• Energy Research

Abstract The optical constants of many metals commonly used in solar cells, e.g. as contacts, rear side planar reflectors, or more complex nanopatterned light-trapping structures, can vary depending on deposition method, thickness and other factors, and as such are not documented consistently in the literature. In the case of nanometallic light-trapping structures specifically designed to improve absorption in a solar cell, the choice of optical constants used in simulations significantly affects the predicted enhancement, as well as the structure's optimal dimensions. The trade-off between coupling into guided modes in the photovoltaic material and the number of photons absorbed parasitically in the metal leads to small differences in the optical constants giving significantly different results for the quantum efficiency and photogenerated current. This work documents several optical constant sources for silver, aluminium, gold and titanium, and the effect this has on plasmon quality factors. The effect of choosing different optical constant sources on modelling outcomes is quantified by considering the optimization of a test structure comprising a grid of metal nanodisks on the front surface of a thinned-down GaAs cell. Finally, we define a new spectrally-integrated figure of merit for comparing the expected performance of metals in light-trapping structures based on their optical constants, which we name the spectral absorption enhancement factor (SAEF).

Efficiency limits for multi-junction solar cells with up to six junctions and arbitrary colour produced by reflecting Sunlight.

Abstract We investigate the use of distributed Bragg reflectors (DBRs) within triple-junction solar cells (TJSC) for spectrum splitting photovoltaics. An optical model of a lattice-matched (LM) GaInP/GaInAs/Ge TJSC with intermediate DBR is developed, in good agreement with measured reflectance. By modifying the DBR layer number, composition and thickness to broaden the reflectance band, we show that a DBR can provide suitable 900–1050 nm reflectance for spectrum splitting from the LM TJSC to a Si cell, resulting in a more efficient 4-junction receiver. For better practicality and cost effectiveness, we propose that the buffer layers in metamorphic (MM) TJSCs could additionally function as a DBR for spectrum splitting applications. We propose several DBR designs to achieve a suitable spectrum-splitting reflectance band from MM TJSCs to a Si cell, again resulting in a more efficient 4-junction receiver. Finally, we show that our intermediate DBR approach to spectrum splitting has the advantage of a greatly reduced angle-of-incidence dependence compared to a discrete dielectric filter.

Abstract Since 2010, over 700,000 small-scale solar photovoltaic (PV) systems have been installed by households in Great Britain and registered under the feed-in tariff (FiT) scheme. This paper introduces a new agent-based model which simulates this adoption by considering decision-making of individual households based on household income, social network, total capital cost of the PV system, and the payback period of the investment, where the final factor takes into account the economic effect of FiTs. After calibration using Approximate Bayesian Computation, the model successfully simulates observed cumulative and average capacity installed over the period 2010–2016 using historically accurate FiTs; setting different tariffs allows investigation of alternative policy scenarios. Model results show that using simple cost control measures, more installation by October 2016 could have been achieved at lower subsidy cost. The total cost of supporting capacity installed during the period 2010–2016, totalling 2.4 GW, is predicted to be £14 billion, and costs to consumers significantly exceed predictions. The model is further used to project capacity installed up to 2022 for several PV cost, electricity price, and FiT policy scenarios, showing that current tariffs are too low to significantly impact adoption, and falling PV costs are the most important driver of installation.

The limiting efficiency for series-connected multijunction solar cells is usually calculated from the assumption that the individual junctions are optically isolated. Here, we develop an analytical formalism to predict efficiencies attainable in the presence of luminescent coupling, i.e., if the individual junctions in a series-connected multijunction stack are coupled optically, so that luminescence from one junction can be absorbed by the lower bandgap junction below. The formalism deals with nonradiative recombination through the definition of the luminescence extraction efficiency. Using our general formalism, we find that the limiting efficiency of a tandem cell becomes much less dependent on exact bandgap combination when luminescent coupling is considered and proceed to consider two technologically important examples of current-mismatched tandem solar cells. We find that a series-connected GaAs on a silicon tandem cell can be more efficient than the underlying silicon cell alone, if the luminescence extraction efficiency of the GaAs junction is sufficient. An analysis of luminescent coupling in a perovskite on a silicon tandem cell shows that the efficiency penalty for a perovskite bandgap below the optimum value can be mitigated if the luminescence extraction efficiency is high. We suggest that material quality and stability might be more important considerations for perovskite on silicon tandems than engineering the bandgap to achieve precise current matching.

AbstractUltra‐thin photovoltaics enable lightweight flexible form factors, suitable for emerging terrestrial applications such as electric vehicle integration. These devices also exhibit intrinsic radiation tolerance and increased specific power and so are uniquely enabling for space power applications, offering longer missions in hostile environments and reduced launch costs. In this work, a GaAs solar cell with an 80‐nm absorber is developed with short circuit current exceeding the single pass limit. Integrated light management is employed to compensate for increased photon transmission inherent to ultra‐thin absorbers, and efficiency enhancement of 68% over a planar on‐wafer equivalent is demonstrated. This is achieved using a wafer‐scale technique, displacement Talbot lithography, to fabricate a rear surface nanophotonic grating. Optical simulations definitively confirm Fabry‐Perot and waveguide mode contributions to the observed increase in absorption and also demonstrate a pathway to short circuit current of 26 mA/cm2, well in excess of the double pass limit.

The aim of this work is to evaluate whether silicon heterojunction solar cells, lacking highly emissive, heavily doped silicon layers, could be better candidates for hybrid photovoltaic thermal collectors than standard aluminium-diffused back contact solar cells. To this end, the near and mid infrared emissivity of full silicon heterojunction solar cells, as well as of its constituent materials – crystalline silicon wafer, indium tin oxide, n-, i- and p-type amorphous silicon – have been assessed by means of ellipsometry and FTIR. The experimental results show that the thermal emissivity of these cells is actually as high as in the more traditional structures, ~80% at 8 μm. Detailed optical modelling combining raytracing and transfer matrix formalism shows that the emissivity in these cells originates in the transparent conductive oxide layers themselves, where the doping is not high enough to result in a reflection that exceeds the increased free carrier absorption. Further modelling suggests that it is possible to obtain lower emissivity solar cells, but that a careful optimization of the transparent conductive layer needs to be done to avoid hindering the photovoltaic performance.