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Abstract A Gas–Solid Vortex Reactor (GSVR), in literature also referred to as Rotating Fluidized Bed in Static Geometry (RFB-SG), is a promising reactor type for Process Intensification (PI) with respect to reactor volume reduction. Although replacing gravitational by centrifugal force has been considered since the seventies, the hydrodynamics of the reactor flow and the bed behavior remain largely unknown. In the present work experiments have been carried out in a cold flow GSVR with diameter of 0.54 m, length of 0.1 m and 36 inlet slots of 2 mm. Gas injection velocities of 55–111 m/s and particles with densities of 950–1800 kg/m 3 and diameters of 1–2 mm have been applied. Depending on solids density, particle diameter and gas injection velocity the bed behavior can be considered as stable, semi-stable or unstable. For semi-stable and stable flow regimes the effect of the above process conditions on the maximum solids capacity was investigated. With increasing solids density, the bed stability considerably decreases, while the maximum solids capacity increases. By increasing the gas injection velocity, both the bed stability and the maximum solids capacity increase. Once bed stability is accomplished, a further increase of the gas injection velocity does not affect the maximum solids capacity. With increasing particle diameter, the bed stability decreases while the maximum solids capacity increases.

Capítulos en libros This paper assesses the scalability and replicability of smart grid projects, by means of the identification of limitations and barriers faced by these projects. Factors have been identified that impact a project s scalability and replicability by means of a review of demonstration projects. The factors are of technical, economic, regulatory and social acceptance nature, and they describe requirements for scalability and replicability. Data was collected from ongoing European smart grid demonstration projects through the use of an elaborated questionnaire on the identified factors. Which allowed to quantify the status quo to what extent projects have taken these factors into account. Dew to their nature the derived factors can be categorized in technical, economic and regulatory & stakeholder related factor areas The obtained results allowed the identification of barriers, i.e. limitations regarding the scalability and replicability of smart grid projects. In particular projects face barriers regarding the absence of standards, the physical limits of the existing infrastructure, the absence of cost-benefit analyses, the neglect of varying macro-economic factors, stakeholder involvement and from the dependency of projects on regional or national regulatory frameworks and market designs. info:eu-repo/semantics/publishedVersion

Effectively incorporating external advice is an important problem in reinforcement learning, especially as it moves into the real world. Potential-based reward shaping is a way to provide the agent with a specific form of additional reward, with the guarantee of policy invariance. In this work we give a novel way to incorporate an arbitrary reward function with the same guarantee, by implicitly translating it into the specific form of dynamic advice potentials, which are maintained as an auxiliary value function learnt at the same time. We show that advice provided in this way captures the input reward function in expectation, and demonstrate its efficacy empirically.

Urban environments provide opportunities for greater resource efficiency and the fostering of urban ecosystems. Brownfield areas are a typical example of underused land resources. Brownfield redevelopment projects that include green infrastructure allow for further ecosystems to be accommodated in urban environments. Green infrastructure also deliver important urban ecosystem services (UES) to local residents, which can greatly contribute to improving quality of life in cities. In this case study, we quantify and assess the economic value of five UES for a brownfield redevelopment project in Antwerp, Belgium. The assessment is carried out using the “Nature Value Explorer” modelling tool. The case includes three types of green infrastructure (green corridor,infiltration gullies and green roofs) primarily intended to connect nature reserves on the urban periphery and to avoid surface runoff. The green infrastructure also provides air filtration, climate regulation, carbon sequestration and recreation ecosystem services. The value of recreation far exceeds other values, including the value of avoided runoff. The case study raises crucial questions as to whether existing UES valuation approaches adequately account for the range of UES provided and whether such approaches can be improved to achieve more accurate and reliable value estimates in future analyses.

Abstract In this study, the external surface of a finned tube was coated by 13X zeolite powder, and the CO2 adsorption equilibrium and dynamics were investigated experimentally. A slurry consisting of dionized water, 13X zeolite powder, and Acrylic latex emulsion (ALE) was used to coat the finned tube. The finned tube was coated by deep coating method. The equilibrium isotherms were measured at the range of 20–90 °C and fitted well by the dual-site Langmuir model. The average difference between the model and the results obtained from the experiments is about 2.5%. The nitrogen adsorption/desorption at 77 K was used for characterization of adsorbents. A 11% reduction was observed in pore volume and surface area. The dynamic test showed that the desorption of adsorbed CO2 takes place in about 14 s which is an order of magnitude faster than the fastest developed method. A conservative criterion was developed for estimating adsorbent working capacity. This criterion showed that the working capacities of the adsorbent are about 80% of its ideal values.

Abstract The present paper proposes a way to introduce chemical reactions in composite curves, in such a way that the irreversibility’s generated by the chemical reaction are expressed as equivalent thermal diffusion. The heat of reaction is considered to be released at a “reversible reaction temperature” and the diffusion between this reversible temperature and the actual temperature generates the actual exergy destruction. Corresponding hot and cold curve contributions result in the composite curves, which visualizes the exergy destruction and the chemical pinches which are present in the exchanger and reactor network. The concept is illustrated through an application on chemical recuperation in a gas turbine cycle.

Life Cycle Assessment is a tool to assess the environmental impacts and resources used throughout a product's life cycle, i.e., from raw material acquisition, via production and use phases, to waste management. The methodological development in LCA has been strong, and LCA is broadly applied in practice. The aim of this paper is to provide a review of recent developments of LCA methods. The focus is on some areas where there has been an intense methodological development during the last years. We also highlight some of the emerging issues. In relation to the Goal and Scope definition we especially discuss the distinction between attributional and consequential LCA. For the Inventory Analysis, this distinction is relevant when discussing system boundaries, data collection, and allocation. Also highlighted are developments concerning databases and Input-Output and hybrid LCA. In the sections on Life Cycle Impact Assessment we discuss the characteristics of the modelling as well as some recent developments for specific impact categories and weighting. In relation to the Interpretation the focus is on uncertainty analysis. Finally, we discuss recent developments in relation to some of the strengths and weaknesses of LCA.