• Energy Research

In this work, front contacts for graphene-based solar cells are made by means of colloidal graphite instead of gold. The performance is characterized by exploiting impedance spectroscopy and is compared to the standard gold contact technology. Impedance data are analysed through equivalent circuit representation in terms of lumped parameters, suitable to describe the complex impedance in the frequency range considered in the experiments. Using this approach, capacitance–voltage of the considered graphene–silicon solar cell is found and the barrier height forming at the graphene–silicon interface is extracted.

This paper focuses on the analytical modeling of albedo reflection in bifacial photovoltaic modules, with particular emphasis on the backside. First, we critically examine the approaches proposed in the literature, presenting them with a tutorial style and a uniform nomenclature. These approaches are demonstrated to yield physically meaningless results, as they erroneously assume that the ground area shaded by the module acts as a source of reflected irradiance independent of the portion of sky dome visible to such an area. Then we introduce a correction based on the view factor between the shaded area and the sky. The result is a comprehensive and accurate analytical model that also describes the case of suspended panels and can be easily implemented into PV plant simulators.

This paper presents a DC side oriented diagnostic method for photovoltaic fields which operates on string currents previously supplied by an appropriate monitoring system. The relevance of the work relies on the definition of an effective and reliable day-by-day target for the power that every string of the field should have produced. The procedure is carried out by comparing the instantaneous power produced by all solar strings having the same orientation and by attributing, as producible power for all of them, the maximum value. As figure of merit, the difference between the maximum allowed energy production (evaluated as the integral of the power during a defined time interval) and the energy actually produced by the strings is defined. Such a definition accounts for both weather and irradiance conditions, without needing additional sensors. The reliability of the approach was experimentally verified by analyzing the performance of two medium size solar fields that were monitored over a period of four years. Results allowed quantifying energy losses attributable to underperforming solar strings and precisely locating their position in the field.

In this paper, an Efficient Method for PHotovoltaic Arrays Study through Infrared Scanning (EMPHASIS) is presented; it is a fast, simple, and trustworthy cell-level diagnosis method for commercial photovoltaic (PV) panels. EMPHASIS processes temperature maps experimentally obtained through IR cameras and is based on a power balance equation. Along with the identification of malfunction events, EMPHASIS offers an innovative feature, i.e., it estimates the electrical powers generated (or dissipated) by the individual cells. A procedure to evaluate the accuracy of the EMPHASIS predictions is proposed, which relies on detailed three-dimensional (3-D) numerical simulations to emulate realistic temperature maps of PV panels under any working condition. Malfunctioning panels were replicated in the numerical environment and the corresponding temperature maps were fed to EMPHASIS. Excellent results were achieved in both the cell- and panel-level power predictions. More specifically, the estimation of the power production of a PV panel with a shunted cell demonstrated an error lower than 1%. In cases of strong nonuniformities as a PV panel in hotspot, an estimation error in the range of 9–16% was quantified.

In this paper, an effective circuit for both voltage and current zeroing of single solar panels embedded in a solar field is presented. The circuit interrupts the panel current by means of a solid-state power switch and zeros the panel voltage by means of an electromechanical relay. Each solar panel can be either connected or disconnected from the string independently from each other. The circuit is connected to the existing junction box and does not require additional wiring, neither for its power supply, which is always derived from the solar panel, nor for its data transmission, which is achieved through a special suited power line communication scheme exploiting the existing dc power bus. Experiments performed on a test solar field equipped with in-house made circuit prototypes evidence the reliability of the proposed approach.

The paper deals with a grid-connected single-phase battery charger integrated with photovoltaic generators (PVGs). The circuit topology consists of a multilevel architecture based on a Cascaded H-Bridge (CHB) rectifier. Its main task is to charge the batteries, primarily from the PVGs, by also assuring to keep their state-of-charge (SOC) balanced. Nevertheless, when the battery SOC overcomes a predefined upper limit, beyond which the charging process could be interrupted, the available PV power can no longer be transferred to the batteries. Therefore, to avoid an undesired curtailment of PV power production, this latter can be supplied to the grid by inverting the system operation. The paper shows how to achieve this result by implementing a dedicated control action based on a multi-step procedure. Numerical investigations are carried out on a 19-level CHB converter implemented in the PLECS environment to validate the feasibility and effectiveness of the proposed control technique.

A wide literature review of recent advance on monitoring, diagnosis, and power forecasting for photovoltaic systems is presented in this paper. Research contributions are classified into the following five macroareas: (i) electrical methods, covering monitoring/diagnosis techniques based on the direct measurement of electrical parameters, carried out, respectively, at array level, single string level, and single panel level with special consideration to data transmission methods; (ii) data analysis based on artificial intelligence; (iii) power forecasting, intended as the ability to evaluate the producible power of solar systems, with emphasis on temporal horizons of specific applications; (iv) thermal analysis, mostly with reference to thermal images captured by means of unmanned aerial vehicles; (v) power converter reliability especially focused on residual lifetime estimation. The literature survey has been limited, with some exceptions, to papers published during the last five years to focus mainly on recent developments.

The aim of this work is to investigate the degradation of perovskite solar cells (PSCs) by means of impedance spectroscopy, a highly sensitive characterization technique used to establish the electrical response of a device in a nondestructive manner. In this paper, PSCs with two different electron transport layers (ETLs) are studied: PSCs with undoped SnO2 as an ETL are compared to PSCs with an ETL composed of graphene-doped SnO2 (G-SnO2). Experimental data were collected immediately after fabrication and after one week, monitoring both impedance spectroscopy and dark current-voltage (I-V) curves. It was observed that, in the case of the undoped PSCs, the degradation of the solar cells affected both the AC behavior of the devices, modifying the associated Nyquist plots, and the DC behavior, observable from the dark I-V measurements. Conversely, the solar cells with G-SnO2 showed no variation. Considering the Nyquist plots, a quantitative analysis was performed by comparing the parameters of a proper equivalent circuit model. The results were coherent with those achieved in the DC analysis, thus proving that the analysis of impedance spectra, supported with dark I-V curves, allows one to gain a deeper knowledge of the degradation phenomena of perovskite solar cells. This study opens the door for further improvement of these devices through a better understanding of their electrical behavior.