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description Publicationkeyboard_double_arrow_right Article 2022 ItalyPublisher:Springer Science and Business Media LLC Funded by:MIURMIURAuthors: Alberto Castellini; Federico Bianchi; Alessandro Farinelli;handle: 11562/1060707
Forecasting future heat load in smart district heating networks is a key problem for utility companies that need such predictions for optimizing their operational activities. From the statistical learning viewpoint, this problem is also very interesting because it requires to integrate multiple time series about weather and social factors into a dynamical model, and to generate models able to explain the relationships between weather/social factors and heat load. Typical questions in this context are: “Which variables are more informative for the prediction?” and “Do variables have different influence in different contexts (e.g., time instant or situations)?” We propose a methodology for generating simple and interpretable models for heat load forecasting, then we apply this methodology to a real dataset, and, finally, provide new insight about this application domain. The methodology merges multi-equation multivariate linear regression and forward variable selection. We generate a (sparse) equation for each pair day-of-the-week/hour-of-the-day (for instance, one equation concerns predictions of Monday at 0.00, another predictions of Monday at 1.00, and so on). These equations are simple to explain because they locally approximate the prediction problem in specific times of day/week. Variable selection is a key contribution of this work. It provides a reduction of the prediction error of 2.4% and a decrease of the number of parameters of 49.8% compared to state-of-the-art models. Interestingly, different variables are selected in different equations (i.e., times of the day/week), showing that weather and social factors, and autoregressive variables with different delays, differently influence heat predictions in different times of the day/week.
IRIS - Università de... arrow_drop_down IRIS - Università degli Studi di VeronaArticle . 2022License: CC 0Full-Text: https://iris.univr.it/bitstream/11562/1060707/1/castellini_AppliedIntelligence_2022_Preprint.pdfData sources: IRIS - Università degli Studi di Veronaadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1007/s10489-021-02949-4&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess RoutesGreen 6 citations 6 popularity Top 10% influence Average impulse Top 10% Powered by BIP!
more_vert IRIS - Università de... arrow_drop_down IRIS - Università degli Studi di VeronaArticle . 2022License: CC 0Full-Text: https://iris.univr.it/bitstream/11562/1060707/1/castellini_AppliedIntelligence_2022_Preprint.pdfData sources: IRIS - Università degli Studi di Veronaadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1007/s10489-021-02949-4&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Part of book or chapter of book , Article , Conference object 2019 ItalyPublisher:Springer International Publishing Authors: BIANCHI, FEDERICO; A. Castellini; P. Tarocco; A. Farinelli;handle: 11562/1002924
District Heating networks (DHNs) are promising technologies for heat distribution in residential and commercial buildings since they enable high efficiency and low emissions. Within the recently proposed paradigm of smart grids, DHNs have acquired intelligent tools able to enhance their efficiency. Among these tools, there are demand forecasting technologies that enable improved planning of heat production and power station maintenance. In this work we propose a comparative study for heat load forecasting methods on a real case study based on a dataset provided by an Italian utility company. We trained and tested three kinds of models, namely non-autoregressive, autoregressive and hybrid models, on the available dataset of heat load and meteorological variables. The optimal model, in terms of root mean squared error of prediction, was selected. It considers the day of the week, the hour of the day, some meteorological variables, past heat loads and social components, such as holidays. Results show that the selected model is able to achieve accurate 48-hours predictions of the heat load in several conditions (e.g., different days of the week, different times, holidays and workdays). Moreover, an analysis of the parameters of the selected models enabled to identify a few informative variables.
https://doi.org/10.1... arrow_drop_down https://doi.org/10.1007/978-3-...Part of book or chapter of book . 2019 . Peer-reviewedLicense: Springer TDMData sources: CrossrefIRIS - Università degli Studi di VeronaConference object . 2020Data sources: IRIS - Università degli Studi di Veronaadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1007/978-3-030-37599-7_46&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu8 citations 8 popularity Top 10% influence Average impulse Top 10% Powered by BIP!
