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Polymer-based multicolor emissive materials have growing demand due to their potential applications in various fields such as full-color displays, bioimaging, and light sources because of their processability and high stability. Herein, we report dual-color emissive hybrid materials based on biocompatible poly(l-lactide) and polyethylene glycol-modified two-dimensional layered double hydroxide quantum dots (PEG-LDHQDs). The morphology of polymer films tunes the spatial distribution of QDs within the polymer matrix, modulating the energy transfer between the QDs and affording the dual emission behavior in the aggregated states. The amorphous hybrid films show single emission (blue) from the finely dispersed QDs (mostly isolated) within the polymer matrix. In contrast, dual emission (blue and red) was observed when the polymer was crystallized due to the possible accumulation of QDs at the interface of crystalline and amorphous phases in the lamellar structure. Furthermore, the dual emission could be enhanced by the aggregation of QDs on the pores of the breath figure pattern constructed on the surface of the hybrid film.

Polymer-based multicolor emissive materials have growing demand due to their potential applications in various fields such as full-color displays, bioimaging, and light sources because of their processability and high stability. Herein, we report dual-color emissive hybrid materials based on biocompatible poly(l-lactide) and polyethylene glycol-modified two-dimensional layered double hydroxide quantum dots (PEG-LDHQDs). The morphology of polymer films tunes the spatial distribution of QDs within the polymer matrix, modulating the energy transfer between the QDs and affording the dual emission behavior in the aggregated states. The amorphous hybrid films show single emission (blue) from the finely dispersed QDs (mostly isolated) within the polymer matrix. In contrast, dual emission (blue and red) was observed when the polymer was crystallized due to the possible accumulation of QDs at the interface of crystalline and amorphous phases in the lamellar structure. Furthermore, the dual emission could be enhanced by the aggregation of QDs on the pores of the breath figure pattern constructed on the surface of the hybrid film.

AbstractIn the present study, we analyze a field-based seven-year data series of surface mass-balance measurements collected during 2011/12 to 2017/18 on Naradu Glacier, western Himalaya, India. The average annual specific mass balance for the said period is − 0.85 m w.e. with the maximum ablation of − 1.15 m w.e. The analysis shows that the topographic features, south and southeast aspects and slopes between 7 to 24 degrees are the reasons behind the maximum ablation from a particular zone. The causes of surface mass balance variability have been analyzed through multiple linear regression analyses (MLRA) by taking temperature and precipitation as predictors. The MLRA demonstrates that 71% of the observed surface mass balance variance can be explained by temperature and precipitation. It clearly illustrates the importance of summer temperature, which alone explains 64% variance of surface mass balance. The seasonal analysis shows that most of the surface mass balance variability is described by summer temperature and winter precipitation as two predictor variables. Among monthly combinations, surface mass balance variance is best characterized by June temperature and September precipitation.

AbstractIn the present study, we analyze a field-based seven-year data series of surface mass-balance measurements collected during 2011/12 to 2017/18 on Naradu Glacier, western Himalaya, India. The average annual specific mass balance for the said period is − 0.85 m w.e. with the maximum ablation of − 1.15 m w.e. The analysis shows that the topographic features, south and southeast aspects and slopes between 7 to 24 degrees are the reasons behind the maximum ablation from a particular zone. The causes of surface mass balance variability have been analyzed through multiple linear regression analyses (MLRA) by taking temperature and precipitation as predictors. The MLRA demonstrates that 71% of the observed surface mass balance variance can be explained by temperature and precipitation. It clearly illustrates the importance of summer temperature, which alone explains 64% variance of surface mass balance. The seasonal analysis shows that most of the surface mass balance variability is described by summer temperature and winter precipitation as two predictor variables. Among monthly combinations, surface mass balance variance is best characterized by June temperature and September precipitation.

