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As a relatively mature technology, biomass molded fuel (BMF) is widely used in distributed and centralized heating in China and has received considerable government attention. Although many BFM incentive policies have been developed, decreased domestic traditional fuel prices in China have caused BMF to lose its economic viability and new policy recommendations are needed to stimulate this industry. The present study built a regionalized net present value (NPV) model based on real production process simulation to test the impacts of each policy factor. The calculations showed that BMF production costs vary remarkably between regions, with the cost of agricultural briquette fuel (ABF) ranging from 86 US dollar per metric ton (USD/t) to 110 (USD/t), while that of woody pellet fuel (WPF) varies from 122 USD/t to 154 USD/t. The largest part of BMF’s cost composition is feedstock, which accounts for up 50%–60% of the total; accordingly a feedstock subsidy is the most effective policy factor, but in consideration of policy implementation, it would be better to use a production subsidy. For ABF, the optimal product subsidy varies from 26 USD/t to 57 USD/t among different regions of China, while for WPF, the range is 36 USD/t to 75 USD/t. Based on the data, a regional BMF development strategy is also proposed in this study.

Bioenergy is considered a sustainable substitute to fossil-fuel resources and the development of a prudent combination of renewable and innovative conversion technologies are essential for the valorization and effective conversion of biowaste to value-added commodities. Here, a negative pressure-induced carbonization process was proposed for the valorization of lignin-enriched biowaste precursor to bio-oil and environmental materials (biochar) at various temperatures. The high heating values (HHV) of the as-prepared biochars from the lignin enriched precursor under negative pressure (low-medium vacuum) were within 25.9-31.5 MJ/kg, which matched satisfactorily to the commercial charcoal. Whereas, the bio-oils produced from the lignin enriched precursor under vacuum conditions was a blend of complex aromatic and straight-chain hydro-carbons, including aldehyde, ketone, phenol, and furans, exhibiting ability as potential heating-oil with HHV within 21.2-28.2 MJ/kg. Moreover, the biochars produced under vacuum environments at higher temperature showed greater stability (22.5-35.9%) than those produced under N2 atmosphere.

Abstract The Liquefied natural gas (LNG) cryogenic submerged pump, the core power equipment for the transportation of liquefied natural gas, is prone to cavitation. However, based on the traditional analysis of the pressure drop, the irreversible loss after cavitation can barely be displayed quantitatively. To solve this problem, an entropy production diagnostic model (EPDM) by the contribution of viscous entropy production (VEP), turbulent entropy production (TEP) and wall entropy production (WEP) for the cavitation flow was established to calculate the energy loss. The cryogenic cavitation model and proposed EPDM were proved to be reliable after comparing results with Hord’s experiment in an ogive and cavitation experiment in a centrifugal pump. Then, by studying the total entropy production, it was found that the EPDM could well predict the occurrence of the critical cavitation and the deterioration of cavitation. When compared with TEP and WEP, the effect of VEP is negligible. As the cavitation area expands from the suction surface of inducer (id) to the first-stage impeller (impA), the cavitation process can be divided into three stages and the total energy loss increases significantly from the first stage to the third one. Through the global distribution of energy loss, it was found that the faster growth of the loss in the second-stage impeller (impB) and the second-stage guide vane (gvB), not in id and impA, contributes more to the energy loss after cavitation. Finally, from the variation of ratio of TEP to WEP, it reveals that cavitation has a greater effect on the WEP rate for the impB, but the turbulent viscous dissipation is still dominant, while the eddy dissipation and resistance loss in gvB with the evolution of cavitation are both crucial.

Abstract The design and operation of a new clapboard-type internal circulating fluidized-bed gasifier is proposed in this article. By arranging the clapboard in the bed, the gasifier is thus divided into two regions, which are characterized by different fluidization velocities. The bed structure is designed so that it can guide the circulating flow passing through the two regions, and therefore the feedstock particles entrained in the flow experience longer residence time. The experimental results based on the present new design, operating in the temperature range of 790°C–850°C, indicate that the gas yield is from 1.6–1.9 Nm3/kg feedstock, the gas enthalpies are 5,345 kJ/Nm3 for wood chip and 4,875 kJ/m3 for rice husk, and a gasification efficiency up to 75% can be obtained.

