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Artículos en revistas It is shown how a standard nonlinear programming approach can be applied to solve a sophisticated version of the static optimal mix problem in generation planning. The model presented includes technical minima of thermal capacity, detailed operating models of storage-hydro and pumped-hydro units, a realistic model of capital costs for hydro plants, operating reserve and minimum demand constraints, and capacity already in existence. The model formulation is in a format that can be directly handled by the well-known MINOS code and can be efficiently solved. The use of a general-purpose nonlinear optimization program results in a great flexibility, making it possible to modify the model formulation easily or to adapt it to the characteristics of a particular electric system. A realistic application to the Spanish generation system is presented info:eu-repo/semantics/publishedVersion

Diesel engine exhausts from a common rail 3.0 L F1C diesel engine were analyzed at two different load conditions of the WLTC testing cycle downstream of both the diesel particulate filter (DPF) and selective catalytic reactor (SCR) to verify their effect on the characteristics of carbon particulate matter. An array of chemical, physical and spectroscopic techniques (gas chromatography coupled with mass spectrometry (GC-MS), mobility analyzer, UV-Visible absorption and fluorescence spectroscopy) was applied for characterizing polycyclic aromatic hydrocarbons (PAH), heavy aromatic compounds and soot, constituting the particulate matter (PM) sampled from the exhaust. The engine was operated in half load (HL) (188 Nm, representing the more common condition for engine in urban traffic) and full load (FL) (452 Nm, representing the best performance of the engine operation) conditions, at the same engine speed (2000 rpm). Soot formation was enhanced in HL condition, with respect to FL, but, just because of the much lower soot amount, the after-treatment systems in this last condition resulted to be less efficient in the soot abatement. Indeed, the abatement through DPF was about 40% lower in the FL condition with respect to HL condition, and any significant further concentration decrease was found after SCR, in both conditions. By contrast, PAH concentration after DPF abatement was found to be higher in the HL with respect to FL condition. A further PAH concentration decrease of about 30% was found after the SCR in the HL condition whereas in FL the reduction was only about 5-6%. Also the heavy aromatic compounds having molecular weight above the GC-MS detection limit (300 u), were mitigated by SCR. Therefore, SCR did not cause a further soot reduction, whereas it was effective in largely reducing PAH and heavy aromatics emissions, especially in the lower temperature condition featuring the half-load condition, when combustion efficiency is worse. Moreover, SCR system reduced the emission of small particles probably due to an enhanced agglomeration of particles, with beneficial effect on the harmfulness to human health.

Capítulos en libros This paper describes a strategic information platform developed for the German electric utility Eon, to provide historical bidding analysis and medium-term forecasting of the Iberian Electricity Market. This platform, PLAMER, has three main modules: Initialization module, consisting of different sub-modules to define the electrical system structure and to organize the input data of the rest of modules, PLAMER-bids, to read, aggregate and visualize market historical bids and also to prepare them for their future forecasted values, and PLAMER-clearing, for market clearing emulation using forecasted bids. PLAMER-clearing models the Iberian market based on a bid clearing mechanism with an inherent market splitting procedure. This market splitting is built with a bi-nodal simplification, one node representing the Spanish System and the other the Portuguese one. Both are simply connected by a unique equivalent interconnection line. The medium term clearing model uses a generation portfolio per generation company in terms of technologies, for supplying monthly demand for different load levels, and labour and non-labour periods. Some technical constraints, such as minimum outputs and pumping energy balance, are also taking into account. The mathematical problem of PLAMER-clearing is a quadratic programming model solved using GAMS language and CPLEX optimizer. Finally, a real Iberian case study is detailed and some market splitting outputs are analyzed. info:eu-repo/semantics/publishedVersion

It is now environmentally desirable and legally mandatory to add renewable fuels such as ethanol or ethyl tert-butyl ether to gasoline. However, biofuels affect, among other properties, the distillation curve of gasoline, which is subject to strict regulations. This work presents a simple mathematical model capable of accurately predicting the influence that the addition of these oxygenates has on the distillation curve. In order to address this issue, it is essential to find a simple mathematical correlation between the boiling temperatures of the hydrocarbons present in gasoline and the properties (boiling temperature and volume or molar concentration of ethanol) of the corresponding azeotropic mixtures formed with ethanol. Power functions have been assumed to model the temperature composition diagrams of the vapour-liquid equilibrium. Experimental data previously published by these and other authors have been used to fit and validate the model. The results provided by the mathematical model can be of great interest to understand the process of fuel evaporation in spark-ignition engines or the adjustment of distillation cuts in refineries, in order to comply with the regulations, in terms of the distillation curve, after adding ethanol or ethyl tert-butyl ether.

Artículos en revistas There has been total unanimity about the vital importance of reliability of supply since the beginning of the electricity sector deregulation process. This paper describes the procedure proposed by Pérez-Arriaga et al. [2005. White paper for the reform of the regulatory scheme of the power generation in Spain. For the Ministry of Industry, Tourism and Trade of Spain (in Spanish)] to improve upon the current scheme to guarantee a reasonable reserve margin, the capacity payment mechanism. This alternative design introduces improvements aimed at guaranteeing at least a minimum capacity reserve margin, as well as at providing a strong incentive for generating units to be available when needed, namely, in situations when supply is likely to be insufficient to meet the total demand. info:eu-repo/semantics/publishedVersion

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In the anodisation of Nb in acidic fluoride solutions or warm aqueous alkali, and in that of Mo in concentrated phosphoric acid, impedance spectroscopy provides evidence that 3D film growth proceeds already during the active–passive transition. Indeed, linear potential dependences of both the inverse of the high-frequency capacitance and of the product of the high-frequency resistance times the steady-state current are observed already below the peak potential. Simultaneously, a pseudo-inductive loop at intermediate frequencies is detected in the impedance spectra. In the present paper, we propose a kinetic model for the interpretation of these data. The model assumes that the metal is covered with a non-stoichiometric oxide containing at least two oxidation states of the cation. The processes of oxidative dissolution of the lower valence cations and their transformation to cations of higher valence, leading to passivation, explain the shape of the I–E curve. These processes are limited by both charge transfer at the film–solution (F/S) interface and transport of cation vacancies through the film. Thickening of the oxide film is assumed to proceed simultaneously, and is limited by transport of oxygen vacancies accelerated by an interfacial charge of cation vacancies.

Capítulos en libros This paper presents a general method to convert State feedback controllers to damp power system electromechanical oscillations to the standard structure formed by an Automatic Voltage Regulator (AVR) and a Power System Stabilizer (PSS). The proposed conversion method is based on least squares fitting in the frequency domain. info:eu-repo/semantics/publishedVersion