• Energy Research

Alternative fuels such as hydrogen, compressed natural gas, and liquefied natural gas are considered as feasible energy carriers. Selected positive factors from the EU climate and energy policy on achieving climate neutrality by 2050 highlighted the need for the gradual expansion of the infrastructure for alternative fuel. In this research, continuity equations and the first and second laws of thermodynamics were used to develop a theoretical model to explore the impact of hydrogen and natural gas on both the filling process and the ultimate in-cylinder conditions of a type IV composite cylinder (20 MPa for CNG, 35 MPa and 70 MPa for hydrogen). A composite tank was considered an adiabatic system. Within this study, based on the GERG-2008 equation of state, a thermodynamic model was developed to compare and determine the influence of (i) hydrogen and (ii) natural gas on the selected thermodynamic parameters during the fast-filling process. The obtained results show that the cylinder-filling time, depending on the cylinder capacity, is approximately 36–37% shorter for pure hydrogen compared to pure methane, and the maximum energy stored in the storage tank for pure hydrogen is approximately 28% lower compared to methane, whereas the total entropy generation for pure hydrogen is approximately 52% higher compared to pure methane.

The transmission of natural gas is a key element of the Polish energy system. The published data of the Polish distribution system operators and the transmission system operator on the volume of gaseous fuel transmitted indicate a growing trend in the consumption of energy produced from natural gas. In connection with the energy transformation, switching energy generation sources from hard coal to natural gas in Poland, it is important for transmission operators to know the future demand for gaseous fuel. The aim of the article is to attempt to develop an econometric model related to the consumption of gaseous fuel by Polish entrepreneurs. The knowledge therein may be useful for making business decisions related to the possible expansion of the transmission system, and thus investing financial resources for this purpose. This knowledge will also provide quantitative information related to the interest in gaseous fuel among industrial consumers and the analysis of the trend of natural gas consumption in Poland in the aspect of energy transition. The intention of the publication was to determine the macroeconomic indicators that strongly affect natural gas consumption by the Polish industry and the quantitative growth of consumption depending on changes in these indicators. The results showed that the highest correlation of the growth of natural gas consumption is related to the production of chemistry, the chemical industry, and the power industry.

Heat losses caused by the operation of compressor units are a key problem in the energy efficiency improvement of the natural gas compression station operation. Currently, waste heat recovery technologies are expensive and have low efficiency. One of these technologies is organic Rankine cycle (ORC) which is often analyzed in scientific works. In this paper, the authors decided to investigate another technology that allows for the usage of the exhaust waste energy—the supercritical Brayton cycle with CO2 (S-CO2). With a thermodynamic model development of S-CO2, the authors preformed a case study of the potential S-CO2 system at the gas compressor station with the reciprocating engines. By comparing the values of selected S-CO2 efficiency indicators with ORC efficiency indicators at the same natural gas compression station, the authors tried to determine which technology would be better to use at the considered installation. Investigations on parameter change impacts on the system operation (e.g., turbine inlet pressure or exhaust gas cooling temperatures) allowed to determine the direction for further analysis of the S-CO2 usage at the gas compressor station. When waste heat management is considered, priority should be given to its maximum recovery and cost-effectiveness.

At least 24 liquefied natural gas (LNG) rollover incidents have been reported since 1960. During rollover, because of the heat ingress through the tank walls, a stratified LNG may be suddenly homogenized while releasing massive amounts of vapor. It can result in an overpressure in the tank and significant amounts of potentially explosive LNG vapor being vented out. Both of these factors represent considerable hazards. Rollover is a physical mixing process in a single tank with two or more different cells of LNG of different compositions, temperatures, and densities that can manifest in large boil-off rates. It can exceed venting equipment capacities, and vapor pressure in tank increases rapidly and in extreme cases can lead to tank damage. This paper presents numerical approach for determination of time of rollover occurrence in storage tank. The presented model is based on the energy balance of the stratified cryogenic liquid and the gas phase as separate three thermodynamic systems in the storage tank. As a result of proposed model, for the adopted assumptions and cylindrical tank volume of 78,500 m3, the approximate time of the rollover occurrence was determined for two cases. In the first case, for heavier LNG, the rollover phenomenon will occur 193.25 h after the start of the calculations from the assumed initial conditions. In the second case, for light LNG with a higher initial liquid level in the tank, the rollover will occur after 150.25 h.

