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9 Figuras, 4 Tablas.-- Material suplementario disponible en línea en la página web del editor. Co-pyrolysis of grape seeds and polystyrene was conducted in a fixed-bed reactor, followed by an analysis of the organic phase for possible further application as a drop-in fuel. Significant positive synergistic effects were found with the addition of polystyrene (5–40 wt%) to the conventional pyrolysis of grape seeds. There was a considerable improvement in the organic phase yield, in particular, reaching values over 80 wt%, markedly higher than those obtained from conventional pyrolysis (61 wt%). Fuel properties of the bio-oil were also upgraded, with a decrease in oxygen content and an increase in the heating value. An organic bio-oil fraction with pH values ranging from 5.4 to 6.2 was obtained, reducing the issues associated with handling bio-oils obtained from common pyrolysis of lignocellulosic biomass, usually ranging pH between 2 and 3. Finally, an increment in the desired compounds, mainly aromatics, was also attained, while at the same time achieving a low content of undesired compounds, such as phenols. It was demonstrated that polystyrene can act as a H2-donor, favoring oligomerization, cyclation and hydrodeoxygenation reactions into aromatic compounds. The authors would like to thank MINECO and FEDER for their financial support (Project ENE2015-68320-R). O.S.P acknowledges the FPI fellowship (BES-2016-077750) funded by MINECO. The authors would also like to thank the Regional Government of Aragon (DGA) for the support provided under the research groups support programme. Peer reviewed

An ever more environmentally conscious society demands the use of green, sustainable and high-efficiency renewable energy resources. However, large-scale energy storage remains a challenge for a deep penetration of power produced from renewables into the grid. The Calcium-Looping (CaL) process, based on the reversible carbonation/calcination of CaO, is a promising technology for thermochemical energy storage (TCES) in Concentrated Solar Power (CSP) plants. Natural limestone to be used as CaO precursor is cheap, non-toxic and abundant. Nevertheless, recent works have shown that carbonation of CaO derived limestone at optimum conditions for TCES is limited by pore-plugging, which leads to severe deactivation for large enough particles to be employed in practice. In our work, we have synthesized inexpensive CaO/SiO composites by means of a biotemplate method using rice husk as support. The morphological and compositional features of the biomorphic materials synthesized help improve the CaO multicycle activity under optimum CSP storage conditions and for particles sufficiently large to be managed in practical processes. Peer Reviewed

13 páginas, 7 figuras, 7 tablas. The trace elements (As, B, Ba, Be, Bi, Cd, Co, Cr, Cs, Cu, Ga, Ge, Hg, Li, Mn, Mo, Ni, Pb, Rb, Sb, Se, Sn, Sr, Ta, Th, Tl, U, V, W, Y, Zn, Zr and REE) in a subbituminous coal and their behaviour during combustion in a large power station were characterized by their content and distribution in the fuel (organic and/or inorganic affinities) and in the combustion wastes (partition and volatility). Samples were fractionated by density and magnetic separations and cascade impactors. Quantitative analyses were performed by X-ray diffraction, ICP-MS, ICP-AES, AAS and ICP-AES with hydride generation. Among the findings is the important role of anhydrite (CaSO4) in the sorption of trace elements such as As, B, Ge, Se, Pb, Mo, Zn and Tl from flue gas and in the reduction of emissions of these potentially toxic elements. Calcium oxide has a high sorption capacity for some of the elements studied. This sorption phenomenon and the condensation, mainly as fine fly ash particles, of important fractions of the trace elements during the cooling of flue gas significantly reduce the gaseous emissions of potentially toxic trace elements from coal combustion in the power station studied. The present study has been supported by the European Coal and Steel Community Contract 7220-ED/014 and the Spanish Research Project NAT91-0571. Peer reviewed

11 Figuras, 2 Tablas.-- Material suplementario disponible en línea en la página web del editor.-- © 2019. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ Among the different Carbon Capture and Storage (CCS) technologies being developed in the last decades, Chemical Looping Combustion (CLC) stands out since it allows inherent CO2 capture. In the CLC process, there is a solid oxygen carrier circulating between two reactors in a cycle that allows providing the oxygen needed for combustion. In one of the reactors, named as fuel reactor, the fuel is introduced and combusted while the oxygen carrier reduction takes place. In the second reactor, named air reactor, the oxygen carrier is reoxidized in air. Different materials based on copper, nickel and iron oxides have been proposed as oxygen carriers for the CLC process. This work presents an environmental evaluation of the CLC process for natural gas based on Life Cycle Assessment (LCA). Five different oxygen carrier materials already tested in pilot plants were considered and the results compared to the conventional natural gas combustion in a gas turbine in a combined cycle without and with CO2 capture using postcombustion capture with amines. In view of the results, lower impact of the CLC process compared to the base case is expected without and with CO2 capture. The influence of several variables on the results was considered, such as temperature in the air reactor, lifetime of the oxygen carrier and possibility of recuperation of the depleted oxygen carrier. The nickel-based oxygen carriers were identified as the most adequate to be used in natural gas combustion. However, due to their toxicity, several analyses were also performed in order to identify improvements in the known oxygen carriers that can qualify them to replace nickel-based materials. This work was supported by the Spanish Ministry of Economy and Competitiveness (MINECO) [grant numbers ENE2017-89473-R, ENE2016-77982-R] and the European Regional Development Fund (ERDF) under the program “Programa Operativo FEDER Aragón 2014-2020 - Construyendo Europa desde Aragón. Proyecto BiosinCO2 (LMP180_18)”. T. Mendiara thanks for the ‘‘Ramón y Cajal’’ post-doctoral contract awarded by MINECO. Peer reviewed

