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Dolomite-based binders are characterised by interesting technical and environmental features. For their synthesis, sources of both CaO and MgO are required. The idea developed in this work is to couple the synthesis of dolomite-based binders, starting from a natural dolomite, through the concept of concentrated solar energy (needed to drive the endothermal dolomite calcination process) in fluidised bed reactors. To this end, a fluidised bed system, where the concentrated solar radiation is mimicked by the use of Xe-lamps (short-arc), has been set up and operated. Natural dolomite (sieved in the 420-590 ?m size range) was calcined at a nominal temperature of 850 °C, and bed temperature profiles during solar-driven calcination were investigated. Then, four binders were prepared by mixing slaked dolomite (obtained from the hydration of solar calcined dolomite) with either blast furnace slag or coal fly ash as supplementary cementitious materials. The binders were hydrated for curing times ranging from 7 to 56 days. X-ray fluorescence, X-ray diffraction and combined differential thermal and thermogravimetric analyses were employed as characterisation techniques both to analyse the chemical composition of starting materials and to investigate the evolution of the hydration in the four systems.

The influence of compost on the growth of bean plants irrigated with As-contaminated waters and its influence on the mobility of As in the soils and the uptake of As (as NaAs(III)O2) by plant components was studied at various compost application rates (3·10(4) and 6·10(4) kg ha(-1)) and at three As concentrations (1, 2 and 3 mg kg(-1)). The biomass and As and P concentrations of the roots, shoots and beans were determined at harvest time, as well as the chlorophyll content of the leaves and nonspecific and specifically bound As in the soil. The bean plants exposed to As showed typical phytotoxicity symptoms; no plants however died over the study. The biomass of the bean plants increased with the increasing amounts of compost added to the soil, attributed to the phytonutritive capacity of compost. Biomass decreased with increasing As concentrations, however, the reduction in the biomass was significantly lower with the addition of compost, indicating that the As phytotoxicity was alleviated by the compost. For the same As concentration, the As content of the roots, shoots and beans decreased with increasing compost added compared to the Control. This is due to partial immobilization of the As by the organic functional groups on the compost, either directly or through cation bridging. Most of the As adsorbed by the bean plants accumulated in the roots, while a scant allocation of As occurred in the beans. Hence, the addition of compost to soils could be used as an effective means to limit As accumulation in crops from As-contaminated waters.

This paper analyzes different policies that may promote the transition to sustainability, with a particular focus on the energy sector. We present a dynamic simulation model where three different strategies for sustainability are identified: reduction in GHG emissions, improvements in energy efficiency and the development of the renewable energy sector. Our aim is to evaluate the dynamics that those strategies may produce in the economy, looking at different performance indicators: rate of growth, unemployment, fiscal position, GHG emission, and transition to renewable energy sources.

This paper investigates the energy distribution and the waste heat energy characteristics of a compression ignition engine for micro-cogeneration applications, at different engine speeds and loads. The experimental activity was carried out on a three-cylinder, 1028 cc, common-rail engine. Tests were performed with diesel fuel and a 20% v/v biodiesel blend (B20). The quantity and the quality of the waste heat energy were studied through energy and exergy analyses, respectively. Combustion characteristics were investigated by means of indicating data. Gaseous emissions were measured and particles were characterized in terms of number and size at exhaust. It was found out that the addition of 20% v/v of RME to diesel fuel does not affect significantly the brake fuel conversion efficiency and the energetic flows. On the other hand, biodiesel blend allows to reduce the combustion noise and the pollutants emissions in most of the operating conditions. A proper phasing of the injection strategy for the biodiesel blend could further reduce the exhaust emissions, mainly at high engine speeds. The results presented in this paper could be useful for the development of diesel engine based micro-cogeneration systems working at different engine speeds and loads.