Assessing the impacts of climate change and land use/land cover changes on water resources within a catchment is essential because it helps us understand how these dynamic factors affect the quantity, quality, and availability of freshwater. This knowledge is crucial for making informed decisions about water management, conservation, and adaptation strategies, especially in regions facing increasing environmental uncertainties and challenges to water resource sustainability. In Pakistan’s Kunhar River Basin (KRB), this investigation explores the potential effects of shifting land use/land cover (LULC), and climate on stream flows. The SWAT (Soil and Water Assessment Tool), a semi-distributed hydrological model, and the most recent Coupled Model Intercomparison Project phase 6 (CMIP6) dataset from multiple global climate models (GCMs) were used to evaluate these effects. The temperature and precipitation data were downscaled using the CMhyd software; for both shared socioeconomic pathways (SSP2 and SSP5), the top-performing GCM out of four was required to produce downscaled precipitation and temperature predictions while taking future land use characteristics into account. The output from the chosen GCM indicated that by the conclusion of the 21st century, relative to the reference period (1985–2014), the study area’s average monthly precipitation, highest temperature, and lowest temperature will be increasing. Precipitation is anticipated to increase between 2015 and 2100 by 20.5% and 29.1% according to the SSP2 and SSP5 scenarios, respectively. This study’s findings, which emphasize the need for project planners and managers taking into account the effects of climate and land cover changes in their management techniques, show that climate change can have a significant impact on the changing seasons of flows in the Kunhar River basin.

Assessing the impacts of climate change and land use/land cover changes on water resources within a catchment is essential because it helps us understand how these dynamic factors affect the quantity, quality, and availability of freshwater. This knowledge is crucial for making informed decisions about water management, conservation, and adaptation strategies, especially in regions facing increasing environmental uncertainties and challenges to water resource sustainability. In Pakistan’s Kunhar River Basin (KRB), this investigation explores the potential effects of shifting land use/land cover (LULC), and climate on stream flows. The SWAT (Soil and Water Assessment Tool), a semi-distributed hydrological model, and the most recent Coupled Model Intercomparison Project phase 6 (CMIP6) dataset from multiple global climate models (GCMs) were used to evaluate these effects. The temperature and precipitation data were downscaled using the CMhyd software; for both shared socioeconomic pathways (SSP2 and SSP5), the top-performing GCM out of four was required to produce downscaled precipitation and temperature predictions while taking future land use characteristics into account. The output from the chosen GCM indicated that by the conclusion of the 21st century, relative to the reference period (1985–2014), the study area’s average monthly precipitation, highest temperature, and lowest temperature will be increasing. Precipitation is anticipated to increase between 2015 and 2100 by 20.5% and 29.1% according to the SSP2 and SSP5 scenarios, respectively. This study’s findings, which emphasize the need for project planners and managers taking into account the effects of climate and land cover changes in their management techniques, show that climate change can have a significant impact on the changing seasons of flows in the Kunhar River basin.

The synthesis of biodiesel from Jatropha curcas by transesterification is kinetically controlled. It depends on the molar ratio, reaction time, and temperature, as well as the catalyst nature and quantity. The aim of this study was to explore the transesterification of low-cost, inedible J. curcas seed oil utilizing both homogenous (potassium hydroxide; KOH) and heterogenous (calcium oxide; CaO) catalysis. In this effort, two steps were used. First, free fatty acids in J. curcas oil were reduced from 12.4 to less than 1 wt.% with sulfuric acid-catalyzed pretreatment. Transesterification subsequently converted the oil to biodiesel. The yield of fatty acid methyl esters was optimized by varying the reaction time, catalyst load, and methanol-to-oil molar ratio. A maximum yield of 96% was obtained from CaO nanoparticles at a reaction time of 5.5 h with 4 wt.% of the catalyst and an 18:1 methanol-to-oil molar ratio. The optimum conditions for KOH were a molar ratio of methanol to oil of 9:1, 5 wt.% of the catalyst, and a reaction time of 3.5 h, and this returned a yield of 92%. The fuel properties of the optimized biodiesel were within the limits specified in ASTM D6751, the American biodiesel standard. In addition, the 5% blends in petroleum diesel were within the ranges prescribed in ASTM D975, the American diesel fuel standard.