The devolatilisation step of coal is a vital stage in both air–coal and oxy-coal combustion and there is interest in whether methods of estimating the reaction parameters are similar for both cases. A network pyrolysis model, the FG-DVC (Functional Group-Depolymerisation Vaporisation Cross-linking) code was employed to evaluate the effect of temperature (1273–1773 K) and heating rate (104–106 K/s) on the devolatilisation parameters of two coals of different rank. The products distribution between char and volatiles, and volatiles and NH3/HCN release kinetics were also determined. In order to assess the accuracy of the FG-DVC predictions, the values for nitrogen distribution and devolatilisation kinetics obtained for a temperature of 1273 K and a heating rate of 105 K/s were included as inputs in a Computational Fluid Dynamics (CFD) model for oxy-coal combustion in an entrained flow reactor (EFR). CFD simulations with the programme default devolatilisation kinetics were performed. The oxygen content in oxy-firing conditions ranged between 21% and 35%, and air-firing conditions were also employed as a reference. The experimental coals burnouts and oxygen concentrations from the EFR experiments were employed to test the accuracy of the CFD model. The temperature profiles, burning rates, char burnout and NO emissions during coal combustion in both air and O2/CO2 atmospheres were predicted. The predictions obtained when using the CFD model with FG-DVC coal devolatilisation kinetics were much closer to the experimental values than the predictions obtained with the ANSYS Fluent (version 12) program default kinetics. The predicted NO emissions under oxy-firing conditions were in good agreement with the experimental values. The present study was carried out with financial support from the Spanish MICINN (Project PS-120000-2005-2) co-financed by the European Regional Development Fund. L.A. and J.R. acknowledge funding from the CSIC JAE program, which was cofinanced by the European Social Fund, and the Asturias Regional Government (PCTI program), respectively. MG acknowledges financial support from E.ON UK, and for an EPSRC Dorothy Hodgkin Postgraduate Award. We also thank Dr L Ma for helpful discussions. Peer reviewed

Coastal areas are more densely populated than inland areas and present faster rates of population increase and urbanization. This trend is expected to continue in the coming decades, and thus, the demand of natural resources in coastal areas, such as water and energy resources, increasing the pressure and impact on the environment, superposed to the effects of climate change. Currently, in Europe, the demand for heating in buildings and businesses outnumbers the demand for cooling. However, the latter is gradually catching up due to rising demand for air cooling or refrigeration for industry such as food, technological and medical supplies. The energy required to cool buildings in Europe is expected to increase by more than 70% by 2030, while energy used to heat buildings may decrease by 30% (UE, 2018). Low Temperature Geothermal Energy (LTGE) is most likely the green energy production method for heating and cooling with the highest potential to provide affordable and clean energy and meet the CO2-emissions reduction goals of the Green Deal. Despite advances on LTGE technologies, the efficiency of these systems remains inherently sensitive to changes in hydrodynamics and the media (e.g., changes in the groundwater thermal regime). Groundwater, on the other hand, is the world's largest freshwater resource, and it is especially important in coastal areas because interactions between aquifer systems and sea water may lead to salinization and resource loss. Because geothermal systems and coastal aquifers interact directly, specially at groundwater discharge areas, it is clear that a better understanding of the potential interactions of geothermal systems with current and prospective coastal aquifer processes is essential for their design and foreseeing potential environmental effects. To address these issues, we model variable-density groundwater coupled with heat transport to simulate the long-term evolution of groundwater salinity and aquifer thermal energy discharge. We find that the heating/cooling-induced water density variations affect the seawater intrusion. Understanding the behavior of the groundwater system is required to ensure sustainable water, energy, and coastal ecosystem management.

AbstractAn eco‐friendly and sustainable salt‐templating approach was proposed for the production of anode materials with a 3D sponge‐like structure for sodium‐ion capacitors using gluconic acid as carbon precursor and sodium carbonate as water‐removable template. The optimized carbon material combined porous thin walls that provided short diffusional paths, a highly disordered microstructure with dilated interlayer spacing, and a large oxygen content, all of which facilitated Na ion transport and provided plenty of active sites for Na adsorption. This material provided a capacity of 314 mAh g−1 at 0.1 A g−1 and 130 mAh g−1 at 10 A g−1. When combined with a 3D highly porous carbon cathode (SBET ≈2300 m2 g−1) synthesized from the same precursor, the Na‐ion capacitor showed high specific energy/power, that is 110 Wh kg−1 at low power and still 71 Wh kg−1 at approximately 26 kW kg−1, and a good capacity retention of 70 % over 10000 cycles.