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Abstract Additional experimental data concerning the kinetics of Ni-Mo codeposition were obtained by investigating cathodic polarization using a rotating disc electrode. The Ni-Mo alloys were deposited from an ammonium citrate bath. The alloy deposition was controlled by activation in the case of low values of the cathode potential and by diffusion in the case of higher values. The hydrogen discharge was found to be diffusion controlled. The inductive influence of nickel results in depolarization of the reduction of molybdenum which cannot be deposited separately. An increase in the disc rotation speed caused an increase in the maximum cathode efficiency and in the molybdenum content of the alloy.

Technical solutions for optimizing the flame aerodynamics and the design of tangentially arranged burners in a TGMP-314 boiler are proposed. The implementation of these solutions will make it possible to achieve more reliable operation of the boiler during fuel oil combustion, smaller amount of NOx emissions during the combustion of gas and fuel oil, and a somewhat lower air excess factor in the furnace.

This paper analyzes the general issues of sectionalizing 110- and 220-kV distribution grids, including by current limiting. The results of calculations of transients in the event of various disturbances in the distribution network, taking into account the operation of emergency control devices, are presented. The results of comparative analysis of sectionalized and desectionalized distribution grids are presented. The authors hereof propose introducing a load increment safety factor to quantify how sectionalization or desectionalization could affect grid reliability. The paper further substantiates the need for accounting excess disturbances in sectionalized grids to design and implement measures to minimize accident-related losses. It analyzes the effectiveness of applying automatic load transfer (ALT) and draws recommendations on how to implement it.

For economic reasons, expansions of transmission networks are based on a compromise between capital cost and security of power system operation. At the same time, the power system must withstand typical highly likely contingencies. Various emergency state control systems, also called special protections, prevent emergencies following less likely contingencies. This paper describes overloads emergency state control (OLEC) used for the alleviation of overload in transmission networks near a power plant. Such control uses the functions of automated power reduction of generating units and has been implemented for a large steam power plant. The OLEC presented here uses different methods of generation curtailment for steam generation units. A case study illustrates the efficiency of the proposed control method.

The temperature dependence of the electrical conductivity of the molten eutectic GdCl3(0.515)–KCl(0.485) containing up to 3.3 mol % gadolinium oxide is studied. The temperature dependences of the conductivity of the molten GdCl3–KCl–Gd2O3 system are approximated by second-order polynomials. The formation of gadolinium oxychlorides is confirmed by spectral studies of the solidified melt.

Two approaches to synthesis of unsymmetrical disulfides based on different types of thiol activation, namely, an electrochemical method in the presence of a redox mediator and a microwave irradiation, were discussed. The mediated electrosynthesis procedures were carried out by the oxidative coupling of thiols or by the thiol-disulfide exchange in the presence of redox pairs—substituted o-aminophenol/o-iminobenzoquinone. It has been established that the formation of unsymmetrical disulfides under electrochemical conditions occurs as a result of both the oxidative coupling of sulfur-centered radicals, and a redox-mediator promoted thiol-disulfide exchange, which led to a high yield of heterodimeric products (89%–99%). The microwave-assisted synthesis made it possible to obtain the target products with yields of 13%–86% depending on different irradiation parameters such as power, temperature, and irradiation duration. However, this method requires a rigorous selection of conditions for each reaction and is therefore inferior to the electrochemical approach.

We have developed algorithms and programs for automated tests of synchronous machines. The programs were made using the LabVIEW development system. They are interrelated and have been combined into one software system. An approximation of its characteristics using regression equations of different orders with mean-square rate control is used in the algorithms to determine static parameters. A combined optimizing algorithm that is based on the least squares method and alternating-variable descent method is used to determine dynamic parameters. A new effective and adaptive method of sliding trigonometric interpolation is used to filter out possible noise in measuring channels of voltage and current sensors, while determining the parameters of sinusoidal signals in the stationary modes and dots of envelope curves in the transient modes. To reduce the time needed to obtain static characteristics, the software has a special virtual instrument with a field current control loop with a PID controller that provides desired field forcing. The SMTest software system has been tested using HIL modeling and laboratory test stations. Analysis of test results shows that, even when the acquired signal has a 30% noise level, the calculation error in the determination of parameters does not exceed 6%. The software, when used in stationary or mobile test stations, allows automating the process of obtaining characteristics and determining the main static and dynamic parameters of midand high-power rotor synchronous machines.

This short report substantiates the advisability of developing a two-stage model for the emergence and development of a boiling crisis. One of the stages is the violation of the stability of the two-phase wall layer, and the other is the appearance and fusion of dry spots on the heating surface. The use of a two-stage (“temporary”) model makes it possible to combine both well-known approaches to crisis analysis—hydrodynamic and thermal—in a single logical system. In the first approach, the characteristics of the boiling crisis are characteristic of high pressures in a boiling liquid, while those in the second are for low pressures.

Abstract Coal gasification is accompanied with formation of tars that cause equipment problems and have to be removed from the raw gas. Our previous studies proved that nickel supported ceria-zirconia catalyst (Ni/CZ) reveals high activity towards decomposition of toluene and 1-methylnaphthalene (1-MN) via steam reforming reaction (SR). However, the components of the raw gas from coal gasification (i.e. H2, CO, CO2 and CH4) may influence the performance of Ni/CZ catalyst. The influence of particular components of the raw gas on catalyst performance during SR of model tar compounds have been studied and discussed in this paper. It has been found that H2 and CO addition to the steam reforming feed drastically decreases the activity of Ni/CZ catalyst, whereas CO2 presence enhances conversion of toluene and 1-MN mixture owing to the occurrence of dry reforming reaction (DR). It has also been observed that methane, which is present in the raw gas from coal gasification consumes partly both the H2O and CO2, causing some decrease in conversion of model tar compounds. The influence of contact time (tc) on hydrocarbons conversion and the participation of (DR) have been examined. As was observed, lower contact times lead to decrease in hydrocarbons conversion in SR, making the same participation of DR more pronounced than for higher tc values. This work proves that Ni/CZ catalyst can be used for removal of tarry compounds via the catalytic hot gas cleaning of the raw gas form coal gasification.