomass (S/B) ratio (0.8?1.2) and pressure (0.1?0.25 MPa) in an allothermal bubblingfluidized bed steam gasifier is investigated. It is found that rising temperature reduces the total tar contentand affects especially heterocyclic and light aromatic compounds. At atmospheric pressure the naphthalenecontent increases slightly with increasing temperature in contrary to pressurized gasificationwhere naphthalene decreases significantly with increasing temperature. An increase in the S/B ratio leadsto a decreasing total tar content, this tar reduction according to a higher steam content is higher at highertemperatures. Increasing pressure leads to increasing total tar content mainly due to naphthalene, theeffect is most distinct for low S/B ratios.

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This study focuses on formulating the most sustainable concrete by incorporating recycled concrete aggregates and other products retrieved from construction and demolition (C&D) activities. Both recycled coarse aggregates (RCA) and recycled fine aggregates (RFA) are firstly used to fully replace the natural coarse and fine aggregates in the concrete mix design. Later, the cement rich ultrafine particles, recycled glass powder and mineral fibres recovered from construction and demolition wastes (CDW) are further incorporated at a smaller rate either as cement substituent or as supplementary additives. Remarkable properties are noticed when the RCA (4–12 mm) and RFA (0.25–4 mm) are fully used to replace the natural aggregates in a new concrete mix. The addition of recycled cement rich ultrafines (RCU), Recycled glass ultrafines (RGU) and recycled mineral fibres (RMF) into recycled concrete improves the modulus of elasticity. The final concrete, which comprises more than 75% (wt.) of recycled components/materials, is believed to be the most sustainable and green concrete mix. Mechanical properties and durability of this concrete have been studied and found to be within acceptable limits, indicating the potential of recycled aggregates and other CDW components in shaping sustainable and circular construction practices. The authors wish to acknowledge the financial support from EU Horizon 2020 Project VEEP ‘‘Cost-Effective Recycling of C&DW in High Added Value Energy Efficient Prefabricated Concrete Compo-nents for Massive Retrofitting of our Built Environment” (No.723582).

Abstract In the present paper, a detailed study of the redox behavior of zirconium in the eutectic LiF-NaF system was carried out on an inert molybdenum electrode at 750 °C. Several transient electrochemical methods were used such as cyclic voltammetry, square wave voltammetry, chronopotentiometry, and open circuit voltammetry. The reduction of Zr (IV) was found to follow a two-step mechanism of Zr (IV)/Zr (II) and Zr (II)/Zr at the potentials of about −1.10 and −1.50 V versus Pt, respectively. The theoretical evaluations of the number of transferred electrons according to both cyclic voltammetry and square wave voltammetry further confirmed the Zr reduction mechanism. The estimations of Zr (IV) diffusion coefficient in the LiF-NaF eutectic melt at 750 °C through cyclic voltammetry and chronopotentiometry are in fair agreement, as to be approximately 1.13E-5 and 2.42E-5 cm 2 /s, respectively.