Abstract This paper presents a novel and environmentally friendly production of direct reduced iron (DRI) technology using biomass as an additive agent in iron ore pellets and simulated biomass-derived syngas as the reducing agent. The effects of biomass addition on iron ore pellets reduction and consequent reduction kinetics in simulated biomass-derived syngas atmosphere were investigated. The results demonstrated that the biomass addition improved the pellet porosity and specific surface area, thus increasing both the reducibility and reduction rate and decreasing the apparent activation energy for pellet reduction. Mathematical modelling of experimental data indicated an interfacial chemical reaction mechanism with FeO → Fe as the rate controlling step. The simulated biomass syngas is an alternative gas-based reductant to natural gas, coal gas, more than 99.5% reduction degree of the oxidized pellets was reduced at 1323 K within 20 min. The apparent activation energies were 86.05 kJ·mol −1 , 97.53 kJ·mol −1 for the pellets with and without biomass addition. The proposed iron ore reduction process therefore would be a potential to reduce iron directly using biomass with high efficiency and real environmental benefits.

Abstract A high-flux solar simulator is essential for evaluating solar thermal components under controlled and adjustable flux input conditions. This study presents a newly built high-flux solar simulator composed of 19 individual units. Each unit includes a xenon short-arc lamp (each consuming up to 6 kW electricity power) coupled with a truncated ellipsoidal reflector, a cooling blower, and a power module. The power module yields a current in the range of 50–160 A. The number of lamps in use is flexible, which allows for a wide range of radiation flux (10%–100%) on the focal plane. The radiation power, peak value, flux distribution on the circular target plane, and conversion efficiency are evaluated based on a flux mapping method. The results indicate that the proposed solar simulator is capable of achieving thermal power of 23.3 kW, peak flux in excess of 1.78 MW/m2, a stagnation temperature exceeding 2360 °C, and average irradiance of 773.4 kW/m2 on the focal plane (diameter of 260 mm). The electro-thermal conversion efficiency of the simulator is 35.7%. A ray-tracing method was employed, and the simulation results were found to be in good agreement with those in the experiments. An experimental test of a volumetric ceramic receiver was conducted, and the results indicate the availability and applicability of the high-flux solar simulator when carrying out studies about solar receivers.

Abstract The absorption refrigeration system driven by low grade heat sources, especially the waste heat sources, becomes more and more attractive in recent decades. However, most traditional absorption systems cannot achieve a high utilization rate of the waste heat with limited heat capacity. These systems are usually designed to obtain heat in the generator, which means that the waste heat sources cannot be utilized to the temperature lower than the generator temperature. This paper proposed a new structure heated by heat conduction oil in the generator and electric heating rings around the stripping section. This structure can simulate the temperature-distributed heat sources when the electric heating rings work. It can also simulate a traditional generator when the electric heating rings do not work. Influences of different heat distributions are analyzed in detail in this paper. The results show that the heat sources utilization rate will increase with the increase of the heat in the stripping section, while the coefficient of performance will be negatively affected by the increasing heat in the stripping section. By optimizing the heating structure, the coefficient of performance can be similar to that of a traditional system when the heat is just added in the middle and lower part of stripping section. The optimum utilization rate of heat sources in this test model can reach 1.8 times to that of a traditional system. Under this heating model, the lowest temperature required in the heating section is 82 °C when the heat conduction oil inlet temperature is 169 °C. It is much lower than the temperature inside the generator, which is 137.3 °C.

It is critical and challenging to develop high performance transition metal phosphides (TMPs) electrocatalysts for oxygen evolution reaction (OER) to address fossil energy shortages. Herein, we report the synthesis of Co2P embedded in N-doped porous carbon (Co2P@N-C) via a facile one-step strategy. The obtained catalyst exhibits a lower overpotential of 352 mV for OER at a current density of 10 mA cm−2 and a small Tafel slope of 84.6 mV dec−1, with long-time reliable stability. The excellent electrocatalytic performance of Co2P@N-C can be mainly owed to the synergistic effect between the Co2P and highly conductive N-C substrate, which not only affords rich exposed active sites but also promotes faster charge transfer, thus significantly promoting OER process. This work presents a promising and industrially applicable synthetic strategy for the rational design of high performance nonnoble metal electrocatalysts with enhanced OER performance.