• Energy Research
• 7. Clean energy close

To study the heating performance of a solar-assisted cold-water phase-change-energy heat pump system, its heating performance under series and parallel connections is simulated for a community in Harbin, the influence of ice thickness on the different operation modes is analyzed, and the economy of the system is calculated for series and parallel connections in this paper. The results show that the water supply temperature is higher and more uniform in the parallel operation, and more terminal heat is supplied; the ice thickness has more of an influence on the series connection compared to the parallel connection; and the dynamic payback period is 6.72 years for the series connection and 7.28 years for the parallel connection. This case study can serve as a guide for practical engineering application projects and act as a reference for heating and economic data for the promotion of this heat pump system.

Fullerene-based materials are widely used as acceptor and electron transport layer materials in organic and planar perovskite solar cells. Modeling of electronic properties such as band alignment and charge transport for these applications is typically done using optimized geometries. Here, we estimate the effects of nuclear motions on band structure, and electron and hole transport in two prototypical fullerenes, C60 and C70. We model the dynamics in solid fullerenes using Density Functional Tight Binding and we use the Density Functional Theory based Projection of Monomer Orbitals on Dimer Orbitals (DIPRO) approach to estimate the effects on the charge transfer integral in the Marcus approximation. We show that room-temperature molecular dynamics cause a shift and spread of frontier orbital energies on the order of 0.1 eV, which leads to an increase by more than a factor of two in the Marcus exponent, and can cause a decrease by up to orders of magnitude in the overlap integral, leading, in most cases, to an overall decrease in the charge transport rate.

In this work, metal-oxide-semiconductor (MOS) capacitors incor-porating D2O-radical annealed atomic-layer-deposition (ALD) HfO2 gate dielectric were fabricated and investigated. The thermo-chemical breakdown model (E model) is used to analyze the TDDB characteristics for lifetime projection. TDDB data shows that Weibull slope (β) is increased with increasingly stress tem-perature. This may come from the temperature sensitive defects and possible redistribution in dielectric. Meanwhile, the Weibull slope is independent of the stress voltage. Based on the TDDB data, the activation energy (Ea), active dipole-moment (p0) electric-field acceleration factor (γ) and electric field at 10 years lifetime (E10years) of the D2O-radical annealed ALD HfO2 thin films were obtained.

Abstract This work, framed in the IEA SHC Task 51 “Solar Energy in Urban Planning”, presents an illustrative perspective of solar energy in urban planning through the analysis of 34 international case studies conducted in 10 countries. The aim here is to examine challenges, barriers and opportunities for active solar systems and passive solar strategies by taking into consideration interrelated technical and non-technical aspects in ongoing and completed projects. It focuses on exposing potential pitfalls and illustrating lessons learned in case studies divided into three categories: (i) existing urban areas, (ii) new urban areas, and (iii) solar landscapes. The analysis has yielded insights into the solar energy strategy adoption, the evaluation of solar energy production, solar irradiation and daylighting, and the architectural quality, sensitivity and visibility of the solar systems for urban planning. The outcomes have implications to stimulate successful practices in implementing solar strategies in urban planning and facilitating their replicability worldwide by avoiding common mistakes.

Abstract This paper aims to investigate sustainable waste management solutions for the city of Rio de Janeiro in Brazil, based on a life cycle approach. The Life Cycle Assessment (LCA) was performed by using the LCA-IWM methodology. The model was adapted to the Brazilian solid waste context and to the local characteristics, including waste composition, electricity mix and regulations. The annual amount of waste generated was the functional unit adopted. Eight municipal solid waste management strategies were evaluated. Scenarios including mixed waste collection and source separated collection as well as materials recovery and energy from waste were investigated. Scenarios were ranked based on the LCA results. Sensitivity analysis was carried out by varying the electricity mix. The results indicate that the current situation of municipal solid waste (MSW) in Rio de Janeiro presents the worst performance in terms of aggregated environmental burdens, indicating the urgency for implement new strategies toward a more environmentally friendly and sustainable MSW management system. It is noted that the better LCA performances were obtained in scenarios with high separately collection rates. Among them, the scenario based on recyclables recovery and anaerobic digestion shows to be a promising strategy to improve environmental sustainability. Sensitivity analysis demonstrates that the ranking of scenarios was not affected by changes in the electricity mix. From the results, the investment in source separated waste collection and materials recovery is the most environmentally friendly MSW strategy for Rio de Janeiro. In addition, scenarios with an emphasis in materials recovery presented higher environmental benefits than the alternatives focused on energy generation.

Abstract The new multicomponent Co-based catalysts with additives of group 8 metal and rare earth elements and supported on alumina have been tested in the dry and steam conversion of a model biogas. The processes were carried out in a flow quartz reactor under the following conditions: atmospheric pressure, a gas hourly space velocity of 1000 h−1 and temperatures of 300–800°C. The catalysts were characterised using electron microscopy, BET and X-ray analysis. The methane is almost completely converted in the dry reforming of biogas at T≤800°C. Synthesis gas with a ratio of H2/CO>1.0 is a main product of biogas reforming over the multicomponent catalysts studied. Adding steam in a feed composition increases both the methane conversion and the hydrogen yield at lower temperatures. Almost complete methane conversion occurs at T<750°C in the steam reforming of biogas. The catalysts are highly effective and exhibit stable activity throughout 100 h of continuous testing.

SummaryNumerous wind turbines form large‐scale wind farms, which are complex nonlinear systems with uncertain parameters. The issue of maximum wind energy capture and coordinated control has always been a research hotspot. In this article, under the condition of limited input and uncertain parameters, the preset controller and the adaptive cooperation control are designed to realize the maximum wind energy capture for every wind turbine and the adaptive cooperation control of multiple wind turbines. The research gap lies in that the Hamilton model of wind power generation system is established with uncertain parameters, and the preset controller (method) is designed to capture the maximum wind energy. Under the hypothesis that the uncertain part can be expressed as a linear form about unknown parameter, and using the saturation function processing method in the diagonal matrix, an adaptive feedback controller with limited input is designed to realize the adaptive cooperation control of multiple wind turbines. The simulation results show that under the conditions such as variable wind speed, limited input and uncertain parameters, the wind turbine remain normal operation at the desired angular velocity. It can be concluded that not only the maximum wind energy capture is realized under the condition of variable wind speed, in which the wind turbine can operate on the optimal power curve to improve the utilization of wind energy, but also the adaptive cooperation control of multiple wind turbines can be achieved with limited input and parameter perturbation.

Abstract In this paper, a reintegration-based multi-objective intentional controlled islanding (ICI) model is proposed to enhance resiliency of electrical power systems under catastrophic events. This remedial measure plan relies on a mixed-integer linear programming model with two objective functions including reintegration risk and total load shedding value. While ensuring that each island includes only coherent generators, the proposed multi-objective model solves the controlled islanding problem using lexicographic optimization approach. To ease the islands’ reintegration, charging reactive power, reliability, capacity, and power flow disruption of transmission lines are considered in the model. After implementation of controlled islanding, each resulted island may face temporary active/reactive load-generation imbalance, which may put the islands at the risk of frequency instability, transient voltage instability or a combination of both. The proposed model reduces these risks by modeling energy storage systems (ESSs) and static VAR compensators (SVCs) as fast corrective control actions. In addition to modeling voltage dependent loads in the controlled islanding problem, a linear island frequency response (IFR) model is proposed for frequency stability assessment. The test results of the proposed ICI model on the IEEE 39-bus and IEEE 118-bus test systems demonstrate its performance.