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Abstract Thin layers of MoOx have been deposited by thermal evaporation followed by post-deposition annealing. The density of states distributions of the MoOx films were extracted deconvoluting the absorption spectra, measured by a photothermal deflection spectroscopy setup, including the small polaron contribution. Results revealed a sub-band defect distribution centered 1.1 eV below the conduction band; the amplitude of this distribution was found to increase with post-deposition annealing temperature and film thickness.

The 5G Radio Access Network (RAN) virtualization aims to improve network quality and lower the operator's costs. One of its main features is the functional split, i.e., dividing the instantiation of RAN baseband functions into different units over metro-network nodes. However, its optimal placement is non-trivial: it depends on the application requirements and on the expected traffic volume, whose daily variation highly impacts the total power consumption. Current optimization solutions fail to provide a placement solution capable of handling traffic fluctuations. In fact, the standard machine learning algorithms used in the literature for planning the network resources in advance result in an allocation that is inadequate to carry the actual traffic at all the time-slots. Hence, we must reserve an artificial buffer capacity in the nodes to ensure feasibility. Instead, our proposed method exploits a fine-grained two-step multi-task algorithm that predicts the mean and quantile traffic, making the artificial capacity no longer necessary. The subsequent placement uses mixed-integer linear programming and a heuristic. The former considers the expected traffic in the objective function (to estimate costs) and the quantile in the constraints (to enforce capacity limits). The heuristic combines the mean and quantile results to minimize the power and comply with the requirements. While using sufficiently large artificial buffers guarantees robustness with a mild power increase compared to the oracle, the fine-grained multi-task model improves the results, reducing the power consumption compared to the mean and meets all constraints. The heuristic enables significant computational time reduction. ; Green Open Access added to TU Delft Institutional Repository 'You share, we take care!' - Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public. ...

This paper investigates a novel routing problem of a multi-robot station in a manufacturing cell. In the existing literature, the objective is to minimize the cycle time or energy consumption separately. The routing problem considered in this paper aims to reduce the cycle time and energy consumption jointly for each robot while avoiding collisions between these robots. For this routing problem, we propose a new flexible time-space network model that allows us to reduce energy consumption while minimizing the cycle time. The corresponding optimization problem is Mixed-Integer Nonlinear Programming (MINLP). For addressing its computational complexity, this paper designs a metaheuristic algorithm tailored to the studied problem and proposes an ϵ-constraint algorithm to study the trade-off between these two objectives. We conduct industrially relevant simulation experiments of case studies to show its effectiveness, in comparison to a conventional method, two state-of-the-art solvers, and two commonly-used metaheuristics. The results show that the proposed methodology can reduce energy consumption by up to 30% without compromising the cycle time. Meanwhile, the proposed algorithm can provide efficient solutions within a reasonable computation time. Note to Practitioners-This paper is motivated by the problem of improving energy efficiency when routing cooperative robots in a manufacturing station. In current approaches for routing multi-robot stations, the cycle time and energy consumption are minimized separately. This paper focuses on the movement of the robot end-effector and its connected joint and suggests a new approach to minimize these two objectives jointly by proposing a new mathematical model. The resulting planning problem is computationally intractable. A customized metaheuristic algorithm is thus designed for efficiently solving this planning problem. Our meta-heuristic algorithm is integrated with the ϵ-constraint method to study the relationship between these two objectives. Simulation experiments ...

Operations of Automated Guided Vehicles (AGVs) are desired to be more energy-efficient while maintaining high transport productivity, motivated by the green production requirements. This paper investigates a new energy-efficient planning problem for determining conflict-free paths of the AGVs in its transport roadmap. In this problem, the vehicle path and transport time in the roadmap are jointly optimized, based on a flexible time–space network (FTSN). We provide the mathematical problem formulation of the energy-efficient path planning problem. The resulting optimization problem is proved to be a non-convex mixed-integer nonlinear programming which is computationally intractable. We further propose a hybrid metaheuristic that integrates the genetic algorithm and estimation of the distribution algorithm to improve its computational efficiency. Numerical results show the effectiveness of the developed algorithm based on the FTSN framework, compared to the existing metaheuristics, the conventional path planning method, and a commercial solver. The proposed method has a wide application in improving energy use of material handling, providing a guiding significance on promoting cleaner production of flexible manufacturing systems. ; Green Open Access added to TU Delft Institutional Repository 'You share, we take care!' - Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public. ; Transport Engineering and Logistics

The building sector has gained significant attention due to its remarkably high energy consumption and greenhouse gas emissions. In China's rural areas, stone is a popular building material, but there are unprecedented demands to improve the life-cycle performance of stone buildings. It is essential to preserve the original architectural features while evolving towards a cleaner production and operation. This study implements a field survey in the Taihang Mountains of Hebei province. The improvement of stone extraction methods and the evolution of three stone wall styles are collected and developed. Thermal transmittances of three stone walls are measured and modeled. A cradle-to-grave life cycle assessment is conducted, and the results are compared to show their environmental performance in the embodiment and operation phases. Their life cycle inventories, including stone extraction, are developed. One representative building style sample is developed for the cooling and heating energy requirement simulation in the DesignBuilder. Based on the inventories, conducting life cycle impact assessment shows various environmental profiles in their whole life cycles. From the outcomes, the stone cladding wall (SCW) outperforms the other stone walls in both the embodiment and operation phases. However, its relatively high cost is a challenge for an individual house owner. This study proves the SCW is more sustainable, providing a basis for the choice of stone wall style in the future construction. ; Green Open Access added to TU Delft Institutional Repository 'You share, we take care!' - Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public. ; Architectural Technology