Life Cycle Assessment is a tool to assess the environmental impacts and resources used throughout a product's life cycle, i.e., from raw material acquisition, via production and use phases, to waste management. The methodological development in LCA has been strong, and LCA is broadly applied in practice. The aim of this paper is to provide a review of recent developments of LCA methods. The focus is on some areas where there has been an intense methodological development during the last years. We also highlight some of the emerging issues. In relation to the Goal and Scope definition we especially discuss the distinction between attributional and consequential LCA. For the Inventory Analysis, this distinction is relevant when discussing system boundaries, data collection, and allocation. Also highlighted are developments concerning databases and Input-Output and hybrid LCA. In the sections on Life Cycle Impact Assessment we discuss the characteristics of the modelling as well as some recent developments for specific impact categories and weighting. In relation to the Interpretation the focus is on uncertainty analysis. Finally, we discuss recent developments in relation to some of the strengths and weaknesses of LCA.

The implementation of resource management strategies aimed at reducing the impacts of the anthropogenic activities system requires a comprehensive approach to evaluate on the whole the environmental burdens of productive processes and to identify the best recovery strategies from both an environmental and an economic point of view. In this framework, an analytical methodology based on the integration of Life Cycle Assessment (LCA), ExternE and Comprehensive Analysis was developed to perform an in-depth investigation of energy systems. The LCA methodology, largely utilised by the international scientific community for the assessment of the environmental performances of technologies, combined with Comprehensive Analysis allows modelling the overall system of anthropogenic activities, as well as sub-systems, the economic consequences of the whole set of environmental damages. Moreover, internalising external costs into partial equilibrium models, as those utilised by Comprehensive Analysis, can be useful to identify the best paths for implementing technology innovation and strategies aimed to a more sustainable energy supply and use. This paper presents an integrated application of these three methodologies to a local scale case study (the Val D'Agri area in Basilicata, Southern Italy), aimed to better characterise the environmental impacts of the energy system, with particular reference to extraction activities. The innovative methodological approach utilised takes advantage from the strength points of each methodology with an added value coming from their integration as emphasised by the main results obtained by the scenario analysis.

Sustainability has become a central issue for firms in the energy industry. These firms have been under increasing pressure to uplift not only their environmental consciousness but also social impact of their actions. One constraint of these firms is prevention of trading off shareholder value maximization with increasing their corporate social responsibility activities geared to the long term benefits of stakeholders. Based on the principles of fairness and equity, Islamic Banking and Finance also provides a vehicle for the firms in the energy industry by incentivizing their corporate social responsibility activities.

Abstract Annual fiber sorghum (FS) and perennial giant reed (GR) cultivated in the Mediterranean area are interesting due to their high productivity under drought conditions and their potential use as lignocellulosic feedstock for biorefinery purposes. This study compares environmental constraints related to FS and GR produced on experimental farms (in the Campania region) using an attributional life cycle assessment (LCA) approach through appropriate modeling of the perennial cultivation. For both crops, primary data were available for agricultural management. Direct field emissions (DFEs) were computed, including the potential soil carbon storage (SCS). Giant reed showed the lowest burdens for all impact categories analyzed (most were in the range of 40%–80% of FS values). More apparent were the differences for climate change and freshwater eutrophication (respectively 80% and 81% lower for GR compared to FS). These results are due to the short-term SCS, experimentally detected in the perennial GR crop (about 0.25 ton C ha−1yr−1, with a global warming offsetting potential of about 0.03 ton CO2/tonGR dry biomass). The results are also due to the annual application of triple superphosphate at the sowing fertilization phase for FS, which occurs differently than it does for GR. Phosphorous fertilization was performed only when crops were being established and therefore properly spread along the overall crop lifetime. For both crops, after normalization, terrestrial acidification and particulate matter formation were relevant impact categories, as a consequence of the NH3 DFE by volatilization after urea were spread superficially. Therefore, the results suggest higher environmental benefits of the perennial crop than the annual crop. Integr Environ Assess Manag 2015;11:397–403. © 2015 SETAC Key Points An LCA comparison between Mediterranean annual and perennial feedstocks was conducted to explore their potential use for biorefinery purposes. Environmental constraints of crops fiber sorghum (annual) and giant reed (perennial), which exhibit high productivity under drought conditions, were investigated. Total burdens were largely affected by direct field emissions following fertilizer application. The perennial crop entailed a better environmental performance with reduced input and emissions.