more_vert https://doi.org/10.1... arrow_drop_down https://doi.org/10.1007/978-3-...Part of book or chapter of book . 2019 . Peer-reviewedLicense: Springer TDMData sources: CrossrefIRIS - Università degli Studi di VeronaConference object . 2020Data sources: IRIS - Università degli Studi di Veronaadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1007/978-3-030-37599-7_46&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Other literature type , Journal 2016Embargo end date: 01 Jan 2016 Germany, Switzerland, Austria, United States, AustriaPublisher:Springer Science and Business Media LLC Funded by:EC | ATMNUCLE, AKA | Measurement of Nano-parti..., AKA | Long-term Observation of ... +21 projectsEC| ATMNUCLE ,AKA| Measurement of Nano-particle Nucelation in the Atmosphere via Cluster Ion Mass Spectrometry ,AKA| Long-term Observation of Ambient Nanoclusters and targeted laboratory experiments ¿ bridging the gap between the particle and gas phase ¿LOAN¿ ,AKA| Infrastructure of Environmental and Atmospheric Sciences (ATM-Science) ,UKRI| Developing a framework to test the sensitivity of atmospheric composition simulated by ESMs to changing climate and emissions ,SNSF| Analysis of the chemical composition of nucleating clusters with Atmospheric Pressure Interface Time of Flight Mass Spectrometry ,EC| NANODYNAMITE ,EC| CLOUD-TRAIN ,AKA| Formation and growth of atmospheric aerosol particles: from molecular to global scale ,SNSF| CLOUD ,NSF| Mixing Thermodynamics in Atmospherically Relevant Organic Aerosol Systems ,AKA| Formation and growth of atmospheric aerosol particles: from molecular to global scale ,EC| nanoCAVa ,NSF| Coupling of Gas-Phase Radical Oxidation Chemistry and Organic-Aerosol Formation ,FWF| A Multi-Channel Expansion Type Condensation Particle Counter ,AKA| Nucleation of particles and ice in the atmosphere: from surface layer to upper troposphere ,AKA| ATMOSPHERIC SCIENCES - Particularly for determination of cluster and nanoaerosol composition ,SNSF| CLOUD ,SNSF| Investigation of new particle formation in the CLOUD chamber at CERN and the PSI smog chamber ,ANR| Cappa ,NSF| Constraining the Role of Gas-Phase Organic Oxidation in New-Particle Formation ,SNSF| Buffer-Capacity-based Livelihood Resilience to Stressors - an Early Warning Tool and its Application in Makueni County, Kenya ,SNSF| Ambient particles and their health effects on the susceptible population: combining particle composition with realistic in vitro technology ,AKA| Computational research chain from quantum chemistry to climate change / Consortium: ComQuaCCXuan Zhang; Arnaud P. Praplan; Kirsty J. Pringle; Gerhard Steiner; Gerhard Steiner; Gerhard Steiner; J. S. Craven; Mario Simon; Anne-Kathrin Bernhammer; Sebastian Ehrhart; Sebastian Ehrhart; Tuukka Petäjä; Tuomo Nieminen; Tuomo Nieminen; Claudia Fuchs; Douglas R. Worsnop; Douglas R. Worsnop; Paul M. Winkler; Yuri Stozhkov; Siegfried Schobesberger; Siegfried Schobesberger; Jonathan Duplissy; Jonathan Duplissy; N. A. D. Richards; Juha Kangasluoma; Xuemeng Chen; John H. Seinfeld; Hamish Gordon; Christopher R. Hoyle; Carla Frege; António