• Energy Research
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A membrane assisted process for green hydrogen production from a bioethanol derived feedstock is here developed and evaluated, starting from the conventional Steam Methane Reforming (SMR) process. Such a process is suitable for centralized hydrogen production, and is here analyzed for a large-scale H2 production unit with the capacity of 40.000 Nm3/h. The basic Steam Ethanol Reforming (SER) process scheme is modified in a membrane assisted process by integrating the Pd-membrane separation steps in the most suitable reaction steps. The membrane assisted process, configured in three alternative architectures (Open architecture, Membrane Reactor and Hybrid architecture) was evaluated in terms of efficiencies and hydrogen yields, obtaining a clear indication of improved process performance. The alternative membrane assisted process architectures are compared to the basic SER process and to the benchmark SMR process fed by natural gas, for an overall comparative assessment of the efficiency and specific CO2 emissions and for an economic analysis based on the operating expenditures.

In the UK electricity market, generators are obliged to produce part of their electricity with renewable energy resources in accordance with the Renewable Obligation Order. Since 2009 technology banding has been added, meaning that different technologies are rewarded with a different number of certificates. We analyze these two different renewable obligation policies in a mathematical representation of an electricity market with random availabilities of renewable generation outputs and random electricity demand. We also present another, alternative, banding policy. We provide revenue adequate pricing schemes for the three obligation policies. We carry out a simulation study via sampling. A key finding is that the UK banding policy cannot guarantee that the original obligation target is met, hence potentially resulting in more pollution. Our alternative provides a way to make sure that the target is met while supporting less established technologies, but it comes with a significantly higher consumer price. Furthermore, as an undesirable side effect, we observe that a cost reduction in a technology with a high banding (namely offshore wind) leads to more CO2 emissions under the UK banding policy and to higher consumer prices under the alternative banding policy.

Experimental research of photocatalytical oxidation (PCO) of aqueous solutions of de‐icing agents (ethylene glycol and ethylene glycol monoethyl ether) and methyl tert‐butyl ether (MTBE) was undertaken. These chemicals are water‐soluble components of jet and motor fuels accidentally disposed to the environment. Titanium dioxide (Degussa P25) under near‐UV irradiation was selected as a photocatalyst. A slightly acidic medium was preferable for the process efficiency for MTBE, whereas a neutral medium was beneficial for de‐icing agents and jet fuel aqueous extracts. TiO2 suspension fractional composition was found to be dependent on pH and the presence of organic admixtures: the minimum size of TiO2 particles at their maximum uniformity was established in an acidic medium, where the efficiency of PCO of de‐icing agents was the poorest. On the other hand, neutral and slightly acidic media, beneficial for PCO efficiency, were favourable for particle agglomeration, which indicates a minimal role for photocatalyst particle size in PCO efficiency. PCO efficiency increased with increasing MTBE and icing inhibitor concentration. The biodegradability of aqueous solutions of oxygenated additives increased as PCO proceeded. The influence of mineral additives—sulphate, calcium, ferric and manganese ions—on the process efficiency was found to be complex. Special attention was paid to energy‐saving PCO with a photocatalyst attached to buoyant glass micro‐spheres and reduced intensity of stirring of the slurry.

In the current situation with the unprecedented deployment of clean technologies for electricity generation, it is natural to expect that storage will play an important role in electricity networks. This paper provides a qualitative methodology to select the appropriate technology or mix of technologies for different applications. The multiple comparisons according to different characteristics distinguish this paper from others about energy storage systems. Firstly, the different technologies available for energy storage, as discussed in the literature, are described and compared. The characteristics of the technologies are explained, including their current availability. In order to gain a better perspective, availability is cross-compared with maturity level. Moreover, information such as ratings, energy density, durability and costs is provided in table and graphic format for a straightforward comparison. Additionally, the different electric grid applications of energy storage technologies are described and categorised. For each of the categories, we describe the available technologies, both mature and potential. Finally, methods for connecting storage technologies are discussed.

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A model for pressurised steam/O2-blown fluidised-bed gasification of biomass with catalytic reforming of hydrocarbons and tars was developed using Aspen Plus simulation software. Seven main blocks were used to model the fluidised-bed gasifier and two for the catalytic reformer. Modelling blocks were complemented with FORTRAN subroutines to simulate the observed non-equilibrium behaviour of the process. The model was fitted with experimental data derived from a 0.5 MW scale test rig operated with crushed wood pellets and forest residues and was shown to be capable of predicting product gas composition from gasification of clean wood. A parametric analysis indicated that a significant improvement in the syngas efficiency could be achieved by rising the filtration temperature and reformer conversions. Other improvement possibilities include fuel drying and lower reforming temperature.

The majority of local respondents in a large-scale survey were in favour of planned local wind farms on the Danish coast, despite these wind farm plans being the source of wider public and political contestation and opposition. Here we discuss results from the open-ended questions in the survey, specifically focusing on comments expressing how some respondents felt split in their views of these wind farms, accepting the need for renewable energy while at the same time being concerned about the potential local impact of the wind farms. Building on previous theoretical propositions relating to energy infrastructure opposition, here we apply the concept of cognitive polyphasia in some depth, providing a socio-cognitive account of the internal contradiction of being positively disposed to renewable energy in principle, but concerned about or opposed to specific de­velopments in localities. We distinguish a cognitive polyphasic account of such mixed feelings from cognitive dissonance accounts, and we identify several types of polyphasic representations, providing a basis for further work in other cases. The majority of local respondents in a large-scale survey were in favour of planned local wind farms on theDanish coast, despite these wind farm plans being the source of wider public and political contestation andopposition. Here we discuss results from the open-ended questions in the survey, specifically focusing oncommentsexpressinghowsomerespondentsfeltsplitintheirviewsofthesewindfarms,acceptingtheneedforrenewableenergywhileatthesametimebeingconcernedaboutthepotentiallocalimpactofthewindfarms.Building on previous theoretical propositions relating to energy infrastructure opposition, here we apply theconceptofcognitivepolyphasiainsomedepth,providingasocio-cognitiveaccountoftheinternalcontradictionof being positively disposed to renewable energy in principle, but concerned about or opposed to specific de-velopments in localities. We distinguish a cognitive polyphasic account of such mixed feelings from cognitivedissonanceaccounts,andweidentify severaltypesofpolyphasicrepresentations,providingabasisforfurtherworkinothercases