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The land transformation process in the last decades produced the urbanization growth in flat and coastal areas all over the world. The combination of natural phenomena and human pressure is likely one of the main factors that enhance coastal dynamics. These factors lead to an increase in coastal risk (considered as the product of hazard, exposure, and vulnerability) also in view of future climate change scenarios. Although each of these factors has been intensively studied separately, a comprehensive analysis of the mutual relationship of these elements is an open task. Therefore, this work aims to assess the possible mutual interaction of land transformation and coastal management zones, studying the possible impact on local coastal communities. The idea is to merge the techniques coming from urban planning with data and methodology coming from the coastal engineering within the frame of a holistic approach. The main idea is to relate urban and land changes to coastal management. Then, the study aims to identify if stakeholders’ pressure motivated the deployment of rigid structures instead of shoreline variations related to energetic and sedimentary balances. The influence of coastal protection (described by an indicator taking into account the linear density of the rigid protection extension alongshore) measures have been considered. Finally, the economical performances in the period just after the land transformation have been studied by means of a dimensionless index based on the concept of the local unit. The method has been applied to the case study of the Abruzzo Region. Results reveal a large urbanization growth and a generalized over-protection of the coast with a resulting spatial alternation of shoreline retreat and advance. On the other hand, the analysis of the local economy reveals that the presence of tourism activities does not necessarily lead to an increase in the local economy. Indeed, the most important improvement in local economies in the region can be associated with coastal stretches characterized by a high environmental value.

Abstract This paper presents a theoretical and experimental investigation about the modelling of a 1:45 scale prototype Wave Energy Converter (WEC). An analytical model is implemented to describe its behaviour in a wave tank. The aim is to provide a contribution to modelling tools used for WEC characterisation and design. Hydrodynamic characterisation software is avoided in favour of a simpler and more versatile design tool destined to a wider range of users. Therefore, an alternative approach is presented, based on mechanical analogies and the use of Matlab/Simulink/SimMechanics environment. This analytical model was constructed using linear wave theory, coupled with a non-linear model for the device and its power take-off system (PTO). Assumptions on incident waves and geometric properties of the device were required and implemented on the basis of literature of naval architecture, ships stabilization and control issues. Simulation results were compared and validated with those obtained in the same range of experimental tests of the prototype in wave tank. Trends and values of both investigation techniques show a good agreement, indicating the validity of the methodology adopted and leaving space for future improvements of the same. Finally, as example of application, the model was applied in a show case in order to estimate the energy yield by the WEC if scaled to real size, using Froude scaling. Results are encouraging and show the viability of the proposed design.

Abstract Nowadays, the coupled codes technique, which consists in incorporating three-dimensional (3D) neutron modeling of the reactor core into system codes, is extensively used for carrying out best estimate (BE) simulation of complex transient in nuclear power plants (NPP). This technique is particularly suitable for transients that involve core spatial asymmetric phenomena and strong feedback effects between core neutronics and reactor loop thermal-hydraulics. Such complex interactions are encountered under normal and abnormal operating conditions of a boiling water reactors (BWR). In such reactors Oscillations may take place owing to the dynamic behavior of the liquid-steam mixture used for removing the thermal power. Therefore, it is necessary to be able to detect in a reliable way these oscillations. The purpose of this work is to characterize one aspect of these unstable behaviors using the coupled codes technique. The evaluation is performed against Peach Bottom-2 low-flow stability tests number 3 using the coupled RELAP5/PARCS code. In this transient dynamically complex neutron kinetics coupling with thermal-hydraulics events take place in response to a core pressure perturbation. The calculated coupled code results are herein assessed and compared against the available experimental data.

Global warming (GW) and urban pollution focused a great interest on hybrid electric vehicles (HEVs) and battery electric vehicles (BEVs) as cleaner alternatives to traditional internal combustion engine vehicles (ICEVs). The environmental impact related to the use of both ICEV and HEV mainly depends on the fossil fuel used by the thermal engines, while, in the case of the BEV, depends on the energy sources employed to produce electricity. Moreover, the production phase of each vehicle may also have a relevant environmental impact, due to the manufacturing processes and the materials employed. Starting from these considerations, the authors carried out a fair comparison of the environmental impact generated by three different vehicles characterized by different propulsion technology, i.e., an ICEV, an HEV, and a BEV, following the life cycle analysis methodology, i.e., taking into account five different environmental impact categories generated during all phases of the entire life of the vehicles, from raw material collection and parts production, to vehicle assembly and on-road use, finishing hence with the disposal phase. An extensive scenario analysis was also performed considering different electricity mixes and vehicle lifetime mileages. The results of this study confirmed the importance of the life cycle approach for the correct determination of the real impact related to the use of passenger cars and showed that the GW impact of a BEV during its entire life amounts to roughly 60% of an equivalent ICEV, while acidifying emissions and particulate matter were doubled. The HEV confirmed an excellent alternative to ICEV, showing good compromise between GW impact (85% with respect to the ICEV), terrestrial acidification, and particulate formation (similar to the ICEV). In regard to the mineral source deployment, a serious concern derives from the lithium-ion battery production for BEV. The results of the scenario analysis highlight how the environmental impact of a BEV may be altered by the lifetime mileage of the vehicle, and how the carbon footprint of the electricity used may nullify the ecological advantage of the BEV.