Amorim; Antti Onnela; F. Bianchi; F. Bianchi; Mikko Sipilä; Mikko Sipilä; Serge Mathot; Ugo Molteni; Kamalika Sengupta; Kenneth S. Carslaw; Andreas Kürten; Penglin Ye; Jaeseok Kim; Jaeseok Kim; Jasmin Tröstl; Heikki Junninen; Joao Almeida; Joao Almeida; Ernest Weingartner; Chao Yan; Jasper Kirkby; Jasper Kirkby; Ismael K. Ortega; Ari Laaksonen; Ari Laaksonen; Nina Sarnela; Armin Hansel; Alexandru Rap; Jani Hakala; Frank Stratmann; Neil M. Donahue; Richard C. Flagan; Matti P. Rissanen; Linda Rondo; Alexey Adamov; Markku Kulmala; Markku Kulmala; Sophia Brilke; António Tomé; Roberto Guida; Otso Peräkylä; Manuel Krapf; Josef Dommen; Martin Heinritzi; Martin Heinritzi; Alexander L. Vogel; Martin Breitenlechner; Christina Williamson; Christina Williamson; Alessandro Franchin; Robert Wagner; Felix Piel; Ilona Riipinen; Tuija Jokinen; Antonio Dias; Daniela Wimmer; Daniela Wimmer; Catherine E. Scott; Joachim Curtius; Urs Baltensperger; Katrianne Lehtipalo; Katrianne Lehtipalo; Andrea Christine Wagner; Vladimir Makhmutov; Paul E. Wagner; Annele Virtanen;AbstractAtmospheric aerosols and their effect on clouds are thought to be important for anthropogenic radiative forcing of the climate, yet remain poorly understood1. Globally, around half of cloud condensation nuclei originate from nucleation of atmospheric vapours2. It is thought that sulfuric acid is essential to initiate most particle formation in the atmosphere3,4, and that ions have a relatively minor role5. Some laboratory studies, however, have reported organic particle formation without the intentional addition of sulfuric acid, although contamination could not be excluded6,7. Here we present evidence for the formation of aerosol particles from highly oxidized biogenic vapours in the absence of sulfuric acid in a large chamber under atmospheric conditions. The highly oxygenated molecules (HOMs) are produced by ozonolysis of α-pinene. We find that ions from Galactic cosmic rays increase the nucleation rate by one to two orders of magnitude compared with neutral nucleation. Our experimental findings are supported by quantum chemical calculations of the cluster binding energies of representative HOMs. Ion-induced nucleation of pure organic particles constitutes a potentially widespread source of aerosol particles in terrestrial environments with low sulfuric acid pollution.
Caltech Authors arrow_drop_down Publication Server of Goethe University Frankfurt am MainArticle . 2016License: CC BYFull-Text: https://doi.org/10.1038/nature17953Data sources: Bielefeld Academic Search Engine (BASE)Caltech Authors (California Institute of Technology)Article . 2016Full-Text: https://doi.org/10.1038/nature17953Data sources: Bielefeld Academic Search Engine (BASE)Hochschulschriftenserver - Universität Frankfurt am MainArticle . 2016Data sources: Hochschulschriftenserver - Universität Frankfurt am Mainadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1038/nature17953&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess RoutesGreen hybrid 553 citations 553 popularity Top 0.1% influence Top 1% impulse Top 0.1% Powered by BIP!
