In this study, modern nitrogen steels used for the manufacture of rings for Honda engines (70CC, 90CC, CRF70F, XL70, XR70, C70, CT70, ATC70, CL70) as well as other transport tribotechnical units was investigated. Due to the present ecological situation in the world, new environmentally friendly lubricating fluids for nitrogen steels’ tribotechnical units and surface treatments have been proposed. The results of tribotechnical tests are presented in the form of diagrams, graphs and step polynomials obtained by mathematically describing the changes in wear intensity when the load changes for different lubricating fluids. Friction pairs were compared with ShellHF-E 46 (synthetic lubricating fluid), ShellHF-R (biological origin) and lubricating and cooling liquids with 1%, 3% and 5% vegetable oil concentrations. In tribocoupling it was found that hydrogen diffuses into the metal because the tribodestruction of lubricating coolants plays an active role in the destruction of friction surfaces.