The use of hydrogen as a non-emission energy carrier is important for the innovative development of the power-generation industry. Transmission pipelines are the most efficient and economic method of transporting large quantities of hydrogen in a number of variants. A comprehensive hydraulic analysis of hydrogen transmission at a mass flow rate of 0.3 to 3.0 kg/s (volume flow rates from 12,000 Nm3/h to 120,000 Nm3/h) was performed. The methodology was based on flow simulation in a pipeline for assumed boundary conditions as well as modeling of fluid thermodynamic parameters for pure hydrogen and its mixtures with methane. The assumed outlet pressure was 24 bar (g). The pipeline diameter and required inlet pressure were calculated for these parameters. The change in temperature was analyzed as a function of the pipeline length for a given real heat transfer model; the assumed temperatures were 5 and 25 ∘ C. The impact of hydrogen on natural gas transmission is another important issue. The performed analysis revealed that the maximum participation of hydrogen in natural gas should not exceed 15%–20%, or it has a negative impact on natural gas quality. In the case of a mixture of 85% methane and 15% hydrogen, the required outlet pressure is 10% lower than for pure methane. The obtained results present various possibilities of pipeline transmission of hydrogen at large distances. Moreover, the changes in basic thermodynamic parameters have been presented as a function of pipeline length for the adopted assumptions.

The one of main quality requirements of natural gas as an engine fuel is the methane number (MN). This parameter indicates the fuel’s capability to avoid knocking in the engine. A higher MN value indicates a better natural gas quality for gas engines. Natural gas with higher methane content tends to have higher MN value. This study presents analysis of deviation of liquefied natural gas (LNG) composition and its impact on LNG quality as an engine fuel. The analysis of higher hydrocarbons and nitrogen content impact on LNG parameters was considered for several samples of LNG compositions. Most engine manufacturers want to set a new, lower limit value for methane number at 80. This fact causes significant restrictions on the range of variability in the composition of liquefied natural gas. The goal of this study was to determine the combination of the limit content of individual components in liquefied natural gas to achieve the strict methane number criterion (MN > 80). To fulfill this criterion, the methane content in LNG would have to exceed 93.7%mol, and a significant part of the LNG available on the market does not meet these requirements. The analysis also indicated that the methane number cannot be the only qualitative criterion, as its variability depends strongly on the LNG composition. To determine the applicability of LNG as an engine fuel, the simultaneous application of the methane number and Wobbe index criteria was proposed.

During the natural gas pipeline transportation process, gas stream pressure is reduced at natural gas regulation stations (GRS). Natural gas pressure reduction is accompanied by energy dissipation which results in irreversible exergy losses in the gas stream. Energy loss depends on the thermodynamic parameters of the natural gas stream on inlet and outlet gas pressure regulation and metering stations. Recovered energy can be used for electricity generation when the pressure regulator is replaced with an expander to drive electric energy generation. To ensure the correct operation of the system, the natural gas stream should be heated, on inlet to expander. This temperature should be higher than the gas stream during choking in the pressure regulator. The purpose of this research was to investigate GRS operational parameters which influence the efficiency of the gas expansion process and to determine selection criteria for a cost-effective application of turboexpanders at selected GRS, instead of pressure regulators. The main novelty presented in this paper shows investigation on discounted payback period (DPP) equation which depends on the annual average natural gas flow rate through the analyzed GRS, average annual level of gas expansion, average annual natural gas purchase price, average annual produced electrical energy sale price and CAPEX.