more_vert Caltech Authors arrow_drop_down Publication Server of Goethe University Frankfurt am MainArticle . 2016License: CC BYFull-Text: https://doi.org/10.1038/nature17953Data sources: Bielefeld Academic Search Engine (BASE)Caltech Authors (California Institute of Technology)Article . 2016Full-Text: https://doi.org/10.1038/nature17953Data sources: Bielefeld Academic Search Engine (BASE)Hochschulschriftenserver - Universität Frankfurt am MainArticle . 2016Data sources: Hochschulschriftenserver - Universität Frankfurt am Mainadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1038/nature17953&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu
description Publicationkeyboard_double_arrow_right Article 2022 ItalyPublisher:Springer Science and Business Media LLC Funded by:MIURMIURAuthors: Alberto Castellini; Federico Bianchi; Alessandro Farinelli;handle: 11562/1060707
Forecasting future heat load in smart district heating networks is a key problem for utility companies that need such predictions for optimizing their operational activities. From the statistical learning viewpoint, this problem is also very interesting because it requires to integrate multiple time series about weather and social factors into a dynamical model, and to generate models able to explain the relationships between weather/social factors and heat load. Typical questions in this context are: “Which variables are more informative for the prediction?” and “Do variables have different influence in different contexts (e.g., time instant or situations)?” We propose a methodology for generating simple and interpretable models for heat load forecasting, then we apply this methodology to a real dataset, and, finally, provide new insight about this application domain. The methodology merges multi-equation multivariate linear regression and forward variable selection. We generate a (sparse) equation for each pair day-of-the-week/hour-of-the-day (for instance, one equation concerns predictions of Monday at 0.00, another predictions of Monday at 1.00, and so on). These equations are simple to explain because they locally approximate the prediction problem in specific times of day/week. Variable selection is a key contribution of this work. It provides a reduction of the prediction error of 2.4% and a decrease of the number of parameters of 49.8% compared to state-of-the-art models. Interestingly, different variables are selected in different equations (i.e., times of the day/week), showing that weather and social factors, and autoregressive variables with different delays, differently influence heat predictions in different times of the day/week.
IRIS - Università de... arrow_drop_down IRIS - Università degli Studi di VeronaArticle . 2022License: CC 0Full-Text: https://iris.univr.it/bitstream/11562/1060707/1/castellini_AppliedIntelligence_2022_Preprint.pdfData sources: IRIS - Università degli Studi di Veronaadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1007/s10489-021-02949-4&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess RoutesGreen 6 citations 6 popularity Top 10% influence Average impulse Top 10% Powered by BIP!
more_vert IRIS - Università de... arrow_drop_down IRIS - Università degli Studi di VeronaArticle . 2022License: CC 0Full-Text: https://iris.univr.it/bitstream/11562/1060707/1/castellini_AppliedIntelligence_2022_Preprint.pdfData sources: IRIS - Università degli Studi di Veronaadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1007/s10489-021-02949-4&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Part of book or chapter of book , Article , Conference object 2019 ItalyPublisher:Springer International Publishing Authors: BIANCHI, FEDERICO; A. Castellini; P. Tarocco; A. Farinelli;handle: 11562/1002924
District Heating networks (DHNs) are promising technologies for heat distribution in residential and commercial buildings since they enable high efficiency and low emissions. Within the recently proposed paradigm of smart grids, DHNs have acquired intelligent tools able to enhance their efficiency. Among these tools, there are demand forecasting technologies that enable improved planning of heat production and power station maintenance. In this work we propose a comparative study for heat load forecasting methods on a real case study based on a dataset provided by an Italian utility company. We trained and tested three kinds of models, namely non-autoregressive, autoregressive and hybrid models, on the available dataset of heat load and meteorological variables. The optimal model, in terms of root mean squared error of prediction, was selected. It considers the day of the week, the hour of the day, some meteorological variables, past heat loads and social components, such as holidays. Results show that the selected model is able to achieve accurate 48-hours predictions of the heat load in several conditions (e.g., different days of the week, different times, holidays and workdays). Moreover, an analysis of the parameters of the selected models enabled to identify a few informative variables.
https://doi.org/10.1... arrow_drop_down https://doi.org/10.1007/978-3-...Part of book or chapter of book . 2019 . Peer-reviewedLicense: Springer TDMData sources: CrossrefIRIS - Università degli Studi di VeronaConference object . 2020Data sources: IRIS - Università degli Studi di Veronaadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1007/978-3-030-37599-7_46&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu8 citations 8 popularity Top 10% influence Average impulse Top 10% Powered by BIP!
