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The Photodegradation of Quercetin: Relation to Oxidation

Authors: DALL'ACQUA, STEFANO; MIOLO, GIORGIA; INNOCENTI, GABBRIELLA; S. Caffieri;

The Photodegradation of Quercetin: Relation to Oxidation

Abstract

The photostability of quercetin in alcoholic solutions was studied. Both UVA and UVB light induced degradation of quercetin, yielding a single product 1 deriving from oxidation and addition of an alcohol molecule to the 2,3 double bond. The same mechanism operated when quercetin was dissolved in alkaline solutions, and again a product 2 due to oxidation and addition of water was characterized. Comparison with quercetin analogs confirmed that, despite the presence of five hydroxy groups in quercetin, those in positions 3, 3′, and 4′ are mainly involved in the antioxidant activity of the compound , as well as in its photolability.

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Keywords

Ultraviolet Rays, Rutin, Organic chemistry, photostability, Article, quercetin, QD241-441, quercetin; photostability; photodegradation, Drug Stability, Ammonia, Apigenin, Kaempferols, Flavonoids, Ethanol, Methanol, Hydrogen-Ion Concentration, Photochemical Processes, Solutions, Solvents, Quercetin, Spectrophotometry, Ultraviolet, photodegradation, Oxidation-Reduction

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    citations
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    104
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 1%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
104
Top 1%
Top 10%
Top 10%
Green
gold
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