Abstract This paper documents a thermo-fluid-dynamic mean-line model for the preliminary design of multistage axial turbines with blade cooling applicable to supercritical CO2 turbines. Given the working fluid and coolant inlet thermodynamic conditions, blade geometry, number of stages and load criterion, the model computes the stage-by-stage design along with the cooling requirement and ultimately provides an estimate of turbine efficiency via a semi-empirical loss model. Different cooling modes are available and can be selected by the user (stand-alone or combination): convective cooling, film cooling, and thermal barrier coating. The model is applied to attain the preliminary aero-thermal design of the 600 MW cooled axial supercritical CO2 turbine of the Allam cycle. Results show that a load coefficient varying from 3 to 1 throughout the machine, and a reaction degree ranging from 0.1 to 0.5 lead to the maximum total-to-static turbine efficiency of about 85%. Consequently, as opposed to uncooled CO2 turbines, a repeated stage configuration is an unsuited design choice for cooled sCO2 machines. Moreover, the study highlights that film cooling is considerably less effective compared to conventional gas turbines, while increasing the number of stages from 5 to 6 and adopting higher rotational speeds leads to an increased efficiency.

Building and programming tiny battery-free energy harvesting embedded computer systems is hard for the average maker because of the lack of tools, hard to comprehend programming models, and frequent power failures. With the high ecologic cost of equipping the next trillion embedded devices with batteries, it is critical to equip the makers, hobbyists, and novice embedded systems programmers with easy-to-use tools supporting battery-free energy harvesting application development. This way, makers can create untethered embedded systems that are not plugged into the wall, the desktop, or even a battery, providing numerous new applications and allowing for a more sustainable vision of ubiquitous computing. In this paper, we present BFree, a system that makes it possible for makers, hobbyists, and novice embedded programmers to develop battery-free applications using Python programming language and widely available hobbyist maker platforms. BFree provides energy harvesting hardware and a power failure resilient version of Python, with durable libraries that enable common coding practice and off the shelf sensors. We develop demonstration applications, benchmark BFree against battery-powered approaches, and evaluate our system in a user study. This work enables makers to engage with a future of ubiquitous computing that is useful, long-term, and environmentally responsible.

Energy consumption is expected to be reduced while maintaining high productivity for container handling. This paper investigates a new energy-efficient scheduling problem of automated container terminals, in which quay cranes (QCs) and lift automated guided vehicles (AGVs) cooperate to handle inbound and outbound containers. In our scheduling problem, operation times and task sequences are both to be determined. The underlying optimization problem is mixed-integer nonlinear programming (MINLP). To deal with its computational intractability, a customized and efficient genetic algorithm (GA) is developed to solve the studied MINLP problem, and lexicographic and weighted-sum strategies are further considered. An e-constraint algorithm is also developed to analyze the Pareto frontiers. Comprehensive experiments are tested on a container handling benchmark system, and the results show the effectiveness of the proposed lexicographic GA, compared to results obtained with two commonly-used metaheuristics, a commercial MINLP solver, and two state-of-the-art methods.

The paper presents a coordinated day-ahead and intra-day approach for the scheduling of the resources in a local energy community (LEC). The considered LEC consists of a collective of power prosumers that can directly trade energy with each other in addition to the external provider. The scheduling approach is based on the alternating direction method of multipliers and aims at minimizing the total energy procurement costs, assuring that each participant has an economical advantage in being part of the community. To cope with the uncertainties of the renewable power generation and consumption during the day, a day-ahead multistage stochastic optimization approach is combined with an intra-day rolling-horizon optimization procedure. The effectiveness of the approach is supported by numerical simulations for several case studies in which the LEC prosumers are either connected to the same low-voltage network or directly to the medium-voltage level. ; Green Open Access added to TU Delft Institutional Repository 'You share, we take care!' - Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public. ; Team Bart De Schutter

The use of metallic periodic structures was considered for melting rate enhancement of a phase change material (PCM) contained in a rectangular enclosure isothermally heated from the side. The critical (optimized) cell size, or pore size, of a periodic structure with fixed porosity, realising the shortest melting time by maximizing the convection and conduction heat transfer rate into the PCM, was studied. Furthermore, the effects of material properties (copper, aluminium, nickel, and stainless steel), enclosure length, wall-melting temperature difference and porosity were numerically investigated. It was observed that increasing porosity and/or reducing thermal conductivity enlarged the critical cell size (i.e. the optimal cell size that minimizes the melting time). The critical PPIs (pores per inch) of copper and aluminium periodic structures for all studied porosities were 10; for nickel, the critical values were 10 PPIs for porosity values of 0.75, 0.8 and 0.85 while it reduces to 5 PPI for the highest porosity considered here being 0.95. Interestingly, showing a different trend, the critical PPI of stainless-steel structures was 5 for the lowest porosity (0.75) and reduced to 3 for higher porosities. The results clearly demonstrated localised melting which was observed in all periodic structures except for the 10 PPI stainless-steel case. Scattered melting islands are observed as opposed to a moving interface when ϕ=(d p /L)α ligament /α PCM >1. For such cases, localized melting occurs and the PCM is melted at the ligaments away from the heated wall before the melt front reaches those ligaments. ; Green Open Access added to TU Delft Institutional Repository 'You share, we take care!' - Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public. ; Process and Energy