more_vert https://doi.org/10.1... arrow_drop_down https://doi.org/10.1007/978-3-...Part of book or chapter of book . 2019 . Peer-reviewedLicense: Springer TDMData sources: CrossrefIRIS - Università degli Studi di VeronaConference object . 2020Data sources: IRIS - Università degli Studi di Veronaadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1007/978-3-030-37599-7_46&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eudescription Publicationkeyboard_double_arrow_right Article , Other literature type , Journal 2016Embargo end date: 01 Jan 2016 Germany, Switzerland, Austria, United States, AustriaPublisher:Springer Science and Business Media LLC Funded by:EC | ATMNUCLE, AKA | Measurement of Nano-parti..., AKA | Long-term Observation of ... +21 projectsEC| ATMNUCLE ,AKA| Measurement of Nano-particle Nucelation in the Atmosphere via Cluster Ion Mass Spectrometry ,AKA| Long-term Observation of Ambient Nanoclusters and targeted laboratory experiments ¿ bridging the gap between the particle and gas phase ¿LOAN¿ ,AKA| Infrastructure of Environmental and Atmospheric Sciences (ATM-Science) ,UKRI| Developing a framework to test the sensitivity of atmospheric composition simulated by ESMs to changing climate and emissions ,SNSF| Analysis of the chemical composition of nucleating clusters with Atmospheric Pressure Interface Time of Flight Mass Spectrometry ,EC| NANODYNAMITE ,EC| CLOUD-TRAIN ,AKA| Formation and growth of atmospheric aerosol particles: from molecular to global scale ,SNSF| CLOUD ,NSF| Mixing Thermodynamics in Atmospherically Relevant Organic Aerosol Systems ,AKA| Formation and growth of atmospheric aerosol particles: from molecular to global scale ,EC| nanoCAVa ,NSF| Coupling of Gas-Phase Radical Oxidation Chemistry and Organic-Aerosol Formation ,FWF| A Multi-Channel Expansion Type Condensation Particle Counter ,AKA| Nucleation of particles and ice in the atmosphere: from surface layer to upper troposphere ,AKA| ATMOSPHERIC SCIENCES - Particularly for determination of cluster and nanoaerosol composition ,SNSF| CLOUD ,SNSF| Investigation of new particle formation in the CLOUD chamber at CERN and the PSI smog chamber ,ANR| Cappa ,NSF| Constraining the Role of Gas-Phase Organic Oxidation in New-Particle Formation ,SNSF| Buffer-Capacity-based Livelihood Resilience to Stressors - an Early Warning Tool and its Application in Makueni County, Kenya ,SNSF| Ambient particles and their health effects on the susceptible population: combining particle composition with realistic in vitro technology ,AKA| Computational research chain from quantum chemistry to climate change / Consortium: ComQuaCCXuan Zhang; Arnaud P. Praplan; Kirsty J. Pringle; Gerhard Steiner; Gerhard Steiner; Gerhard Steiner; J. S. Craven; Mario Simon; Anne-Kathrin Bernhammer; Sebastian Ehrhart; Sebastian Ehrhart; Tuukka Petäjä; Tuomo Nieminen; Tuomo Nieminen; Claudia Fuchs; Douglas R. Worsnop; Douglas R. Worsnop; Paul M. Winkler; Yuri Stozhkov; Siegfried Schobesberger; Siegfried Schobesberger; Jonathan Duplissy; Jonathan Duplissy; N. A. D. Richards; Juha Kangasluoma; Xuemeng Chen; John H. Seinfeld; Hamish Gordon; Christopher R. Hoyle; Carla Frege; António Amorim; Antti Onnela; F. Bianchi; F. Bianchi; Mikko Sipilä; Mikko Sipilä; Serge Mathot; Ugo Molteni; Kamalika Sengupta; Kenneth S. Carslaw; Andreas Kürten; Penglin Ye; Jaeseok Kim; Jaeseok Kim; Jasmin Tröstl; Heikki Junninen; Joao Almeida; Joao Almeida; Ernest Weingartner; Chao Yan; Jasper Kirkby; Jasper Kirkby; Ismael K. Ortega; Ari Laaksonen; Ari Laaksonen; Nina Sarnela; Armin Hansel; Alexandru Rap; Jani Hakala; Frank Stratmann; Neil M. Donahue; Richard C. Flagan; Matti P. Rissanen; Linda Rondo; Alexey Adamov; Markku Kulmala; Markku Kulmala; Sophia Brilke; António