Biodiesel is a fuel generally consisting of a mixture of fatty acid methyl esters (FAMEs) which is used in alternative or in combination with petroleum diesel for its environmental benefits. Biodiesel is conveniently manufactured from vegetable oils by transesterification of triglycerides with methanol. However, the process brings about the concurrent formation of glycerol, which may become an oversupplied chemical if biodiesel production keeps growing. A novel biodiesel-like material (abbreviated as DMC-BioD) was developed by reacting soybean oil with dimethyl carbonate (DMC), which avoided the co-production of glycerol. The main difference between DMC-BioD and biodiesel produced from vegetable oil and methanol (MeOH-biodiesel) was the presence of fatty acid glycerol carbonate monoesters (FAGCs) in addition to FAMEs. In the following study, details regarding synthesis and composition of DMC-BioD are provided along with physical properties relevant for its use as a fuel. In addition, the production of potential pyrogenic contaminants was investigated by analytical pyrolysis and compared with those from MeOH-biodiesel, and the model compounds tristearin, triolein, trilinolein and oleic acid glycerol carbonate ester (OAGC). The presence of FAGCs influenced both fuel and flow properties, while the distribution of main pyrogenic compounds, including polycyclic aromatic hydrocarbons (PAHs), was little affected. Benefits and drawbacks of DMC as a candidate transmethylating reagent for producing biofuel from renewable resources and alternative co-products (glycerol carbonate and glycerol dicarbonate) are discussed.

Abstract The present work focuses on the numerical simulation of Moderate or Intense Low oxygen Dilution combustion condition, using the Partially-Stirred Reactor model for turbulence-chemistry interactions. The Partially-Stirred Reactor model assumes that reactions are confined in a specific region of the computational cell, whose mass fraction depends both on the mixing and the chemical time scales. Therefore, the appropriate choice of mixing and chemical time scales becomes crucial to ensure the accuracy of the numerical simulation prediction. Results show that the most appropriate choice for mixing time scale in Moderate or Intense Low oxygen Dilution combustion regime is to use a dynamic evaluation, in which the ratio between the variance of mixture fraction and its dissipation rate is adopted, rather than global estimations based on Kolmogorov or integral mixing scales. This is supported by the validation of the numerical results against experimental profiles of temperature and species mass fractions, available from measurements on the Adelaide Jet in Hot Co-flow burner. Different approaches for chemical time scale evaluation are also compared, using the species formation rates, the reaction rates and the eigenvalues of the formation rate Jacobian matrix. Different co-flow oxygen dilution levels and Reynolds numbers are considered in the validation work, to evaluate the applicability of Partially-Stirred Reactor approach over a wide range of operating conditions. Moreover, the influence of specifying uniform and non-uniform boundary conditions for the chemical scalars is assessed. The present work sheds light on the key mechanisms of turbulence-chemistry interactions in advanced combustion regimes. At the same time, it provides essential information to advance the predictive nature of computational tools used by scientists and engineers, to support the development of new technologies.

The use of liquid metals in solar power systems is not new. The receiver tests with liquid sodium in the 1980s at the Plataforma Solar de Almer a (PSA) already proved the feasibility of liquid metals as heat transfer fluid. Despite the high efficiency achieved with that receiver, further investigation of liquid metals in solar power systems was stopped due to a sodium spray fire. Recently, the topic has become interesting again and the gained experience during the last 30 years of liquid metals handling is applied to the concentrated solar power community. In this paper, recent activities of the Helmholtz Alliance LIMTECH concerning liquid metals for solar power systems are presented. In addition to the components and system simulations also the experimental setup and results are included.

This work investigates a new nanostructured gas-diffusion-layer (nano-GDL) to improve performance of air-cathode Single-Chamber-Microbial-Fuel-Cells (a-SCMFCs). The new nano-GDLs improves the direct oxygen-reduction-reaction by exploiting the best of nanofibers from electrospinning in terms of high surface ratio to volume and high porosity, and laser-based processing to promote adhesion. Nano-GDLs by electrospinning were fabricated directly collecting two nanofibers mats on the same carbon-based electrode, acting as the substrate. Each layer was designed with a specific function: water resistant, oxygen permeable polyvinylidene-difluoride (PVDF) nanofibers served as a barrier to prevent water-based electrolyte leakage, while an inner layer of cellulose nanofibers was added to promote oxygen diffusion towards the catalytic sites. The maximum current density obtained for a-SCMFCs with the new nano-GDLs is (132.2 ± 10.8) mA m-2, and it doubles the current density obtained with standard PTFE-based GDL (58.5 ± 2.4 mA m-2), used as reference material. The energy recovery (EF) factor, i.e. the ratio of the power output to the inner volume of the device, was then used to evaluate the overall performance of a-SCMFCs. a-SCMFCs with nano-GDL provided an EF value of 60.83 mJ m-3: one order of magnitude higher than the value of 3.92 mJ m-3 obtained with standard GDL