Tomé; Roberto Guida; Otso Peräkylä; Manuel Krapf; Josef Dommen; Martin Heinritzi; Martin Heinritzi; Alexander L. Vogel; Martin Breitenlechner; Christina Williamson; Christina Williamson; Alessandro Franchin; Robert Wagner; Felix Piel; Ilona Riipinen; Tuija Jokinen; Antonio Dias; Daniela Wimmer; Daniela Wimmer; Catherine E. Scott; Joachim Curtius; Urs Baltensperger; Katrianne Lehtipalo; Katrianne Lehtipalo; Andrea Christine Wagner; Vladimir Makhmutov; Paul E. Wagner; Annele Virtanen;AbstractAtmospheric aerosols and their effect on clouds are thought to be important for anthropogenic radiative forcing of the climate, yet remain poorly understood1. Globally, around half of cloud condensation nuclei originate from nucleation of atmospheric vapours2. It is thought that sulfuric acid is essential to initiate most particle formation in the atmosphere3,4, and that ions have a relatively minor role5. Some laboratory studies, however, have reported organic particle formation without the intentional addition of sulfuric acid, although contamination could not be excluded6,7. Here we present evidence for the formation of aerosol particles from highly oxidized biogenic vapours in the absence of sulfuric acid in a large chamber under atmospheric conditions. The highly oxygenated molecules (HOMs) are produced by ozonolysis of α-pinene. We find that ions from Galactic cosmic rays increase the nucleation rate by one to two orders of magnitude compared with neutral nucleation. Our experimental findings are supported by quantum chemical calculations of the cluster binding energies of representative HOMs. Ion-induced nucleation of pure organic particles constitutes a potentially widespread source of aerosol particles in terrestrial environments with low sulfuric acid pollution.
Caltech Authors arrow_drop_down Publication Server of Goethe University Frankfurt am MainArticle . 2016License: CC BYFull-Text: https://doi.org/10.1038/nature17953Data sources: Bielefeld Academic Search Engine (BASE)Caltech Authors (California Institute of Technology)Article . 2016Full-Text: https://doi.org/10.1038/nature17953Data sources: Bielefeld Academic Search Engine (BASE)Hochschulschriftenserver - Universität Frankfurt am MainArticle . 2016Data sources: Hochschulschriftenserver - Universität Frankfurt am Mainadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1038/nature17953&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.euAccess RoutesGreen hybrid 553 citations 553 popularity Top 0.1% influence Top 1% impulse Top 0.1% Powered by BIP!
more_vert Caltech Authors arrow_drop_down Publication Server of Goethe University Frankfurt am MainArticle . 2016License: CC BYFull-Text: https://doi.org/10.1038/nature17953Data sources: Bielefeld Academic Search Engine (BASE)Caltech Authors (California Institute of Technology)Article . 2016Full-Text: https://doi.org/10.1038/nature17953Data sources: Bielefeld Academic Search Engine (BASE)Hochschulschriftenserver - Universität Frankfurt am MainArticle . 2016Data sources: Hochschulschriftenserver - Universität Frankfurt am Mainadd ClaimPlease grant OpenAIRE to access and update your ORCID works.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.This Research product is the result of merged Research products in OpenAIRE.
You have already added works in your ORCID record related to the merged Research product.All Research productsarrow_drop_down <script type="text/javascript"> <!-- document.write('<div id="oa_widget"></div>'); document.write('<script type="text/javascript" src="https://beta.openaire.eu/index.php?option=com_openaire&view=widget&format=raw&projectId=10.1038/nature17953&type=result"></script>'); --> </script>
For further information contact us at helpdesk@openaire.eu